Limnological investigation of biogenic silica sedimentation and silica biogeochemistry in Lake St. Moritz and Lake Zürich

Biogenic silica concentrations were determined from core samples of laminated sediments collected from Lake Zürich and Lake St. Moritz and used to calculate rates of biogenic silica sedimentation. In Lake Zürich biogenic silica sedimentation increased from 65 g SiO₂·^?2·yr^?1 in 1894 to nearly 900 g SiO₂·m^?2·yr^?1 in 1896 and in Lake St. Moritz biogenic silica sedimentation increased about 6-fold during the 1930s. Both periods of increased biogenic silica flux followed increased loadings of domestic sewage to the lakes. In Lake Zürich the period of increased flux only lasted for a few years whereas in Lake St. Moritz high fluxes were maintained to the top of the core. In Lake Zürich increased production and sedimentation of diatoms could be maintained only until the silca reservoir in the water mass was depleted whereas in Lake St. Moritz (0.10 year residence time and a mean depth of 25 m) diatom production and sedimentation was maintained at a high level by rapid replenishment of silica from tributary inputs. Although historical patterns of biogenic silica sedimentation differed for the two lakes, it is hypothesized that increased biogenic silica deposition in both lakes occurred because diatom production was stimulated by phosphorus enrichment of the water mass and that the silica biogeochemistry of both lakes was affected as a result.     

Late Pleistocene variations in Antarctic sea ice I: effect of orbital insolation changes

The effect of orbitally induced insolation changes on Antarctic sea-ice cover are examined by means of a dynamic-thermodynamic seaice model. Results are compared with modified CLIMAP 18 000 B.P. sea-ice reconstructions. Calculations suggest that changes in insolation receipt had only a minor influence on Pleistocene sea-ice distributions. The small response can be explained by a number of factors: albedo effects reduce the insolation perturbation at the surface; some of the shortwave radiation entering the ocean contributes to bottom ablation rather than lateral melting; the radiation perturbation at the upper surface of the ice must go to warming the surface to the melting point before melting ensues; and, finally, the relatively high heat capacity of open water dampens the surface temperature response to altered seasonal insolation perturbations.     

Detecting post-depositional sediment disturbance in sandy deposits using optical luminescence

Post-depositional mixing or exhumation is common in surficial sediments, yet may be unobservable from field evidence. However, any disturbance may have significant consquences in terms of establishing a reliable luminescence age determination. Optically stimulated luminescence (OSL) measurements, particularly measurements at the single grain level, can be used to gain an insight into both contemporary and past post-depositional processes.

This paper examines sites from Texas and Florida (USA) with independent chronological control to demonstrate the potential effects of varying degrees of bioturbation on OSL. Results show that contemporary soil forming processes clearly impact on the palaeodose (D_e) replicate distributions which are measured in order to derive an OSL age. Significant levels of scatter and apparently zero dose grains are observed in the upper-most sediments; declining with depth from the surface. D_e replicates from undisturbed and fully bleached sediments are unskewed, show low overdispersion (OD) and comparable single grain and single aliquot OSL ages. Bioturbated sediments, however, may show highly skewed multi-model D_e distributions with higher OD values, zero dose grains at depth, and significant diffences between single grain and single aliquot results. True burial ages may be derived from minimally bioturbated sediments through the application of statistical analysis such as finite mixture modelling to isolate D_e components. However, for significantly bioturbated sediments, the latter approach, even at the single grain level, produces inaccurate ages. In such cases we argue that additional evidence (both dating and contexual) may be required to identify with confidence the burial D_e population.     

Developing a protocol for selecting and dating sandy sites in East Central Texas: Preliminary results

Vast areas of East Central Texas are overlain by deep unconsolidated sands, previously assumed to have been formed by in situ weathering and pedoturbation of the bedrock. This hypothesis would imply that palaeoenvironmental and archaeological reconstructions are of limited value. However, recent research has hinted that some elements of the landscape may have undergone repeated phases of erosion and redeposition, suggesting firstly that a reliable record of past environmental conditions may be gleaned from these deposits, and secondly that optically stimulated luminescence (OSL) may provide the key to unlocking this record. This research examines the depositional history of sites shown to provide a reliable chronology. Dates from these sites show that aeolian deposition occurred in East Central Texas at a number of times during the Holocene and Late Glacial, whilst three episodes of gullying occurred between approximately 123,000 and 44,000 years ago. The concordance of some of these results indicates that some phases of deposition may be regional.     

Subduction initiation and ophiolite crust: new insights from IODP drilling

International Ocean Discovery Program (IODP) Expedition 352 recovered a high-fidelity record of volcanism related to subduction initiation in the Bonin fore-arc. Two sites (U1440 and U1441) located in deep water nearer to the trench recovered basalts and related rocks; two sites (U1439 and U1442) located in shallower water further from the trench recovered boninites and related rocks. Drilling in both areas ended in dolerites inferred to be sheeted intrusive rocks. The basalts apparently erupted immediately after subduction initiation and have compositions similar to those of the most depleted basalts generated by rapid sea-floor spreading at mid-ocean ridges, with little or no slab input. Subsequent melting to generate boninites involved more depleted mantle and hotter and deeper subducted components as subduction progressed and volcanism migrated away from the trench. This volcanic sequence is akin to that recorded by many ophiolites, supporting a direct link between subduction initiation, fore-arc spreading, and ophiolite genesis.     

A submillimetre survey for protostellar accretion discs using the JCMT–CSO interferometer

We present a submillimetre continuum survey for accretion discs around seven embedded protostars in the Perseus and Serpens molecular clouds. Observations were made at frequencies between 339 and 357 GHz using the James Clerk Maxwell Telescope–Caltech Submillimeter Observatory single-baseline interferometer on Mauna Kea, Hawaii. All the objects in our survey show compact dust emission on scales ≲1 arcsec, assumed to arise in a circumstellar accretion disc. We compare the properties of this compact component with evolutionary indicators, such as the ratio of compact to extended emission, and bolometric temperature. We find that discs of mass ∼0.01 M_⊙ have formed by the Class 0 stage, and that similar mass discs are observed in Class I and Class II sources. A trend is observed whereby the ratio of compact to extended emission in our sources increases from Class 0 to Class II sources. For three of the objects in the survey, NGC 1333 IRAS2:CR1 and SVS13 in Perseus, and FIRS1 in Serpens, the signal-to-noise ratio is sufficient to allow us to model the brightness distributions with elliptical Gaussian and power-law disc models. The Gaussian fits give semimajor half-power radii of approximately 90 to 140 au, at the assumed distance of 350 pc to the Perseus and Serpens clouds.     

Perturbation of fluvial sediment fluxes following the 2008 Wenchuan earthquake

Quantifying the removal of co‐seismic landslide material after a large‐magnitude earthquake is central to our understanding of geomorphic recovery from seismic events and the topographic evolution of tectonically active mountain ranges. In order to gain more insight into the fluvial erosion response to co‐seismic landslides, we focus on the sediment fluxes of rivers flowing through the rupture zone of the 2008 M_w 7.9 Wenchuan earthquake in the Longmen Shan of the eastern Tibetan Plateau. Over the post‐seismic period of 2008–2013, we annually collected river sediment samples (0.25–1 mm) at 19 locations and measured the concentration of cosmogenic ¹⁰Be in quartz. When compared with published pre‐earthquake data, the ¹⁰Be concentrations declined dramatically after the earthquake at all sampling sites, but with significant spatial differences in the amplitude of this decrease, and were starting to increase toward pre‐earthquake level in several basins over the 5‐year survey. Our analysis shows that the amplitude of ¹⁰Be decrease is controlled by the amount of landslides directly connected to the river network. Calculations based on ¹⁰Be mixing budgets indicate that the sediment flux of the 0.25–1 mm size fraction increased up to sixfold following the Wenchuan earthquake. Our results also suggest that fluvial erosion became supply limited shortly after the earthquake, and predict that it could take a few years to several decades for fluvial sediment fluxes to go back to pre‐earthquake characteristics, depending on catchment properties. We also estimate that it will take at least decades and possibly up to thousands of years to remove the co‐seismic landslide materials from the catchments in the Longmen Shan. Copyright © 2017 John Wiley & Sons, Ltd.     

Biochemical indicators for the bioavailability of organic carbon in ground water

The bioavailability of total organic carbon (TOC) was examined in ground water from two hydrologically distinct aquifers using biochemical indicators widely employed in chemical oceanography. Concentrations of total hydrolyzable neutral sugars (THNS), total hydrolyzable amino acids (THAA), and carbon-normalized percentages of TOC present as THNS and THAA (referred to as "yields") were assessed as indicators of bioavailability. A shallow coastal plain aquifer in Kings Bay, Georgia, was characterized by relatively high concentrations (425 to 1492 μM; 5.1 to 17.9 mg/L) of TOC but relatively low THNS and THAA yields (∼0.2%–1.0%). These low yields are consistent with the highly biodegraded nature of TOC mobilized from relatively ancient (Pleistocene) sediments overlying the aquifer. In contrast, a shallow fractured rock aquifer in West Trenton, New Jersey, exhibited lower TOC concentrations (47 to 325 μM; 0.6 to 3.9 mg/L) but higher THNS and THAA yields (∼1% to 4%). These higher yields were consistent with the younger, and thus more bioavailable, TOC being mobilized from modern soils overlying the aquifer. Consistent with these apparent differences in TOC bioavailability, no significant correlation between TOC and dissolved inorganic carbon (DIC), a product of organic carbon mineralization, was observed at Kings Bay, whereas a strong correlation was observed at West Trenton. In contrast to TOC, THNS and THAA concentrations were observed to correlate with DIC at the Kings Bay site. These observations suggest that biochemical indicators such as THNS and THAA may provide information concerning the bioavailability of organic carbon present in ground water that is not available from TOC measurements alone.     

Stochastic downscaling method: application to wind refinement

In this article, we propose a new stochastic downscaling method: provided a numerical prediction of wind at large scale, we aim to improve the approximation at small scales thanks to a local stochastic model. We first recall the framework of a Lagrangian stochastic model borrowed from Pope. Then, we adapt it to our meteorological framework, both from the theoretical and numerical viewpoints. Finally, we present some promising numerical results corresponding to the simulation of wind over the Mediterranean Sea.