Processing of oxidised nitrogen compounds by passage through winter-time orographic cloud

Four case studies are described, from a three-site field experiment in October/November 1991 using the Great Dun Fell flow-through reactor hill cap cloud in rural Northern England. Measurements of total odd-nitrogen nitrogen oxides (NO _y ) made on either side of the hill, before and after the air flowed through the cloud, showed that 10 to 50% of the NO _y , called NO _z , was neither NO nor NO₂. This NO _z failed to exhibit a diurnal variation and was often higher after passage through cloud than before. No evidence of conversion of NO _z to NO₃ ^- in cloud was found. A simple box model of gas-phase chemistry in air before it reached the cloud, including scavenging of NO₃ and N₂O₅ by aerosol of surface area proportional to the NO₂ mixing ratio, shows that NO₃ and N₂O₅ may build up in the boundary layer by night only if stable stratification insulates the air from emissions of NO. This may explain the lack of evidence for N₂O₅ forming NO₃ ^- in cloud under well-mixed conditions in 1991, in contrast with observations under stably stratified conditions during previous experiments when evidence of N₂O₅ was found. Inside the cloud, some variations in the calculated total atmospheric loading of HNO₂ and the cloud liquid water content were related to each other. Also, indications of conversion of NO _x to NO _z were found. To explain these observations, scavenging of NO _x and HNO₂ by cloud droplets and/or aqueous-phase oxidation of NO₂ ^- by nitrate radicals are considered. When cloud acidity was being produced by aqueous-phase oxidation of NO _x or SO₂, NO₃ ^- which had entered the cloud as aerosol particles was liberated as HNO₃ vapour. When no aqueous-phase production of acidity was occurring, the reverse, conversion of scavenged HNO₃ to particulate NO₃ ^-, was observed.     

ENSO,the IOD and the intraseasonal prediction of heat extremes across Australia using POAMA-2

The simulation and prediction of extreme heat over Australia on intraseasonal timescales in association with the El Niño–Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) is assessed using the Bureau of Meteorology’s Predictive Ocean Atmosphere Model for Australia (POAMA). The analysis is based on hindcasts over 1981–2010 and focuses on weeks 2 and 3 of the forecasts, i.e. beyond a typical weather forecast. POAMA simulates the observed increased probabilities of extreme heat during El Niño events, focussed over south eastern and southern Australia in SON and over northern Australia in DJF, and the decreased probabilities of extreme heat during La Niña events, although the magnitude of these relationships is smaller than observed. POAMA also captures the signal of increased probabilities of extreme heat during positive phases of the IOD across southern Australia in SON and over Western Australia in JJA, but again underestimates the strength of the relationship. Shortcomings in the simulation of extreme heat in association with ENSO and the IOD over southern Australia may be linked to deficiencies in the teleconnection with Indian Ocean SSTs. Forecast skill for intraseasonal episodes of extreme heat is assessed using the Symmetric Extremal Dependence Index. Skill is highest over northern Australia in MAM and JJA and over south-eastern and eastern Australia in JJA and SON, whereas skill is generally poor over south-west Western Australia. Results show there are windows of forecast opportunity related to the state of ENSO and the IOD, where the skill in predicting extreme temperatures over certain regions is increased.     

Influence of the Andes Mountains on South American moisture transport, convection, and precipitation

Mountain ranges are known to have a first-order control on mid-latitude climate, but previous studies have shown that the Andes have little effect on the large-scale circulation over South America. We use a limited-domain general circulation model (RegCM3) to evaluate the effect of the Andes on regional-scale atmospheric dynamics and precipitation. We present experiments in which Andean heights are specified at 250 m, and 25, 50, 75, and 100% of their modern values. Our experiments indicate that the Andes have a significant influence on moisture transport between the Amazon Basin and the central Andes, deep convective processes, and precipitation over much of South America through mechanical forcing of the South American low-level jet (LLJ) and topographic blocking of westerly flow from the Pacific Ocean. When the Andes are absent, the LLJ is absent and moisture transport over the central Andes is mainly northeastward. As a result, deep convection is suppressed and precipitation is low along the Andes. Above 50% of the modern elevation, a southward flowing LLJ develops along the eastern Andean flanks and transports moisture from the tropics to the subtropics. Moisture drawn from the Amazon Basin provides the latent energy required to drive convection and precipitation along the Andean front. Large northerly moisture flux and reduced low-level convergence over the Amazon Basin leads to a reduction in precipitation over much of the basin. Our model results are largely consistent with proxy evidence of Andean climate change, and have implications for the timing and rate of Andean surface uplift.     

Climate change links fate of glaciers and an endemic alpine invertebrate

Climate warming in the mid- to high-latitudes and high-elevation mountainous regions is occurring more rapidly than anywhere else on Earth, causing extensive loss of glaciers and snowpack. However, little is known about the effects of climate change on alpine stream biota, especially invertebrates. Here, we show a strong linkage between regional climate change and the fundamental niche of a rare aquatic invertebrate—the meltwater stonefly Lednia tumana—endemic to Waterton-Glacier International Peace Park, Canada and USA. L. tumana has been petitioned for listing under the U.S. Endangered Species Act due to climate-change-induced glacier loss, yet little is known on specifically how climate impacts may threaten this rare species and many other enigmatic alpine aquatic species worldwide. During 14 years of research, we documented that L. tumana inhabits a narrow distribution, restricted to short sections (~500 m) of cold, alpine streams directly below glaciers, permanent snowfields, and springs. Our simulation models suggest that climate change threatens the potential future distribution of these sensitive habitats and the persistence of L. tumana through the loss of glaciers and snowfields. Mountaintop aquatic invertebrates are ideal early warning indicators of climate warming in mountain ecosystems. Research on alpine invertebrates is urgently needed to avoid extinctions and ecosystem change.     

Dynamic modelling of passive margin salt tectonics: effects of water loading, sediment properties and sedimentation patterns

We investigate the evolution of passive continental margin sedimentary basins that contain salt through two‐dimensional (2D) analytical failure analysis and plane‐strain finite‐element modelling. We expand an earlier analytical failure analysis of a sedimentary basin/salt system at a passive continental margin to include the effects of submarine water loading and pore fluid pressure. Seaward thinning sediments above a weak salt layer produce a pressure gradient that induces Poiseuille flow in the viscous salt. We determine the circumstances under which failure at the head and toe of the frictional–plastic sediment wedge occurs, resulting in translation of the wedge, landward extension and seaward contraction, accompanied by Couette flow in the underlying salt. The effects of water: (i) increase solid and fluid pressures in the sediments; (ii) reduce the head to toe differential pressure in the salt and (iii) act as a buttress to oppose failure and translation of the sediment wedge. The magnitude of the translation velocity upon failure is reduced by the effects of water. The subsequent deformation is investigated using a 2D finite‐element model that includes the effects of the submarine setting and hydrostatic pore pressures. The model quantitatively simulates a 2D approximation of the evolution of natural sedimentary basins on continental margins that are formed above salt. Sediment progradation above a viscous salt layer results in formation of landward extensional basins and listric normal growth faults as well as seaward contraction. At a later stage, an allochthonous salt nappe overthrusts the autochthonous limit of the salt. The nature and distribution of major structures depends on the sediment properties and the sedimentation pattern. Strain weakening of sediment favours landward listric growth faults with formation of asymmetric extensional depocentres. Episodes of low sediment influx, with partial infill of depocentres, produce local pressure gradients in the salt that result in diapirism. Diapirs grow passively during sediment aggradation.     

Exploiting the archive: and the animals came in two by two, 16mm, CD-ROM and BetaSp

Summary Using an account of the construction and subsequent exploitation of the film archive at the BBC's Natural History Unit, this paper explores the ways in which animals are embedded in the different cultures of care, control and commodification in the zoo and the wildlife film-making unit. Network analysis is used to account for the similarities and tensions between these forms of animal exhibition, as revealed in the electronic zoo at Wildscreen World.     

Structure and evolution of mass transport deposits in the South Caspian Basin,Azerbaijan

The Quaternary to late Pliocene sedimentary succession along the margin of the South Caspian Basin contains numerous kilometre‐scale submarine slope failures, which were sourced along the basin slope and from the inclined flanks of contemporaneous anticlines. This study uses three‐dimensional (3D) seismic reflection data to visualise the internal structure of 27 mass transport deposits and catalogues the syndepositional structures contained within them. These are used to interpret emplacement processes occurring during submarine slope failure. The deposits consist of three linked structural domains: extensional, translational and compressive, each containing characteristic structures. Novel features are present within the mass transport deposits: (1) a diverging retrogression of the headwall scarp; (2) the absence of a conventional headwall scarp around growth stratal pinch outs; (3) restraining bends in the lateral margin; (4) a downslope increase in the throw of thrust faults. The results of this study shed light on the deformation that occurred during submarine slope failure, and highlight an important geological process in the evolution of the South Caspian Basin margin.