Geochemistry, K–Ar geochronology and Sr–Nd–Pb isotope compositions of pitchstone in Gohado, southwestern Okcheon Belt, South Korea

Abstract Geochemical and Sr–Nd–Pb isotope characteristics, as well as K–Ar geochronology of a massive pitchstone (volcanic glass) stock erupted into Late Cretaceous lapilli tuff and rhyolite in the Gohado area, southwestern Okcheon Belt, South Korea, are reported. The pitchstones are highly evolved with SiO₂ contents ranging from ～72 to 73 wt%, K₂O/Na₂O ratios of 1.04–1.23 and low MgO/FeO^t values (0.17–0.20). The pitchstones are weakly peraluminous and the ASI (molar Al₂O₃/Na₂O + K₂O + CaO) values are significantly lower than 1.1. The pitchstones also display a general calc‐alkaline nature with significant alkali contents. The rare earth elements (REE) compositions show moderately fractionated nature with (La/Yb)_N ranging from 11 to 16. Chondrite normalized REE patterns show relative enrichment of light REE over heavy REE and moderate Eu anomaly (Eu/Eu* ratio varies from 0.53 to 0.57). A distinct negative Nb anomaly is observed for all pitchstones on a primitive mantle normalized trace element diagram, typical of subduction‐related magmatism and crustal‐derived granites. All these features are characteristic of I‐type granites derived from a continental arc. The pitchstones have Zr contents of 98.5–103.5 ppm with zircon thermometry yielding temperatures of 749–755°C (mean 752°C). The K–Ar analyses of representative pitchstone samples yielded ages of 58.7 ± 2.3 and 62.4 ± 2.1 Ma with a mean age of 61 Ma. The rocks show nearly uniform initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of 0.7104–0.7106 and identical ¹⁴³Nd/¹⁴⁴Nd initial ratio of 0.5120. The rocks display negative εNd (61 Ma) values of ?12. The depleted mantle model ages (T_DM) range from 1.54 Ga to 1.57 Ga. The Pb isotope ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.522–18.552, ²⁰⁷Pb/²⁰⁴Pb = 15.642–15.680 and ²⁰⁸Pb/²⁰⁴Pb = 38.794–38.923. These ratios suggest that the Gohado pitchstones were formed in a continental arc environment by partial melting of a 1.54 Ga to 1.57 Ga parental sources of lower crustal rocks probably of mafic or intermediate compositions.     

Pyrite paragenesis and multiple sulfur isotope distribution in late Archean and early Paleoproterozoic Hamersley Basin sediments

The sulfur isotope record in late Archean and early Paleoproterozoic rocks is of considerable importance because it provides evidence for changes in early Earth atmospheric oxygen levels and potentially constrains the origin and relative impact of various microbial metabolisms during the transition from an anoxic to oxic atmosphere. Mass independently fractionated (MIF) sulfur isotopes reveal late Archean and early Paleoproterozoic sulfur sources in different pyrite morphologies in Western Australia's Hamersley Basin. Multiple sulfur isotope values in late Archean pyrite vary according to morphology. Fine grained pyrite has positive sulfur MIF, indicating a reduced elemental sulfur source, whereas pyrite nodules have negative sulfur MIF, potentially derived from soluble sulfate via microbial sulfate reduction. The Hamersley Basin δ³⁴S–Δ³³S record suggests that the extent of oxygenation of the surface ocean fluctuated through the Late Archean from at least 2.6 Ga, more than 150 million yr before the Great Oxidation Event. In the early Paleoproterozoic, there is less distinction between pyrite morphologies with respect to sulfur isotope fractionation, and pyrite from the Brockman Iron Formation trends toward modern sulfur isotope values. An important exception to this is the strong negative MIF recorded in layer parallel pyrite in Paleoproterozoic carbonate facies iron formation. This may suggest that deeper water hydrothermal environments remained anoxic while shallower water environments became more oxidised by the early Paleoproterozoic. The results of the current study indicate that sulfide paragenesis is highly significant when investigating Archean and early Paleoproterozoic multiple sulfur isotope compositions and sulfur sources.     

Investigation of CO2 behavior and study on design of optimal injection into Gorae-V aquifer

This study presents the Bottom-hole pressure (BHP) behavior with different wettabilities and the optimal design scheme to effectively inject CO₂ into the Gorae-V aquifer. As a result, the injection rate and injectivity were increased as the wettability condition became more water-wet. However, the more wettability condition becomes water-wet, the more the ultimate CO₂ injection volume decreases. When the injectivity was 346 ton/day/Mpa at the Gorae-V aquifer, the aquifer can sustain CO₂ injection at a rate of 2,425 tons per day over this time period. A design for a complete CCS system was developed based on the existing off-shore pipeline in combination with new on-shore CO₂ transport infrastructure, and a pressure of 12.8 MPa is required at the CO₂ source to maintain this injection rate.     

CO2 exchange at air-sea interface in the Huanghai Sea

INTRODUCTIONTheroleoftheoceaniscrucialintheoverallcycleofCOZ,withitsspecialpumpingmechanismssuchassolubilitypumpingattheair-seainterfacewithcarbonatechemistry,biologicalpumpinginsurfacewatersandalsointhewatercolumn,anddynamicpumpingassociatedwithoceancirculation(BroeckerandPeng,1982).Inordertounderstandthesevariouspumpingprocessesintheocean,muchresearchhasbeencarriedoutonaglobalscaleasapartofeffortstounderstandtheglobalgeochemicalcycleofCOZ.TheHuanghaiSea,atypicalmid-latitudeepicontine…     

Estimation of turbulent sensible heat and momentum fluxes over a heterogeneous urban area using a large aperture scintillometer

The accurate determination of surface-layer turbulent fluxes over urban areas is critical to understanding urban boundary layer (UBL) evolution. In this study, a remote-sensing technique using a large aperture scintillometer (LAS) was investigated to estimate surface-layer turbulent fluxes over a highly heterogeneous urban area. The LAS system, with an optical path length of 2.1 km, was deployed in an urban area characterized by a complicated land-use mix (residential houses, water body, bare ground, etc.). The turbulent sensible heat (Q H) and momentum fluxes (τ) were estimated from the scintillation measurements obtained from the LAS system during the cold season. Three-dimensional LAS footprint modeling was introduced to identify the source areas ("footprint") of the estimated turbulent fluxes. The analysis results showed that the LAS-derived turbulent fluxes for the highly heterogeneous urban area revealed reasonable temporal variation during daytime on clear days, in comparison to the land-surface process-resolving numerical modeling. A series of sensitivity tests indicated that the overall uncertainty in the LAS-derived daytime Q H was within 20%-30% in terms of the influence of input parameters and the non-dimensional similarity function for the temperature structure function parameter, while the estimation errors in τ were less sensitive to the factors of influence, except aerodynamic roughness length. The 3D LAS footprint modeling characterized the source areas of the LAS-derived turbulent fluxes in the heterogeneous urban area, revealing that the representative spatial scales of the LAS system deployed with the 2.1 km optical path distance ranged from 0.2 to 2 km2 (a "micro-α scale"), depending on local meteorological conditions.     

Determining the seasonality of groundwater recharge using water isotopes: a case study from the upper North Han River basin,Korea

The stable isotopes of oxygen and hydrogen were used to determine the seasonal contributions of precipitation to groundwater recharge at a forested catchment area in the upper North Han River basin, Korea. A comparison of the stable isotopic signatures of groundwater and precipitation indicates that the precipitations which occurred during both the dry and rainy seasons are the important source of groundwater recharge in this region. A stable isotopic signature shown in the stream waters at the upstream reaches is similar to that of groundwaters, indicating that stream waters are mostly fed by groundwater discharge. Reservoir waters in the downstream flood control dams have lower deuterium excess values or d-values compared with those of the upstream waters, indicating a secondary evaporative enrichment. These results can provide a basis for the effective management of groundwater and stream water resources in the North Han River basin.     

Influence of the total atmospheric optical depth and cloud cover on solar irradiance components

Broadband solar irradiance data obtained in the spectral range 400–940 nm at Kwangju, South Korea from 1999–2000 have been analyzed to investigate the effects of cloud cover and atmospheric optical depth on solar radiation components. Results from measurements indicate that the percentage of direct and diffuse horizontal components of solar irradiance depend largely on total optical depth (TOD) and cloud cover. During summer and spring, the percentages of diffuse solar irradiance relative to the global irradiance were 5.0% and 4.9% as compared to 2.2% and 3.0% during winter and autumn. The diffuse solar irradiance is higher than the direct in spring and summer by 24.2%, and 40.6%, respectively, which may largely be attributed to the attenuation (scattering) of radiation by heavy dust pollution and large cloud amount. In cloud-free conditions with cloud cover ≤2/10, the fraction of the direct and diffuse components were 66.0% and 34.0%, respectively, with a mean daily global irradiance value of 7.92±2.91 MJ m⁻² day⁻¹. However, under cloudy conditions (with cloud cover ≥8/10), the diffuse and direct fractions were 97.9% and 2.2% of the global component, respectively. The annual mean TOD under cloudless conditions (cloud cover≤2/10) yields 0.74±0.33 and increased to as much as 3.15±0.67 under cloudy conditions with cloud amount ≥8/10. An empirical formula is derived for estimating the diffuse and direct components of horizontal solar irradiance by considering the total atmospheric optical depth (TOD). Results from statistical models are shown for the estimation of solar irradiance components as a function of TOD with sufficient accuracy as indicated by low standard error for each solar zenith angle (SZA).     

Regime interplay: the case of biodiversity and climate change

In this paper, the interplay between the biodiversity and climate change regimes is examined in the context of a case study. An understanding of how the regimes interact is crucial to their successful operation, since it provides insight into how policy options might be drawn up to create synergy rather than conflict among the respective regimes’ objectives. Despite the increasing importance of the study of regime interplay, due to its potential influence on regime effectiveness, there is limited understanding of why regimes interact and how their interplay may affect their successful operation, since few empirical studies have been conducted in this area. By analysing the causes of the regime interplay and the potential effects thereof, this paper draws policy implications regarding how the interacting regimes might be better co-ordinated to create synergy.