Distribution, characterization, and geochemical controls of elements of concern in uranium mine tailings, Key Lake, Saskatchewan, Canada

The distribution of As, Mo, Ni and Se in the aqueous and solid phases of U mine tailings in the Deilmann Tailings Management Facility (DTMF), located at the Key Lake mine in northern Saskatchewan, Canada, was defined using as-discharged tailings samples collected monthly starting in 1996 and core samples collected from the DTMF from 3 locations on 3 occasions between 2004 and 2009. These data indicated that the DTMF can be divided into two geochemical zones; tailings generated from the Deilmann ore body between 1996 and 2000 and tailings from the McArthur River ore body, mined after July 2000. The Deilmann tailings solids are generally characterized by greater elemental concentrations than those in the McArthur River tailings, particularly for As, Co and Ni. These elevated concentrations are attributed to the abundance of Ni–Co–As–S minerals in this ore. The mean aqueous concentrations of As, Mo, Ni, and Se are 3.7, 23.2, 0.14, and 0.02 mg L⁻¹, respectively, in the Deilmann porewaters and 0.20, 4.16, 0.06, and 0.03 mg L⁻¹, respectively, in the McArthur River porewaters. Similarly, the mean As, Mo, Ni, and Se solid phase concentrations are 5.89 × 10³, 69.9, 3.20 × 10³, and 17.4 μg g⁻¹, respectively, for the Deilmann tailings and 440, 13.6, 551, and 3.03 μg g⁻¹ in the McArthur River tailings. Statistically, pH remained unchanged from the time of discharge while Eh values have remained oxic with no significant change between the two tailings types over 15 a of residence time. Results from sequential extractions, thermodynamic modeling, and results of complimentary research indicated that ferrihydrite solubility is the dominant control on aqueous As concentrations and also plays a role in controlling dissolved Mo, Ni and Se.     

Colloidal arsenic composition from abandoned gold mine tailing leachates in Nova Scotia,Canada

Asymmetric-Flow Field-Flow Fractionation (AsFlFFF) coupled to an inductively coupled plasma-mass spectrometer (ICP-MS) was used to determine whether colloidal As exists in mine tailings from abandoned Au mine sites in Nova Scotia. Using this technique, the chemical composition and the size of the colloidal material was determined. Tailings samples were collected from the sites and leachates were analyzed. The resulting fractograms showed the presence of colloidal As. Arsenic co-elutes with Fe and Al suggesting that the As is associated with colloids containing these elements. The colloidal material present in the samples has a calculated median size of 7 nm. The leachates were also analyzed for totalAs, Fe and Al using ICP-MS. The colloidal fraction was determined to account for approximately 20% of the total dissolved As present in these samples. Dissolved As concentrations at the selected mine sites are very high and the arbitrary cutoff for dissolved still incorporates colloidal material. Therefore. it is important to distinguish between truly dissolved and colloidal As as the speciation will affect the toxicity and mobility of As at these locations.     

A parametric study on seakeeping assessment of fast ships in conceptual design stage

The paper presents an approach to investigate the effects of some parameters on seakeeping assessment of fast ships in conceptual design stage. Hull form parameters have been classified into two groups: main dimensions (L, B and T) and secondary form parameters (LCB and C_P). To demonstrate the approach a fast ship is redesigned as parent hull and alternative hull forms are generated by changing these parameters systematically. Some hull forms are selected related the geometric limits and seakeeping analyzes are here investigated and discussed. The obtained results are satisfactory for seakeeping predictions during the conceptual design stage.     

Geological evolution of the West Luzon Basin (South China Sea,Philippines)

Interpretation of deep 2-D multi-channel seismic data sheds insights into the geological evolution of the West Luzon Basin, Philippines. This basin is a sediment-filled trough that is located between the island of Luzon and the outer arc high of the west Luzon subduction zone. High-amplitude, low-frequency reflection bands mark the acoustic basement. The basement, at about 6 s (TWT), is dissected by normal faults with some of them being inverted in a later phase of deformation. The sedimentary successions, overlying the basement are stratified with partly chaotic structures and discontinuous reflectors. Five regional unconformities separate major stratigraphic units. Grid calculations of our seismic data reveal variations in the sedimentation pattern of the basin with a shift of the deposition centre from east to west and backwards during formation. A distinct bottom-simulating reflector is commonly observed. Because the northern boundary of the continental fragments to the South of the West Luzon Basin is unclear we speculate that the basin may be (partly) underlain by continental crust. The continental crust was affected by rifting prior to and during the opening of the South China Sea and the basin was overprinted at a later stage by a forearc structural setting when subduction was initiated.     

Barremian–Danian chemostratigraphic sequences of the Cauvery Basin,India: Implications on scales of stratigraphic correlation

Chemostratigraphic concepts postulate that distinct chemozones could be recognized from rock records to help correlate geographically separated strata. Many studies have upheld this view, but were limited to classic boundaries such as Cenomanian–Turonian or Cretaceous–Tertiary. Only a few elements and isotopic compositions were made use in such studies. An attempt to recognize chemozones of Barremian–Danian strata of the Cauvery Basin, South India through whole-rock chemistry had revealed many complex signals and depositional events as expressed by bulk geochemical profiles. The signals indicate major shift in sedimentation pattern from dynamic depocenter to stable depositional conditions during Santonian. Varying sensitivities of different elements towards prevalent depositional conditions are also inferred. Trends of geochemical composition indicated domination of single depositional control all through the depositional history, basinal configuration that limited terrestrial sediment source and episodic influx of detrital materials. Presence of distinct change in whole-rock geochemistry across geochronological and lithostratigraphic boundaries is deciphered through a statistical tool ANOVA. These results demonstrate that visual delineation of chemozones in a long ranging rock record would be tenuous and has to be exercised with caution.     

Zircon ages of late Palaeoproterozoic (ca. 1.72–1.70 Ga) extension-related granitoids in NE Rajasthan,India: Regional and tectonic significance

The Khetri region forms a late Palaeoproterozoic igneous–metamorphic complex in NE Rajasthan, India. Seven granitoid plutons of the Khetri complex have been studied for zircon U–Pb and Pb–Pb dating along with whole-rock and Nd–Sr isotope geochemistry to provide new constraints on the Palaeoproterozoic magmatic activity in the Aravalli orogen of northwestern India. Most intrusives show evidence of moderate to extreme albitisation forming microcline–albite granite and albite granite, respectively. The rocks are metaluminous to weakly peraluminous, largely ferroan and intraplate A-type granites. The U–Pb zircon ages for four plutons cover a time span of 1732–1682 Ma, whereas Pb–Pb zircon evaporation data for three intrusives indicate minimum emplacement ages between 1671 and 1537 Ma. The Nd–Sr isotopic systematics suggest the involvement of Neoarchaean to Palaeoproterozoic crustal components in the petrogenesis of these granitoids. A regional survey of late Palaeoproterozoic ages in the Aravalli orogen provides evidence for a geographically widespread extension-related event in the northwestern Indian shield about 1720–1700 Ma ago. The record of comparable ages and the magmatic history reported in parts of North America and the North China Craton may indicate the significance of this event for the rift tectonics of the hypothetical supercontinent Columbia.     

Stratigraphy and palaeoenvironment of the Lower-“middle” Oligocene units in the northern part of the Western Taurides (İncesu area,Isparta, Turkey)

This study describes the stratigraphic and palaeoenvironmental significance of the Lower-“middle” Oligocene sediments based on the fauna from the Delikarkas? Formation and the microflora from the ?ncesu Formation of the ?ncesu area (northern part of the western Taurides, Isparta province, Turkey). In the area, the Oligocene sediments show a regressive succession, which begins with the limestones of the Delikarkas? Formation indicating marine conditions followed by conglomerates, sandstones and coaly mudstones of alluvial and fluvial (shallow marine-continental) origin. A well preserved foraminiferal assemblage including Nummulites intermedius, Nummulites vascus and Halkyardia maxima proves an Early Oligocene age for the Delikarkas? Formation. Due to palynological markers such as Boehlensipollis hohli, Slowakipollis hippophaëoides, Dicolpopollis kockelii, Magnolipollis neogenicus ssp. minor, Plicapollis pseudoexcelsus, Caryapollenites simplex and Intratriporopollenites instructus the ?ncesu Formation, which concordantly rests on the Delikarkas? Formation, may be assigned to the Early-“middle” Oligocene. From the palynomorph assemblage, three zones have been recognised according to abundance of species. Zone 1 is characterized by predominance of C. simplex and Momipites punctatus and rarely presence of tricolpate and tricolporate pollen. Zone 2 consists mainly of Inaperturopollenites dubius, Leiotriletes maxoides ssp. maximus, Verrucatosporites favus, Verrucatosporites alienus and infrequently marine dinoflagellate cysts. Zone 3 is characterized by a high percentage of ferns such as Echinatisporis?chattensis and Polypodiaceoisporites saxonicus. The presence of marine dinoflagellate cysts like Apectodinium sp. and Cleistosphaeridium sp., back-mangrove elements such as Acrostichum aureum and lepidocaryoid palms (e.g. Longapertites discordis, Longapertites punctatus and Longapertites psilatus) in the sediments of the ?ncesu Formation imply coastal or near-coastal conditions. Terrestrial palynomorphs in more inland settings were transported by running water towards the sea. Conifers are represented by poorly preserved and rare pollen grains of Pityosporites, Cathayapollis and Piceapollis which may have been transported by wind. In this study, the terrestrial climate of the ?ncesu Formation is also discussed on the basis of the Coexistence Approach method. The climate was warm at the coast (over 20 °C), as evidenced by A. aureum and lepidocaryoid palms, whereas there was a mean annual temperature of 17.2–17.4 °C must be assumed for the upland environment(s).     

Lattice-preferred orientations of late-Variscan granitoids derived from neutron diffraction data: implications for magma emplacement mechanisms

The lattice-preferred orientation (LPOs) of two late-Variscan granitoids, the Meissen monzonite and the Podlesí dyke granite, were determined from high-resolution time-of-flight neutron diffraction patterns gained at the diffractometer SKAT in Dubna, Russia. The results demonstrate that the method is suitable for the LPO analysis of polyphase, relatively coarse-grained (0.1–6 mm) rocks. The Meissen monzonite has a prominent shape-preferred orientation (SPO) of the non-equidimensional minerals feldspar, mica and amphibole, whereas SPO of the Podlesí granite is unapparent at the hand-specimen scale. The neutron diffraction data revealed distinct LPOs in both granitoids. The LPO of the non-equidimensional minerals feldspar, mica and amphibole developed mainly during magmatic flow. In the case of the Meissen monzonite, the magmatic flow was superimposed by regional shear tectonics, which, however, had no significant effect on the LPOs. In both samples, quartz shows a weak but distinct LPO, which is atypical for plastic deformation and different in the syn-kinematic Meissen monzonite and the post-kinematic Podlesí granite. We suggest that, first of all, the quartz LPO of the Meissen monzonite is the result of oriented growth in an anisotropic stress field. The quartz LPO of the Podlesí granite, which more or less resembles a deformational LPO in the flattening field of the local strain field, developed during magmatic flow, whereby the rhombohedral faces of the quartz crystals adhered to the (010) faces of aligned albite and to the (001) faces of zinnwaldite. Due to shape anisotropy of their attachments, the quartz crystals were passively aligned by magmatic flow. Thus, magmatic flow and oriented crystal growth are the major LPO-forming processes in both granitoids. For the Meissen monzonite, the solid-state flow was too weak to cause significant crystallographic re-orientation of the minerals aligned by magmatic flow. Finally, the significance of our results for the evaluation of the regional tectonic environment during magma emplacement is discussed. The discussion on the regional implications of the more methodologically oriented results provides the basis for future, more regionally aimed studies in view of the fabric characteristics of such plutons and their developing mechanisms.     

Preface: Proceedings of the 5th International Symposium on Lithographic Limestone and Plattenkalk

Magmatic rocks from the pre-Mesozoic basements of the Sambuco and Maggia nappes have been dated by U–Pb zircon ages with the LA-ICPMS technique. Several magmatic events have been identified in the Sambuco nappe. The mafic banded calc-alkaline suite of Scheggia is dated at 540 Ma, an age comparable to that of mafic rocks in the Austroalpine Silvretta nappe. The Sasso Nero peraluminous augengneiss has an age of 480–470 Ma, like many other “older orthogneisses” in Alpine basement units. It hosts a large proportion of inherited zircons, which were dated around 630 Ma, a Panafrican age indicating the Gondwanan affiliation of the Sambuco basement. The calc-alkaline Matorello pluton yielded ages around 300 Ma, similar to numerous Late Carboniferous intrusions in other basement units of the Lower Penninic (Monte Leone, Antigorio, Verampio) and Helvetic domains (Gotthard and other External Crystalline Massifs). Associated lamprophyric dykes are slightly younger (300–290 Ma), like similar dykes sampled in gneiss blocks included in the sedimentary cover of the underlying Antigorio nappe (290–285 Ma). The Cocco granodiorite and Rüscada leucogranite, both intruding the basement of the neighbouring Maggia nappe, yielded ages of ca. 300–310 Ma, identical within errors to the age of the Matorello pluton. They are significantly older than former age determinations. This age coincidence, coupled with remarkable petrologic similarities between the Cocco and Matorello granodiorites, strongly suggests paleogeographic proximity of the Sambuco and Maggia nappes in Late Carboniferous times. In recent publications these two nappes have been interpreted as belonging to distinct Mesozoic paleogeographic domains: “European” for Sambuco and “Briançonnais” for Maggia, separated by the “Valais” oceanic basin. In this case, the similarity of the Matorello and Cocco intrusions would demonstrate the absence of any significant transcurrent movement between these two continental domains. Alternatively, according to a more traditional view, Sambuco and Maggia might belong to a single large Alpine tectonic unit.