Stratigraphy of late Quaternary estuarine deposits and amino acid stereochemistry of oyster shells beneath San Francisco Bay,California

The sequence of Quaternary deposits beneath the floor of San Francisco Bay includes four to seven noncontemporaneous estuarine units intercalated with alluvium and dune sand. Units L (0–10,000 B.P.), M (>40,000 B.P., probably ca. 80,000–140,000 B.P.), and N (older than unit M) are distinctly superposed. The dominant molluscan fossil in each of these three units is Ostrea lurida Carpenter, the native oyster along much of the pacific Coast of North America. Despite a lamellar structure that suggests vulnerability to contamination, O. lurida shells generally yield amino acid enantiomeric ratios that are analytically reproducible and stratigraphically consistent. The kinetics of racemization in O. lurida conceivably resembles that of Protothaca and Saxidomus, other bivalves whose kinetics of racemization are relatively well understood. Assuming such a resemblance, enantiomeric ratios in O. lurida imply that (1) unit M is the same approximate age as estuarine terrace deposits bordering San Pablo Bay and Carquinez Strait, providing that the terrace deposits have been at diagenetic temperatures 1°-2°C warmer than unit M; and (2) the age of unit N is about four times greater than that of unit M, providing that both units have been at the same approximate diagenetic temperature.     

Theoretical grain size limits for single-domain,pseudo-single-domain and multi-domain behavior in titanomagnetite (x = 0.6) as a function of low-temperature oxidation

A theoretical model of grain size variation of domain transitions in titanomagnetite (x = 0.6) as a function of oxidation (z) is presented. The superparamagnetic (SP) to single-domain (SD) transition d_s, the SD to two-domain (TD) transition d₀, the TD to three-domain (3D) transition and the pseudo-single domain (PSD) to multi-domain (MD) transition are calculated as a function of z. It is shown that all the transition grain sizes increase with z, except for the PSD-MD transition for z > 0.6. The calculations predict that d_s increases from 0.044 to 0.197 μm, d₀ increases from 0.54 to 13 μm, the TD-3D transition increases from 1.6 to 49 μm as z varies from 0 to 0.8. The PSD-MD transition increases from 42 μm at z = 0 to 150 μm at z = 0.6, whereas between z = 0.6 to z = 0.8, the PSD-MD transition decreases to 49 μm. Qualitatively, the model explains some of the trends in magnetic properties of submarine basalts with low-temperature oxidation. Quantitatively, the model does give reasonable estimates of the PSD-MD boundary and d₀, which are close to the experimental values for x = 0.6 and z = 0. Furthermore, the model predicts that psarks or two-domain grains could be the major contributors to the remanence of oxidized submarine pillow basalts.     

The effectiveness of trenches in reducing seismic motion

The effect of placing barriers in the travel path of P, SV and SH seismic waves has been studied using time-domain solutions of plane-strain finite element programs for two-dimensional crustal models. The wavefields considered propagate parallel to the free surface of an elastic medium consisting of a single layer over a halfspace. Barriers take the form of open-air trenches. Effects of damping are assessed by considering representative viscoelastic conditions. Computations are presented as the ratio of spectral energy observed at a point with the barrier system in place in the model to the spectral energy observed at the same point without the barrier system in the model. These spectral ratios are dependent upon the direction of wave propagation. The calculations brought to light the marked role of surficial layering and attenuation properties of the surface rocks or soils on the effectiveness of seismic trench barriers. Barrier models without these features cannot in general reliably predict seismic wavefields at the surface. In the range of cases studied, trench depth d rather than width is the most sensitive parameter. When the ratio d/λ, the ratio of trench depth to the wavelength of shear waves, is greater than about 0·6, power spectral ratios of 0·06 and less are found for SH waves and the vertical component of SV motion for frequencies of 4–6 Hz. By contrast, for frequencies less than 3–4 Hz, power spectral ratios from unity to about two and greater are observed, indicating amplification for the horizontal component of wave motion. Spectral ratios calculated at some locations in front of the barrier system show over two-fold amplification. Spectral ratios also change significantly with the relative location of the free surface observation point.     

The Tichka Massif,Morocco—an example of contemporaneous acidic and basic plutonism

The Tichka Massif is a shallowly emplaced, domal intrusion that has produced a thermal aurole in surrounding rocks. The interior of the massif consists of a series of leucocratic granitic, tear-shaped pods sorrounded by dioritic rocks that range in composition from gabbro to granodiorite. The orientation of the pods has a strong vertical component. Flow foliation is well-developed in the rocks that surround the pods, whereas foliation is poorly developed in the granite pods. Dikes of andesite emanate from dioritic rocks and crosscut the granite pods. These rock relationships indicate that a highly viscous granitic liquid (pods) coexisted with a less viscous, denser dioritic liquid. Differences in viscosities of the two magmas and low diffusion rates in the granite magma prevented mixing.     

Fluids in the lithosphere, 1. Experimentally-determined wetting characteristics of CO2H2O fluids and their implications for fluid transport, host-rock physical properties, and fluid inclusion formation

The equilibrium distribution of CO₂H₂O fluids in synthetic rock samples (principally dunite and quartzite) has been characterized by measurements of the dihedral wetting angle, θ, resulting from 5-day annealing periods at 950–1150°C and 1 GPa. For fluids in equilibrium with polycrystalline quartz, θ varies systematically from 57° for pure H₂O to 90° at X_CO2 0.9. Similarly, for San Carlos olivine, θ varies from 65° for pure H₂O to 90° at X_CO2 0.9. The addition of solutes (NaCl, KCl, CaF₂, Na₂CO₃) to H₂O causes a major decrease in θ in the quartz/fluid system (to values as low as 40°), but has no effect on fluid wetting in dunite. Reconnaissance experiments on other mono- and polymineralic aggregates indicate universally high wetting angles (θ 60°) in upper mantle assemblages and for CO₂ in felsic compositions. For diopside + H₂O, θ 80°, with large variation due to crystalline anisotropy. In no case does θ approach 0°, the condition necessary for fluid to be present along all grain boundaries.Because a value of θ greater than 60° precludes the existence of an interconnected fluid phase in a rock, our results have important implications not only for fluid transport but also for the physical properties of the bulk fluid/rock system. Any static fluid present in the upper mantle must exist as isolated pores located primarily at grain corners, and transport can occur only by hydrofracture. In the continental crust, aqueous fluids (especially saline ones) are likely to form an interconnected network along grain edges, thus contributing to high electrical conductivity and allowing the possibility of fluid transport by porous flow or surface energy-driven infiltration.     

Magnetic polarity stratigraphy of the Pleistocene section at Portland (Victoria), Australia

Three to seven oriented paleomagnetic samples were collected from 16 sites in the Nelson Bay and Bridgewater formations at Portland, Victoria, which contains the recently discovered Nelson Bay local fauna (L.F.). The entire section has reversed polarity. These results, along with Globorotalia truncatulinoides within the section, and the presence of underlying middle Pliocene-dated basalts, indicate that the Portland section, and the included Nelson Bay L.F., was deposited within the late Matuyama Chron between 1.66 and 0.73 myr ago. This represents the first well-documented pre-¹⁴C Pleistocene mammalian fauna in Australia calibrated in direct stratigraphic context with absolute dating methods. In addition, the reversed polarity for the Bridgewater Formation confirms the previous hypothesis that the depositional history of this beach-sand deposit is time-transgressive across the Brunhes-Matuyama boundary.     

Geochemical and strontium isotopic characteristics of parental Aleutian arc magmas: evidence from the basaltic lavas of Atka

Eighteen flows from a basal stratigraphic sequence on the Aleutian Island of Atka were analyzed for major elements, trace elements and initial ⁸⁷Sr/⁸⁶Sr ratios. Petrographically, these lavas contain abundant plagioclase (24–45%) and lesser amounts of olivine (<7%), magnetite and clinopyroxene phenocrysts. Compositionally, the lavas are high-alumina (20wt%) basalts (48–51 wt% SiO₂) with low TiO₂ (<1%) and MgO (<5%). Within the section, compositional variations for all major elements are quite small. While MgO content correlates with olivine phenocryst contents, no such relationship exists between the other oxides and phenocryst content. These lavas are characterized by 8–10 ppm Rb, high Sr (610–669 ppm), 308–348 ppm Ba and very constant Zr (23–29 ppm) and Sc (23–29 ppm) abundances. Ni and Cr display extremely large compositional ranges, 12–118 ppm and 12–213 ppm, respectively. No correlation exists between trace element concentrations and phenocryst contents. Strontium isotopic ratios show a small but significant range (0.70314–0.70345) and are slightly elevated with respect to typical MORB. No systematic correlation between stratigraphic position and petrography or geochemistry is evident. REE abundances measured on six samples are LREE enriched ((La/ Yb)_N = 2.20–2.81) and display similar chondrite normalized patterns. One sample has a slight positive Eu anomaly but the other lavas do not. Compared to other Aleutian basalts of similar silica content, these lavas are less LREE enriched and have lower overall abundances. The geochemical characteristics of these basalts suggest they represent true liquid compositions despite their highly porphyritic nature. Published phase relations indicate fractionation of a more MgO-rich magma could not have produced these lavas. The high Al₂O₃ and low MgO and compatible element abundances suggest a predominantly oceanic crustal source for parental high-alumina basalts.