Geochemistry of the Mesozoic regional basic dykes of western Dronning Maud Land,Antarctica

Regional dolerite dykes of Mesozoic age in western Dronning Maud Land are variable in both major and trace element composition and include picritic types (MgO>18 wt%). The range in incompatible element concentrations is considerable (e.g. Zr 40–478 ppm) and shows little correlation with MgO content. Both high-and low-Ti, Zr (HTZ and LTZ) magma types are present and there is a spread of compositions between these types. Major element oxide variations in dykes having MgO>10 wt% indicate that olivine and orthoyproxene fractionation occurred, presumably at an early high-pressure stage of magma evolution. Major element oxide variations in dykes having MgO<10 wt% indicate control by olivine and clinopyroxene. A minority of the more evolved dykes are compositionally similar to the nearby Kirwan basalts, but the majority cannot be related to the Kirwan basalts by any simple petrogenetic process as they contain higher concentrations of incompatible elements and have higher Mg-numbers. The HTZ Dronning Maud Land dolerites have incompatible trace element concentrations which are very similar to the HTZ basalt magma types of the Karoo of southern Africa with the exception of lower K and Rb in DML dolerites. The HTZ dolerites occur in the part of Dronning Maud Land which appears to have been tectonically stable since the Archaean and are not found to intrude the surrounding high-grade (about 1000 Ma) metamorphic rocks of the Sverdrup Group. These data provide qualified support for models which seek to relate spatially the HTZ Mesozoic basalt types of Gondwana to sources beneath stable Archaean cratons.     

Generation of critical stochastic earthquakes

A stochastic critical excitation is defined as that excitation with a given variance that maximizes the variance in the dynamic response of a system. A non-stationary filtered shot noise is used to develop a stochastic critical excitation model of an earthquake ground motion process, and the response statistics for a linear system are determined in both time and frequency domains. The sensitivity of response to several assumed earthquake pulse arrival rate functions is examined. Responses to recorded strong ground motion and to stochastic critical excitations with the same total energy are compared to assess the degree of conservatism in the procedure. An application of the procedure to seismic qualification of equipment is presented.     

Sedimentation, distribution and diagenesis of organic matter in a recent carbonate environment, Abu Dhabi, U.A.E.

In the modern hypersaline carbonate lagoon and sabkha sedimentary environments of Abu Dhabi (United Arab Emirates), three types of organic matter originate respectively from microbial mat, Avicennia mangrove, and Halodule lagoonal seagrass. The study of recent sedimentary processes and cross sections through the sabkha sediments lead to the definition of organo-sedimentary facies based on geochemical and sedimentological criteria. This permits the construction of an organo-sedimentary sequence which expresses the Holocene sedimentary record involving a transgressive and a regressive sequence. The various organic facies occur in both sequences.Heterogeneity within the individual organic facies reflects several factors, including sedimentation dynamics, mineral matrix, oxidation and reduction, and selective organic and mineral diagenesis. These parameters are discussed in terms of depositional environment and location within the organo-sedimentary sequence. Changes in distribution, quantity, and preservation potential of the buried organic matter are discussed in terms of sea level changes and sedimentary accretion rates.     

Gold and copper mineralization at the El Indio deposit, Chile

A Middle Tertiary volcanic belt in the High Andes of north-central Chile hosts numerous precious- and base-metal epithermal deposits over its 150 km north-south trend. The El Indio district, believed to be associated with a hydrothermal system in the late stages of development of a volcanic caldera, consists of a series of separate vein systems located in an area of 30 km² which has undergone intense argillic-sericitic-solfataric alteration. The majority of the known gold-copper-silver mineralization occurs within a structural block only 150 by 500 m in surface area, with a recognized vertical extent exceeding 300 m. This block is bounded by two high-angle northeast-trending faults oriented subparallel to the mineralized veins.Hypogene mineralization at El Indio is grouped into two main ore-forming stages: Copper and Gold. The Copper stage is composed chiefly of enargite and pyrite forming massive veins up to 20 m wide, and is accompanied by alteration of the wall rocks to alunite, kaolinite, sericite, pyrite and quartz. The Gold stage consists of vein-filling quartz, pyrite, native gold, tennantite and subordinate amounts of a wide variety of telluride minerals. Associated with this stage is pervasive alteration of the wall rocks to sericite, kaolinite, quartz and minor pyrophyllite. The transition from copper to gold mineralization is marked by the alteration of enargite to tennantite and by minor deposition of sphalerite, galena, huebnerite, chalcopyrite and gold. Mineral stability relations indicate that there was a general decrease in the activity of S₂ accompanied by variations in the activity of Te₂ during the Gold stage.Fluid-inclusion data show homogenization temperatures ranging from about 220 to 280°C, with salinities on the order of 3–4 eq. wt. % NaCl for the Copper stage. The Gold-stage inclusions indicate a similar range in homogenization temperatures, but significantly lower salinities (0.1–1.4 eq. wt. % NaCl). Fluid inclusions of transition minerals show a weak inverse relationship between homogenization temperatures (190–250°C) and salinities (3.4–1.4 eq. wt. % NaCl), which may represent mixing of hotter Gold-stage fluids with cooler late-Copper-stage fluids. No evidence of boiling was found in fluid inclusions, but CO₂ vapor-rich inclusions were identified in wall-rock quartz phenocrysts which pre-date copper and gold mineralization.Mineral stability calculations indicate that given a fairly restricted range of solution compositions, the Copper-, Transition- and Gold-stage minerals at El Indio could have been deposited from a single solution, with constant total dissolved sulfur which underwent reduction through time. Limited sulfur-isotope data indicates that pyrite from the Copper stage was not in isotopic equilibrium with Copper-stage alunite or Transition-stage sphalerite. The sulfur-isotope and fluid-inclusion data indicate that two fluids with comparable temperatures but different compositions flowed through the El Indio system. The earlier fluid deposited copper attended by sericite-alunite-kaolinite alteration, and later epithermal fluids deposited gold with quartz-sericite-kaolinite-pyrite alteration.     

Stable isotopes and cellulase activity as evidence for detritus as a food source for juvenile Gulf menhaden

Menhaden are one of the most abundant components of fish communities in Gulf and Atlantic estuaries. Juvenile menhaden have been reported to have zooplankton, phytoplankton, andSpartina-derived detritus in their guts. However, there has been disagreement over the importance of the detritus as a food source. We show, using physiological and stable isotope evidence, that detritus can be used by juvenile Gulf menhaden. Their diet is very roughly 30% detritus- and 70% plankton-based.     

Thorium sorption in the marine environment: Equilibrium partitioning at the hematite/water interface,sorption/desorption kinetics and particle tracing

Thorium(IV) sorption onto hematite (-Fe₂O₃) was examined as a function of pH and ionic strength. Sorption behaved Langmuirian over an eleven order of magnitude range in adsorption densities, : 10^–12 to 10^–1 moles Th sorbed per mole hematite sites, indicating that the overall free energy of Th adsorption is independent of adsorption density. Modeling of Th sorption was conducted with the Triple Layer Model of Davis and Leckie; reactions considered included solution-phase hydroxy and carbonato complexes of thorium, and carbonate/hematite surface complexes. The entire Th sorption isotherm can be modeled with a single surface complex formation reaction

Linear flow behaviour of matched joints – case study on standard JRC profiles

Roughness on rock joints produces a variable aperture across the joints and increases the flow path length. These conditions should be taken into account for a good approximation from cubic law. In this paper, the concept of local true aperture and tortuosity is applied to assumed joints where surfaces are matched to each other and correspond with standard Joint Roughness Coefficient (JRC) profiles. Furthermore, the hydraulic behaviour of JRC profiles is studied by a new laboratory experiment setup. The analytical approach provides new insights into the effects of roughness on hydraulic properties of rock joints. The results indicate that for a constant mechanical aperture, both the minimum local aperture and hydraulic aperture decrease with increasing JRC. Furthermore, tortuosity and standard deviation of local true aperture increase with JRC increment. The trend obtained between different parameters and JRC shows an obvious fluctuation for JRC lower than 10. On one hand, the results of this study along with a critical review of previous studies demonstrate that JRC profiles cannot present a precise roughness increment when JRC is less than 10. A new laboratory setup was designed to study the flow behaviour of JRC profiles. The results obtained from laboratory experiments under linear flow conditions validate the accuracy of the applied analytical method.