天然和人为地震活动性的对比研究

为了充分发挥现有的区域性、地方性数字地震台站在防震减灾中的作用，中国地震局地球物理研究所与美国达拉斯南卫理大学地球科学系合作开展“中美合作延庆一怀来盆地和海城地区天然和人为地震活动性的对比研究”。该合作项目以北京西北的延庆一怀来盆地与东北辽宁的海城地区作为流动地震观测试验场，计划在现有台网的基础上，在近震源与区域性的距离上布设15套由STS—2型宽频带数字地震仪组成的流动地震台网加密观测，以改善在区域性距离上台距过长、不利于分析、解释、研究所观测到地震记录的状况。2002年秋，双方在河北怀来一带首先架设了5个宽频带数字地震台并随即投入观测。到2003年3月上旬，中方又在预定地点架设了另5个宽频带数字地震台。目前，已建成的10个宽频带数字地震台仪器运行正常，运用已获得的研究区内天然和人为地震的高质量记录，合作双方按照计划开展了相关的研究工作。     

Triple-Hot-Film Anemometer Performance in Cases-99 and A Comparison With Sonic Anemometer Measurements

Two levels of triple-hot-film and sonic anemometers were deployed on a 5.5-m towerduring the Cooperative Atmospheric Surface Exchange Study (CASES-99) in October1999. Each triple-hot-film probe was collocated 50 mm from the sonic sensing path ona common boom. Various problems with using triple-hot-films in the atmosphere toresolve wind components are addressed including the derivation of a yaw angle correction using the collocated sensors. It was found that output voltage drift due to changes in environmental temperature could be monitored and corrected using an automated system. Non-unique solutions to heat transfer equations can be resolved using a collocated sonic anemometer. Multi-resolution decomposition of the hot-film data was used to estimate appropriate day and night averaging periods for turbulent flux measurements in and near the roughness sub-layer. Finally, triple-hot-film measurements of mean wind magnitude (M), turbulent kinetic energy (TKE), sensible heat flux (H), and local friction velocity (u_*) are compared to those of the collocated CSAT3 sonic anemometers. Overall, the mean wind magnitudes measured by the triple-hot-film and the collocated sonic sensorswere close, consistent and independent of stability or proximity to the ground. The turbulent statistics, TKE, u_*, and H, measured by the two sensor systems were reasonably close together at z = 5 m. However, the ratio of sonic measurement/hot-film measurement decreased toward the ground surface, especially during stable conditions.     

Lacaille 250 years on

Brian Warner , Department of Astronomy, University of Cape Town, tells the story of Nicolas Louis de Lacaille's sojourn in South Africa.
Two hundred and fifty years ago French astronomer Nicolas Louis de la Caille spent two years at the Cape of Good Hope, carrying out astronomical and geodetic observations that had long-lasting repercussions. His measurements of the positions of nearly 10 000 southern stars led to the definition of the southern constellations which are used to this day; his discrepant measurement of the radius of the Earth provided a challenge that took much 19th-century labour to rectify, but led to an accurate trigonometric survey of South Africa that would otherwise not have occurred until much later.     

Impacts of hydrological changes on phytoplankton succession in the Swan River, Western Australia

The Swan River estuary, Western Australia, has undergone substantial hydrological modifications since pre-European settlement. Land clearing has increased discharge from some major tributaries roughly 5-fold, while weirs and reservoirs for water supply have mitigated this increase and reduced the duration of discharge to the estuary. Nutrient loads have increased disproportionately with flow and are now approximately 20-times higher than pre-European levels. We explore the individual and collective impacts of these hydrological changes on the Swan River estuary using a coupled hydrodynamic-ecological numerical model. The simulation results indicate that despite increased hydraulic flushing and reduced residence times, increases in nutrient loads are the dominant perturbation producing increases in the incidence and peak biomass of blooms of both estuarine and freshwater phytoplankton. Changes in salinity associated with altered seasonal freshwater discharge have a limited impact on phytoplankton dynamics.     

Off-Line and On-Line Determination of Eleven Rare Earth Elements in Silicate Rocks by ICP-AES Using Dowex Minicolumns for Separation of Interfering Elements in Continuous Flow Systems

The methodologies developed in this work comprise ion-exchange separation of interfering elements from rare earth elements (Fe, Al and Ca), by using resin minicolumns (Dowex-50W-X8 200-400 mesh) for the determination of La, Ce, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb and Lu by inductively coupled plasma-atomic emission spectrometry, using both off-line and on-line continuous flow systems. These methods can be used to determine rare earth elements in common silicate rocks, such as granite, basalt, rhyolite and andesite. Thirteen geochemical reference materials were used to evaluate the accuracy and precision of the off-line and on-line methods. Chondrite-normalized diagrams were obtained and compared to values reported in the literature. When compared to conventional procedures, the proposed methods provide fast and low cost rare earth elements determinations in the analysis of silicate rocks. Eighteen samples per hour could be analysed by the proposed method using the automated procedure for the determination of the eleven rare earth elements.     

Inter-mineral Fe isotope variations in mantle-derived rocks and implications for the Fe geochemical cycle

Iron isotope and major- and minor-element compositions of coexisting olivine, clinopyroxene, and orthopyroxene from eight spinel peridotite mantle xenoliths; olivine, magnetite, amphibole, and biotite from four andesitic volcanic rocks; and garnet and clinopyroxene from seven garnet peridotite and eclogites have been measured to evaluate if inter-mineral Fe isotope fractionation occurs in high-temperature igneous and metamorphic minerals and if isotopic fractionation is related to equilibrium Fe isotope partitioning or a result of open-system behavior. There is no measurable fractionation between silicate minerals and magnetite in andesitic volcanic rocks, nor between olivine and orthopyroxene in spinel peridotite mantle xenoliths. There are some inter-mineral differences (up to 0.2‰ in ⁵⁶Fe/⁵⁴Fe) in the Fe isotope composition of coexisting olivine and clinopyroxene in spinel peridotites. The Fe isotope fractionation observed between clinopyroxene and olivine appears to be a result of open-system behavior based on a positive correlation between the Δ⁵⁶Fe_{clinopyroxene-olivine} fractionation and the δ⁵⁶Fe value of clinopyroxene and olivine. There is also a significant difference in the isotopic compositions of garnet and clinopyroxene in garnet peridotites and eclogites, where the average Δ⁵⁶Fe_{clinopyroxene-garnet} fractionation is +0.32 ± 0.07‰ for six of the seven samples. The one sample that has a lower Δ⁵⁶Fe_{clinopyroxene-garnet} fractionation of 0.08‰ has a low Ca content in garnet, which may reflect some crystal chemical control on Fe isotope fractionation. The Fe isotope variability in mantle-derived minerals is interpreted to reflect subduction of isotopically variable oceanic crust, followed by transport through metasomatic fluids. Isotopic variability in the mantle might also occur during crystal fractionation of basaltic magmas within the mantle if garnet is a liquidus phase. The isotopic variations in the mantle are apparently homogenized during melting processes, producing homogenous Fe isotope compositions during crust formation.     

Experimental constraints on Fe isotope fractionation during magnetite and Fe carbonate formation coupled to dissimilatory hydrous ferric oxide reduction

Iron isotope fractionation between aqueous Fe(II) and biogenic magnetite and Fe carbonates produced during reduction of hydrous ferric oxide (HFO) by Shewanella putrefaciens, Shewanella algae, and Geobacter sulfurreducens in laboratory experiments is a function of Fe(III) reduction rates and pathways by which biogenic minerals are formed. High Fe(III) reduction rates produced ⁵⁶Fe/⁵⁴Fe ratios for Fe(II)_aq that are 2-3‰ lower than the HFO substrate, reflecting a kinetic isotope fractionation that was associated with rapid sorption of Fe(II) to HFO. In long-term experiments at low Fe(III) reduction rates, the Fe(II)_aq-magnetite fractionation is −1.3‰, and this is interpreted to be the equilibrium fractionation factor at 22°C in the biologic reduction systems studied here. In experiments where Fe carbonate was the major ferrous product of HFO reduction, the estimated equilibrium Fe(II)_aq-Fe carbonate fractionations were ca. 0.0‰ for siderite (FeCO₃) and ca. +0.9‰ for Ca-substituted siderite (Ca_0.15Fe_0.85CO₃) at 22°C. Formation of precursor phases such as amorphous nonmagnetic, noncarbonate Fe(II) solids are important in the pathways to formation of biogenic magnetite or siderite, particularly at high Fe(III) reduction rates, and these solids may have ⁵⁶Fe/⁵⁴Fe ratios that are up to 1‰ lower than Fe(II)_aq. Under low Fe(III) reduction rates, where equilibrium is likely to be attained, it appears that both sorbed Fe(II) and amorphous Fe(II)(s) components have isotopic compositions that are similar to those of Fe(II)_aq.The relative order of δ⁵⁶Fe values for these biogenic minerals and aqueous Fe(II) is: magnetite > siderite ≈ Fe(II)_aq > Ca-bearing Fe carbonate, and this is similar to that observed for minerals from natural samples such as Banded Iron Formations (BIFs). Where magnetite from BIFs has δ⁵⁶Fe >0‰, the calculated δ⁵⁶Fe value for aqueous Fe(II) suggests a source from midocean ridge (MOR) hydrothermal fluids. In contrast, magnetite from BIFs that has δ⁵⁶Fe ≤0‰ apparently requires formation from aqueous Fe(II) that had very low δ⁵⁶Fe values. Based on this experimental study, formation of low-δ⁵⁶Fe Fe(II)_aq in nonsulfidic systems seems most likely to have been produced by dissimilatory reduction of ferric oxides by Fe(III)-reducing bacteria.     

Geochemical processes in the Onyx River, Wright Valley, Antarctica: Major ions, nutrients, trace metals

We present data on major ions, nutrients and trace metals in an Antarctic stream. The Onyx River is located in Wright Valley (77-32 S; 161-34 E), one of a group of ancient river and glacier-carved landforms that comprise the McMurdo Dry Valleys of Antarctica. The river is more than 30 km long and is the largest of the glacial meltwater streams that characterize this relatively ice-free region near the Ross Sea. The complete absence of rainfall in the region and the usually small contributions of glacially derived tributaries to the main channel make this a comparatively simple system for geochemical investigation. Moreover, the lack of human impacts, past or present, provides an increasingly rare window onto a pristine aquatic system.For all major ions and silica, we observe increasing concentrations with distance from Lake Brownworth down to the recording weir near Lake Vanda. Chemical weathering rates are unexpectedly high and may be related to the rapid dissolution of ancient carbonate deposits and to the severe physical weathering associated with the harsh Antarctic winter. Of the nutrients, nitrate and dissolved reactive phosphate appear to have quite different sources. Nitrate is enriched in waters near the Lower Wright Glacier and may ultimately be derived from stratospheric sources; while phosphate is likely to be the product of chemical weathering of valley rocks and soils. We confirm the work of earlier investigations regarding the importance of the Boulder Pavement as a nutrient sink.Dissolved Mn, Fe, Ni, Cu, and Cd are present at nanomolar levels and, in all cases, the concentrations of these metals are lower than in average world river water. We hypothesize that metal uptake and exchange with particulate phases along the course of the river may serve as a buffer for the dissolved load. Concurrent study of these three solute classes points out significant differences in the mechanisms and sites of their removal from the Onyx River.