Mississippi Valley-type lead–zinc deposits through geological time: implications from recent age-dating research

Remarkable advances in age dating Mississippi Valley-type (MVT) lead-zinc deposits provide a new opportunity to understand how and where these deposits form in the Earth's crust. These dates are summarized and examined in a framework of global tectonics, paleogeography, fluid migration, and paleoclimate. Nineteen districts have been dated by paleomagnetic and/or radiometric methods. Of the districts that have both paleomagnetic and radiometric dates, only the Pine Point and East Tennessee districts have significant disagreements. This broad agreement between paleomagnetic and radiometric dates provides added confidence in the dating techniques used. The new dates confirm the direct connection between the genesis of MVT lead-zinc ores with global-scale tectonic events. The dates show that MVT deposits formed mainly during large contractional tectonic events at restricted times in the history of the Earth. Only the deposits in the Lennard Shelf of Australia and Nanisivik in Canada have dates that correspond to extensional tectonic events. The most important period for MVT genesis was the Devonian to Permian time, which corresponds to a series of intense tectonic events during the assimilation of Pangea. The second most important period for MVT genesis was Cretaceous to Tertiary time when microplate assimilation affected the western margin of North America and Africa-Eurasia. There is a notable paucity of MVT lead-zinc ore formation following the breakup of Rodinia and Pangea. Of the five MVT deposits hosted in Proterozoic rocks, only the Nanisivik deposit has been dated as Proterozoic. The contrast in abundance between SEDEX and MVT lead-zinc deposits in the Proterozoic questions the frequently suggested notion that the two types of ores share similar genetic paths. The ages of MVT deposits, when viewed with respect to the orogenic cycle in the adjacent orogen suggest that no single hydrologic model can be universally applied to the migration of the ore fluids. However, topographically driven models best explain most MVT districts. The migration of MVT ore fluids is not a natural consequence of basin evolution; rather, MVT districts formed mainly where platform carbonates had some hydrological connection to orogenic belts. There may be a connection between paleoclimate and the formation of some MVT deposits. This possible relationship is suggested by the dominance of evaporated seawater in fluid inclusions in MVT ores, by hydrological considerations that include the need for multiple-basin volumes of ore fluid to form most MVT districts, and the need for adequate precipitation to provide sufficient topographic head for topographically-driven fluid migration. Paleoclimatic conditions that lead to formation of evaporite conditions but yet have adequate precipitation to form large hydrological systems are most commonly present in low latitudes. For the MVT deposits and districts that have been dated, more than 75% of the combined metal produced are from deposits that have dates that correspond to assembly of Pangea in Devonian through Permian time. The exceptional endowment of Pangea and especially, North America with MVT lead-zinc deposits may be explained by the following: (1) Laurentia, which formed the core of North America, stayed in low latitudes during the Paleozoic, which allowed the development of vast carbonate platforms; (2) intense orogenic activity during the assembly of Pangea created ground preparation for many MVT districts through far-field deformation of the craton; (3) uplifted orogenic belts along Pangean suture zones established large-scale migration of basin fluids; and (4) the location of Pangea in low latitudes with paleoclimates with high evaporation rates led to the formation of brines by the evaporation of seawater and infiltration of these brines into deep basin aquifers during Pangean orogenic events.     

Secondary flows in the lee of porous shelterbelts

The results of wind-tunnel experiments indicate that the flow close to the surface behind shelterbelts is quite sensitive to the orientation of the barrier to the mean flow direction, and that orientation is more important for short than long windbreaks. The implications of these findings are discussed in the context of field experiments to validate mathematical models of shelter effects.     

Stable lead isotopes reveal a natural source of high lead concentrations to gasoline-contaminated groundwater

Concentrations of total lead as high as 1,600 g/L were detected in gasoline-contaminated and uncontaminated groundwater at three gasoline-release sites in South Carolina. Total lead concentrations were highest in turbid groundwater samples from gasoline-contaminated and uncontaminated wells, whereas lower turbidity groundwater samples (collected using low-flow methods) had lower total lead concentrations. Dissolved lead concentrations in all wells sampled, however, were less than 15 g total lead/L, the current United States Environmental Protection Agency (US EPA) maximum contaminant level (MCL). Because many total lead concentrations exceeded the MCL, the source of lead to the groundwater system at two of the three sites was investigated using a stable lead isotope ratio approach. Plots of the stable isotope ratios of lead (Pb) in groundwater as ²⁰⁷Pb/²⁰⁶Pb versus ²⁰⁸Pb/²⁰⁶Pb, and ²⁰⁸Pb/²⁰⁴Pb versus ²⁰⁶Pb/²⁰⁴Pb were similar to ratios characteristic of lead-based minerals in local rocks of the southeastern US, and were not similar to the stable lead isotopes ratios characteristic of distant lead ore deposits such as Broken Hill, Australia, used to produce tetraethyl lead in gasoline products prior to its phase-out and ban in the United States. Moreover, the isotopic composition of dissolved lead was equivalent to the isotopic composition of total lead in turbid samples collected from the same well, suggesting that the majority of the lead detected in the groundwater samples was associated with sediment particulates of indigenous aquifer material, rather than lead associated with spilled leaded gasoline. The results of this investigation indicate that (1) lead detected at some gasoline-release sites may be derived from the local aquifer material, rather than the gasoline release, and consequently may affect site-specific remediation goals; (2) non-low flow groundwater sampling methods, such as a disposable bailer, may result in turbid groundwater samples and high total lead concentrations, and; (3) stable lead isotopes can be used to clarify the source of lead detected above permissible levels in gasoline-contaminated groundwater systems.     

Cosmogenic nuclide chronology of pre-last glacial maximum moraines at Lago Buenos Aires, 46°S, Argentina

At Lago Buenos Aires, Argentina, ¹⁰Be, ²⁶Al, and ⁴⁰Ar/³⁹Ar ages range from 190,000 to 109,000 yr for two moraines deposited prior to the last glaciation, 23,000–16,000 yr ago. Two approaches, maximum boulder ages assuming no erosion, and the average age of all boulders and an erosion rate of 1.4 mm/10³ yr, both yield a common estimate age of 150,000–140,000 yr for the two moraines. The erosion rate estimate derives from ¹⁰Be and ²⁶Al concentrations in old erratics, deposited on moraines that are >760,000 yr old on the basis of interbedded ⁴⁰Ar/³⁹Ar dated lavas. The new cosmogenic ages indicate that a major glaciation during marine oxygen isotope stage 6 occurred in the mid-latitude Andes. The next five youngest moraines correspond to stage 2. There is no preserved record of a glacial advance during stage 4. The distribution of dated boulders and their ages suggest that at least one major glaciation occurred between 760,000 and >200,000 yr ago. The mid-latitude Patagonian glacial record, which is well preserved because of low erosion rates, indicates that during the last two glacial cycles major glaciations in the southern Andes have been in phase with growth and decay of Northern Hemisphere ice sheets, especially at the 100,000 yr periodicity. Thus, glacial maxima are global in nature and are ultimately paced by small changes in Northern Hemisphere insolation.     

Long-term patterns of solar irradiance forcing in model experiments and proxy based surface temperature reconstructions

Comparisons are made of long-term empirical and model-estimated patterns of solar irradiance forcing during a 200-year period (1650-1850), which precedes any apparent anthropogenic influence on climate. This interval encompasses a considerable range (approximately 4 W/m²) of estimated variation in solar output, including the "Maunder" and "Dalton" Minima of solar irradiance, and an intervening interval of relatively high values of irradiance, but does not encroach into the industrial era wherein it is difficult to separate solar and anthropogenic influences. Particular emphasis is placed on comparing empirical and modeled patterns of forced surface temperature variation. The empirical patterns bear a greater similarity to the pattern of forced response of a coupled ocean-atmosphere general circulation model (AOGCM) than with an independent model simulation result using an ocean with specified heat transport, both in terms of the spatial pattern of response and implied global mean sensitivity to forcing. Heightened sensitivity in the western Pacific warm pool apparent in the empirical response pattern, is not observed in the forced response of the coupled model. It is possible that this pattern is the result of feedback processes not currently reproduced in course-resolution coupled models. The greatest empirical response is found at the multidecadal-to-century (> 40 year period) time scale, for which the forcing is dominated by the roughly 90-year Gleissberg Cycle of irradiance. This indicates a global-mean sensitivity (approximately 0.3 K/W/m²), which is close to the coupled model result (approximately 0.4 K/W/m²). At decadal time scales (8-25 year period), for which the forcing is dominated by the 11-year and 22-year period solar cycles), the temperature sensitivity is moderately reduced, and its spatial pattern of response is dominated by an apparent resonance with known decadal modes of climate variability.     

Assessment of natural attenuation of aromatic hydrocarbons in groundwater near a former manufactured-gas plant, South Carolina, USA

 Shallow, anaerobic groundwater near a former manufactured-gas plant (MGP) in Charleston, South Carolina, USA, contains mono- and polycyclic aromatic hydrocarbons (MAHs and PAHs, respectively). Between 1994 and 1997, a combination of field, laboratory, and numerical-flow and transport-model investigations were made to assess natural attenuation processes affecting MAH and PAH distributions. This assessment included determination of adsorption coefficients (K _ad ) and first-order biodegradation rate constants (K _bio ) using aquifer material from the MGP site and adjacent properties. Naphthalene adsorption (K _ad =1.35×10^–7 m³/mg) to aquifer sediments was higher than toluene adsorption (K _ad =9.34×10^–10 m³/mg), suggesting preferential toluene transport relative to naphthalene. However, toluene and benzene distributions measured in January 1994 were smaller than the naphthalene distribution. This scenario can be explained, in part, by the differences between biodegradation rates of the compounds. Aerobic first-order rate constants of ¹⁴C-toluene, ¹⁴C-benzene, and ¹⁴C-naphthalene degradation were similar (–0.84, –0.03, and 0.88 day^–1, respectively), but anaerobic rate constants were higher for toluene and benzene (–0.002 and –0.00014 day^–1, respectively) than for naphthalene (–0.000046 day^–1). Both areal and cross-sectional numerical simulations were used to test the hypothesis suggested by these rate differences that MAH compounds will be contained relative to PAHs. Predictive simulations indicated that the distributions of toluene and benzene reach steady-state conditions before groundwater flow lines discharge to an adjacent surface-water body, but do discharge low concentrations of naphthalene. Numerical predictions were "audited" by measuring concentrations of naphthalene, toluene, and benzene at the site in early 1997. Measured naphthalene and toluene concentrations were substantially reduced and the areal extent of contamination smaller than was both observed in January 1994 and predicted for 1997. Measured 1997 benzene concentrations and distribution were shown to be relatively unchanged from those measured in 1994, and similar to predictions for 1997. Received: 26 June 1997 · Accepted: 25 August 1997     

A sample of 6C radio sources designed to find objects at redshift z > 4 — I. The radio data

We describe the selection of a sample of 34 radio sources from the 6C survey from a region of sky covering 0.133 sr. The selection criteria for this sample, hereafter called 6C*, were chosen to optimize the chances of finding radio galaxies at redshift z  > 4. Optical follow-up observations have already led to the discovery of the most distant known radio galaxy at z  = 4.41. We present VLA radio maps and derive radio spectra for all the 6C* objects.     

High-frequency earthquakes at White Island volcano, New Zealand: insights into the shallow structure of a volcano-hydrothermal system

Volcano-tectonic earthquakes at White Island are concentrated in a single seismically active zone, southeast of the active vents and at depths of less than 1 km. A few deeper earthquakes also occur beneath the active vents. A composite focal mechanism indicates that the stress regime in the shallow seismic zone is N-S extensional. Shallow seismicity occurs within the main volume of the volcano-hydrothermal system that underlies the Main Crater floor, and we interpret this as a region where the rocks have been weakened by past magmatic intrusions, elevated pore fluid pressure and physico-chemical effects of acid volcanic fluids, thereby allowing preferential seismic failure. Brittle seismic failure within this region requires a temperature less than about 400 °C, and implies high horizontal temperature gradients close to the active craters and fumaroles. Spasmodic bursts events are also a result of brittle failure, but occur close to zones of significant permeability in response to changes in local fluid pressure.