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101.
It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E4/E6 ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches. 相似文献
102.
Nishi Kant Prasoon Kumar Singh Bijendra Kumar 《Journal of the Geological Society of India》2018,91(1):67-75
This paper reports petrography, geochemistry and Rb-Sr age data on the rare metal bearing Neoarchean fertile (Nb-Ta) granite at Allapatna and elucidates its petrogenesis and role in Nb-Ta-Li-Be mineralization. The Allapatna granite (AG) intrudes the Tonalitic-Trondhjemitic - Granodioritic (TTG) Peninsular Gneiss and analysed SiO2 (72.3-75.6 wt%), K2O (4.0-5.7wt%), Na2O (3.0-4.4wt%), CaO (0.7-1wt%), MgO (0.13-0.25wt%) and K2O/Na2O (>1) indicating evolved nature. The presence of muscovite, biotite and garnet in the mode, peraluminous nature and high initial 87Sr/86Sr ratio (0.7284±0.0083) attest to their S-type characteristics. Varying Nb/Ta ratio and high Li with moderate abundance of Cs further indicate affinity to Li-Cs-Ta (LCT) type granite-pegmatite system. TheAG showing whole rock Rb-Sr isochron age of 2803± 68 Ma, is the oldest reported fertile granite in India parental to rare metal pegmatites hosting Nb-Ta, Be, and Li resources. Partial melting of a mixed source consisting of both basement TTG rocks and metapelites has generated such type of granitic magma. Fractionation of such granitic magma possibly has given rise to the rare metal (Ta-Nb-Li-Be) bearing pegmatites intruding the nearby schist belt. 相似文献
103.
随着气候变化和人类活动对水资源影响越来越显著,大量水文序列的统计规律不再满足一致性要求而出现了变异。水资源日益重要的社会地位,要求在对水文变异进行检测的同时,需进一步量化影响其变异的因素,但目前归因分析的研究仍以定性或半定量为主。由于降雨和径流是水循环中关键的水文要素,且分别可以反映气候变化和人类活动对水资源的影响,利用降雨-径流关系提出了定量研究水资源变异的归因分析方法。结合乌力吉木仁河三级区1956~2000的年径流和年降雨序列,在对其分别进行变异诊断的基础上,定量地分析了造成该区水文变异的原因。计算结果表明:气候变化对乌力吉木仁河三级区水资源变异的贡献率为24%,而人类活动影响的贡献率为76%,可见人类活动是造成该区水资源变异的主要因素。 相似文献
104.
Calcite was synthesized by four methods, and the luminescence decay-time was measured for nine samples before and after heating
hydrothermally in the temperature range 200–400°C. Decay-time data were collected between room temperature and approximately
15 K. The decay time at room temperature is approximately 50 ms, with little difference between a given calcite before and
after hydrothermal treatment. The decay time at 15 K is always greater than at room temperature as the effect of thermal quenching
diminishes. Differences in decay time before and after heating are more apparent at low temperature owing to this reduction
in thermal quenching. The decay time decreased significantly in two samples, and an increase in decay time was observed in
the remaining seven samples following heating. Among the latter group, the change in decay time was insignificant in three
samples. The results are compared with previous data in which it was shown that the effect of heating is to increase the intensity
of luminescence. 相似文献
105.
Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and 57Fe–58Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ56Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ56Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ57Fe?=?0.534?±?0.010, 2SE). 相似文献
106.
A careful selection of waste dumpsites, particularly hazardous ones, is very important for sustainable water resources management. Several laboratory experiments were carried out on the field samples to study adsorption capacity using p-dichlorobenzene (a solvent used in various industrial processes) as the test contaminant. The effect of parameters such as organic matter, clay, and iron and aluminium oxides, which are known to influence the soil adsorption capacity, are studied in the present work. Several soil samples from the Patancheru Industrial Area (Hyderabad, India) were collected and characterized. Only three soils, which had a comparatively high percentage of organic matter, clay, iron and aluminium oxide contents were used for the adsorption studies. The results clearly indicated a decrease in the adsorption capacity of the soils by as much as 75% when organic matter was removed. The other parameters such as clay and iron and aluminium oxides also play an important role in adsorption (57 and 39.8% reduction respectively). It was observed that out of the selected factors organic matter in the soils has the maximum effect regarding the adsorption of p-dichlorobenzene. Since the selected soils contain comparatively more organic matter, clay and iron and aluminium oxides in the selected industrial area, these can be used as sites for dumping hazardous waste, which can be further treated by methods like bioremediation. 相似文献
107.
磷对过铝质岩浆液相线温度影响的实验研究 总被引:1,自引:1,他引:1
以宜春414岩体中的钠长花岗岩作为实验初始物,利用"RQV-快速内冷淬火"高温高压装置实验研究了100MPa压力、含5%H2O条件下,P对过铝质花岗岩液相线温度的影响.实验结果表明,碱性长石是最早结晶的矿物;随着体系中P2O5含量从0.27%增加到7.71%,液相线温度从最初的810℃降低到740℃,表明P有效地降低了过铝质岩浆体系的液相线温度.在过铝质岩浆体系中,P5+与Al3+的结合形成AlPO4,降低了熔体中碱性长石组分的活度,很可能是液相线温度降低的机制. 相似文献
108.
Helmut Kerndorff Stephan Kühn Thomas Minden Dagmar Orlikowski Thomas Struppe 《Environmental Geology》2008,55(2):291-301
The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater
affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority
called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be
used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of
individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling
and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization
of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing
gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones. 相似文献
109.
François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481
Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO4 2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses. 相似文献
110.