基于五种油源的中重度风化溢油的常规鉴定指标的应用效果评估

本文利用采集于我国三大油田的五种原油样品开展了长达210天的溢油风化模拟实验,并依据相对偏差和重复性限数学分析法,进行溢油风化过程分析和诊断比值应用效果评估。研究结果表明:经过210天的风化,溢油鉴定诊断比值发生明显改变;其中来源于萜烷、甾烷和多环芳烃的诊断比值变化率要远低于正构烷烃,可用于中长期风化溢油鉴定。此外,研究发现,在这些有效诊断比值中有4个变化率较小,相对偏差低于5%,保持了较好的稳定性,更适合于重度风化溢油鉴定。     

基于单景高分辨率光学卫星遥感影像的浅海水下地形提取

本文基于海浪波折射现象和浅水波理论,提出了一种基于单景高分辨率光学遥感影像的浅海地形提取方法。首先,基于浅水波理论推导出适用于浅海区域的水深与海浪波长、频率的定量关系,针对近岸光学遥感图像复杂的海浪特征,讨论了两种海浪波长提取方法,即FFT方法和剖面线法。然后提出了基于长距离波长波动分析的海浪频率计算方法,解决了单景遥感影像的波浪频率计算难题。最后,利用单景QuickBird高分辨率光学遥感影像,以海南岛三亚湾为研究区域进行了应用实验,结果表明,对12m以浅的浅海区域,在不需要任何辅助参数的情况下,反演获得了浅海地形(DEM),经与1:25000比例尺海图的水深对比验证,地形趋势吻合良好,反演水深的均方根误差为1.07m,相对水深误差为16.2%,表明该方法适合于浅海水下地形的提取,且具有无需实测水深数据和环境参数的支持的优点。     

北极秋季海冰密集度与中国初冬降雨之间的关系

本文通过对中国地区实测降水及北极海冰卫星数据的分析,研究了北极秋季海冰密集度与中国初冬降雨的关系。合成分析的研究结果表明2000年之前中国南方和北方冬季降水偏少,中部降水偏多,这之后中国南方和北方冬季降水增加,中部降水减少。SVD研究结果显示,北极海冰减少使得近三十年来中国南方和北方冬季降雨呈现逐渐增多,中部地区(从青藏高原向东北方向至日本)降雨逐步减少的趋势。随着北极海冰的进一步减少,如遇合适的气候条件,南方冻雨出现的概率会加大。北极秋季海冰异常的回复过程加之冬季海冰异常的延续信号在中国、蒙古及日本北部激发一个阻塞高压,以巴伦支海/卡拉海为中心激发一个异常低压。这使得来自北冰洋大西洋扇区的冷空气南下至欧洲大陆和亚洲北部,在阻塞高压的影响下,冷空气进一步南下,进入东亚地区。这不仅使得亚洲冬季温度降低,也为中国北部降水增加提供条件。     

天津市滨海新区芦苇湿地恢复适宜性评价

利用综合评价模型,结合地理信息系统技术的空间分析功能,以土地利用、土壤类型、坡度、降雨量和人类干扰活动作为评价因子,对天津滨海新区芦苇湿地恢复进行了适宜性评价。结果表明,较适宜开展湿地恢复的比例为21.46%,一般适宜比例为21.87%,不适宜比例占56.68%,其中较适宜湿地恢复的区域集中分布在北大港湿地自然保护区周边、独流减河下游、北塘入海口以及沿海滩涂,海河流域两侧也有零星分布。在适宜性评价基础上,对未来芦苇湿地恢复与建设的重点区域进行了成效预评估,芦苇对TC、TN、TP的年吸收通量约为1.3935×104、0.0258×104、0.0017×104t,能有效地减少入海排污压力和污染物对近岸海域环境质量的影响。研究结论可为天津湿地治理与生态恢复、土地利用结构调整、景观优化等提供理论依据和科学参考。     

Study of Influence of Regional Geodynamic Background on Strata Behaviors in China's Tongxin Mine

Strata behaviors are mainly affected by regional geodynamic background. The influence of rock mass stress and energy distribution on strata behaviors in the Tongxin mine is studied in terms of regional tectonic movement, seismic activity and tectonic stress field. The results show that the extrusion lifting movement of Kouquan fault adjacent to the Tongxin mine results in the stress concentration in the rock of the Carboniferous coal bed and accumulation of a large amount of elastic energy and forms structural background of Tongxin mine. Due to various seismic activities in the mine area, the strain energy is known to reach much higher levels, up to 0.5×10⁸ J^1/2. Since the stratigraphic structure is sensitive to the mining operation, the strain energy could cause strong strata behaviors. A special geological structure model of the Tongxin mine is established based on the geodynamic division method. The distribution of regional structure stress field is determined by the rock mass stress analysis system. Based on this model, Tongxin mine is divided into five areas with high stress, eight areas with low stress and eight areas with gradient stress. The strong strata behaviors mostly occur in high stress areas. These results could provide guidance to predict the strength of regional or mine pressure and control strata behavior in different areas.     

A new landslide-induced tsunami simulation model and its application to the 1792 Unzen-Mayuyama landslide-and-tsunami disaster

By combining landslide dynamics research and tsunami research, we present an integrated series of numerical models quantitatively simulating the complete evolution of a landslide-induced tsunami. The integrated model simulating the landslide initiation and motion uses measured landslide dynamic parameters from a high-stress undrained dynamic-loading ring shear apparatus. It provides the numerical data of a landslide mass entering and moving under water to the tsunami simulation model as the trigger of tsunami. The series of landslide and tsunami simulation models were applied to the 1792 Unzen-Mayuyama megaslide and the ensuing tsunami disaster, which is the largest landslide disaster, the largest volcanic disaster, and the largest landslide-induced tsunami disaster to have occurred in Japan. Both the 1792 megaslide and the tsunami portions of the disaster are well documented, making this an excellent test of the reliability and precision of the new simulation model. The simulated tsunami heights at the coasts well match the historical tsunami heights recorded by “Tsunami-Dome-Ishi” (a stone showing the tsunami reaching point) and memorial stone pillars.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

硫酸镁对仿刺参幼参麻醉效果的研究

本研究以硫酸镁作为麻醉剂,比较了在不同水温条件下硫酸镁对仿刺参幼参的麻醉效果,分析了不同浓度硫酸镁对仿刺参幼参的麻醉效果。实验水温设置11℃、13℃、15℃、17℃、19℃和21℃六个温度梯度,实验用仿刺参幼参规格分为大规格(L)40.26±1.84g、中规格(M)21.83±1.72g、小规格(S)11.03±1.63g。实验结果显示:1.在硫酸镁麻醉剂浓度相同时,仿刺参规格越大麻醉所需时间越长,复苏时间却越短;随着麻醉剂浓度增加,对仿刺参幼参麻醉时间相应缩短,但复苏时间呈现逐渐延长。不同浓度硫酸镁麻醉剂对不同规格仿刺参的麻醉效果具有显著差异(P0.05)。2.在水温11℃~20℃范围内,随着水温的升高,对仿刺参幼参的麻醉时间从26.13±17.78min缩短到21.47±3.52min,但复苏时间从26.13±17.78min增加到71.05±12.32min,不同水温条件下硫酸镁对仿刺参幼参麻醉效果影响显著(P0.05)。研究表明,仿刺参体重在20g以下的适宜麻醉浓度为0.1~0.25mol·L-1,体重在20g以上的适宜麻醉浓度为0.25~0.35mol·L~(-1)。     

赵各庄矿地下水位时间序列数字滤波分析

为了更好地了解煤矿地下水位的变化趋势,结合工程实例,运用递归和非递归2种滤波技术进行分析,通过对比2种滤波技术的滤波效果,可以得到地下水位的变化规律和成因机理。结果表明:滤波系数的调校对滤波效果的影响至关重要。根据平滑度指标、均方根误差和信噪比对现有观测数据进行计算的结果可知,当b=0.5时递归滤波效果相对较好,当q=5时非递归滤波效果相对较好。滤波结果可以作为预测未来该地区地下水位变化趋势的依据,也可以为安全生产提供参考。     

山东曹县地区土壤地球化学特征

山东省曹县地区土壤地球化学调查是按浅层土壤样品1点/4 km~2,深层土壤样品1点/16 km~2。测试N,P,K,Cu,Zn,B,Mo,Mn,F,As,Hg,Pb,Cr,Cd等14种指标。在统计这些指标的表层、深层土壤地球化学特征参数的基础上,对其与世界、全省同类参数的差异进行了分析,并分析了区内表层、深层土壤元素含量的相关性,认为该区表层土壤元素含量的显著特征是高F而低P,Zn,Mo。大部分元素在表层土壤中的含量继承了土壤母质的成分特征,但N,P,F,Hg等受人为活动和污染源的作用在表层土壤中明显富集。