Epikarst hydrology and implications for stalagmite capture of climate changes at Grotta di Ernesto (NE Italy): results from long‐term monitoring

Grotta di Ernesto is a cave site well suited for palaeoclimate studies because it contains annually laminated stalagmites and was monitored from 1995 to the end of 2008 for microclimate, hydrology and hydrochemistry. Long‐term monitoring highlighted that cave drips show three different hydrological responses to rainfall and infiltration: (1) fast seasonal drips in the upper part of the cave, which are mostly fed by fractures, (2) slow seasonal drips, located at mid‐depth in the cave characterized by mixed feeding and (3) slow drips, mostly located in the deeper gallery, which are fed by seepage flow from bulk porosity with a minor fracture‐fed component. The slow drips display daily cycles during spring thaw. Monitoring also indicated that drip waters are only slightly modified by degassing within the soil zone and aquifer and by prior calcite precipitation. Hydrochemical studies show a clear seasonality in calcite saturation index, which results in most cave calcite precipitation occurring during late autumn and winter with similar amounts of precipitated calcite on most stalagmites, regardless of drip rate (discharge) differences. Drip rate, and drip rate variability, therefore, has a minor role in modulating the amount of annual calcite formation. In contrast, drip rate, when associated with moderate reduction in calcite saturation index, clearly influences stalagmite morphology. Increasing drip rate yields a passage from candle‐, to cone‐ to dome‐shaped stalagmites. Very high drip rates feed speleothems with flowstone morphology. In summary, monitoring provides information about the karst aquifer and how hydrology influences those physical and chemical characteristics of speleothems which are commonly used as climate proxies. Copyright © 2010 John Wiley & Sons, Ltd.     

Biomarkers in sedimentary sulfides of precambrian age

Samples of the Mt Isa formation (Australia, c, 1.5 Ga), and the Shungit formation (U.S.S.R., c. 2.3 Ga) were studied by organic geochemical means. All samples were freed of any low-molecular-weight solvent soluble organic material in order to insure the authenticity of the analysed material. The isolation of biochemical compounds entrapped in sulfides was the major goal of this work.Organic compounds that were entrapped during the early stages of sulfide formation may obviously survive extended periods of time and can be released by a mild hydrogenation of the sulfides. Preliminary investigations of the hydrocarbon fraction indicate n-alkanes, monomethylalkanes, cycloalkanes, and an unknown series of branched alkanes as major constituents. Their distribution patterns show great selectivity with respect to structures and chain lengths of individual compounds. Differences between the hydrogenation reaction product and the sample extract may arise from the release of a different kind of lipid material through dissolution of the sulfides.     

Steroid and triterpenoid distributions in bransfield strait sediments: Hydrothermally-enhanced diagenetic transformations

Recent sediments from Bransfield Strait, Antarctica have been analyzed for triterpenoid and steroid hydrocarbons, sterols and steroid ketones to consider the effects of hydrothermal fluids on the sedimentary organic matter. The steroid distributions in unaltered and altered sediments are controlled more by inputs from source organisms than by the effects of hydrothermal activity, which is suggested to be limited to low temperature alteration. Nevertheless, chemical reactions occurred in altered sediments and include dehydration of sterols to sterenes, isomerization of triterpenes and sterenes, rearrangement of sterenes to diasterenes and reductive processes leading to generation of phytane from phytol via phytenes.     

A three dimensional perspective on the evolution of Archaean crust: LITHOPROBE seismic reflection images in the southwestern Superior province

15011993

Abstract

In 1990–1991 the LITHOPROBE project completed 450 km of seismic reflection profiles across the late Archaean crust of the southwestern Superior province. The results define a broad three-fold division of crust: upper crust in the Abitibi greenstone belt is non-reflective and is a 6–8 km veneer of volcanic and plutonic supracrustal rocks, whereas, in the sediment-gneiss dominated Pontiac subprovince, upper crust comprises shallow northwest-dipping turbidite sequences; mid-crust, in both the Abitibi and the Pontiac subprovinces, is interpreted as imbricate sequences of metasedimentary and metaplutonic rocks; lower crust in both subprovinces has a horizontal layer parallel strycture which may represent interleaved mafic-intermediate gneisses. The seismic signature of the northern Abitibi greenstone belt may be represented in an exposed 25 km crustal section in the Kapuskasing stuctural zone.

Preliminary tectonic models based on the seismic data are consistent with a plate-tectonic scenario involving oblique subduction and imbrication of sedimentary, plutonic and volcanic sequences. The northern Abitibi supracrustal sequences either represent an allochthon, or overlie an allochthonous underthrust metasedimentary and plutonic sequence which may be equivalent to a metasedimentary subprovince such as the Pontiac or Quetico.

Seismic velocities have yet to be defined. However, crustal thicknesses are relatively constant at 35–40 km. The thinnest crust is adjacent to the Grenville Front where Moho is very well defined.     

Land use and land transformation

Types and pattern of land use in the GDR are controlled both by the historical development and the strong influences of technological, social and political alterations during the last four decades. Owing to these factors and the favourable natural conditions the share of non-arable area is small. The two basic features of land transformation are land use alteration and intensification. Compared to other European countries the first process lies on the average. It is still remarkable because most alterations of land use drastically reduce the agricultural area. Intensification consequently is the main type of land transformation in all sections of regional development. In most cases the benefit of strong intensification serves to particular users. Therefore various by-effects arise like pollution, contamination, blocking and devastating of renewable natural resources. Under the auspices of long term rationalization land transformation must be accompanied by the development of a dense network of protective measures and reservation areas, and in addition by different types for multiple utilization of renewable natural resources. At present complicated systems of land use are in evolution.     

Organic geochemistry and pore water chemistry of sediments from Mangrove Lake,Bermuda

Mangrove Lake, Bermuda, is a small coastal, brackish-water lake that has accumulated 14 m of banded, gelatinous, sapropelic sediments in less than 10⁴ yr. Stratigraphic evidence indicates that Mangrove Lake's sedimentary environment has undergone three major depositional changes (peat, freshwater gel, brackish-water gel) as a result of sea level changes. The deposits were examined geochemically in an effort to delineate sedimentological and diagenetic changes. Gas and pore water studies include measurements of sulfides, ammonia, methane, nitrogen gas, calcium, magnesium, chloride, alkalinity, and pH. Results indicate that sulfate reduction is complete, and some evidence is presented for bacterial denitrification and metal sulfide precipitation. The organic-rich sapropel is predominantly algal in origin, composed mostly of carbohydrates and insoluble macromolecular organic matter called humin with minor amounts of proteins, lipids, and humic acids. Carbohydrates and proteins undergo hydrolysis with depth in the marine sapropel but tend to be preserved in the freshwater sapropel. The humin, which has a predominantly aliphatic structure, increases linearly with depth and composes the greatest fraction of the organic matter. Humic acids are minor components and are more like polysaccharides than typical marine humic acids. Fatty acid distributions reveal that the lipids are of an algal and/or terrestrial plant source. Normal alkanes with a total concentration of 75 ppm exhibit two distribution maxima. One is centered about n-C₂₂ with no odd/even predominance, suggestive of a degraded algal source. The other is centered at n-C₃₁ with a distinct odd/even predominance indicative of a vascular plant origin. Stratigraphic changes in the sediment correlate to observed changes in the gas and pore water chemistry and the organic geochemistry.     

PLL Tracking Performance in the Presence of Oscillator Phase Noise

The tracking performance of a Phase Lock Loop (PLL) is affected by the influence of several error sources. In addition to thermal noise and dynamic stress error, oscillator phase noise can cause significant phase jitter which degrades the tracking performance. Oscillator phase noise is usually caused by two different effects: Allan deviation phase noise is caused by frequency instabilities of the receiver's reference oscillator and the satellite's frequency standard. It can be termed as system-inherent phase noise and is relevant for both static and dynamic applications. “External” phase noise, however, is caused by vibration and is a major problem for dynamic applications. In the context of this paper, both types of phase noise will be modeled and the resulting integrals will be evaluated for PLLs up to the third order. Besides, phase jitter induced by thermal noise and signal dynamics will also be discussed, thus providing all necessary formulas for analyzing the performance of a phase lock loop in case of different forms of stress. Since the main focus is centered on the effects of oscillator phase noise, the overall PLL performance is graphically illustrated with and without consideration of oscillator phase noise. © 2002 Wiley Periodicals, Inc.     

0.99999999 confidence ambiguity resolution with GPS and Galileo

In this short contribution it is demonstrated how integer carrier phase cycle ambiguity resolution will perform in near future, when the US GPS gets modernized and the European Galileo becomes operational. The capability of ambiguity resolution is analyzed in the context of precise differential positioning over short, medium and long distances. Starting from dual-frequency operation with GPS at present, particularly augmenting the number of satellites turns out to have beneficial consequences on the capability of correctly resolving the ambiguities. With a 'double' constellation, on short baselines, the confidence of the integer ambiguity solution increases to a level of 0.99999999 or beyond. Electronic Publication     

Enhancing mobile applications by combination of GNSS and W-CDMA

The location requirements for emergency callers outside urban areas can hardly be fulfilled without global navigation satellite systems (GNSS). Consequently, interest in positioning techniques based on use of a GNSS such as GPS or on the cellular network infrastructure itself is growing rapidly in the mobile-telephone community. Moreover, the increasing demand for commercial location-based services (LBS) has driven cellular-phone and network manufacturers to focus on positioning solutions which are even more accurate than the regulatory mandates for positioning of emergency callers. One example of these upcoming LBS is our PARAMOUNT project, which aims at improving user-friendly info-mobility services for hikers and mountaineers by combining wireless communications (GMTS), satellite navigation (GNSS) and geographic information systems (GIS), based on a mobile client/server architecture. The availability of mobile phones or PDAs with combined GNSS and cellular network-based wireless communication on a high integration level is one primary demand of such LBS applications. Based on this, we will give some initial answers to the question of whether mobile handset architecture synergies exist for the combination of GNSS with wireless location in CDMA cellular wireless networks. In order to identify synergies, we will outline similarities and differences between wireless communication and satellite navigation. In this respect, we pay particular attention to the so-called RAKE receiver architecture employed in mobile CDMA cellular handsets. Our initial investigations will show that the RAKE receiver architecture, on which mobile CDMA cellular handsets are based, will most likely be the one most suitable for achieving synergies between the two positioning techniques within the same mobile handset architecture. Consequently, several receiver components could be used to handle both types of signals (navigation and communications), resulting in a reduction of manufacturing costs and in a decrease in energy consumption. Electronic Publication