Diurnal variations in,and influences on,concentrations of particulate and dissolved arsenic and metals in the mildly alkaline Wallkill River,New Jersey,USA

Diurnal variations in particulate and dissolved As and metal concentrations were observed in mildly alkaline water from a wetlands site on the Wallkill River in northwestern New Jersey. The site, underlain by glacial sediments over dolomite bedrock, is 10 km downstream from a mined area of the Franklin Marble, host to Zn ores, also As and Mn minerals. In mid-September 2005, maxima and minima in dissolved-oxygen-concentration and pH, typically caused by photosynthesis and respiration, occurred at 2000 and 0800 hours. Concentrations of dissolved As (1.52–1.95 μg/L) peaked at dusk (2000 hours), whereas dissolved Mn and Zn concentrations (76.5–96.9 and 8.55–12.8 μg/L, respectively) were lowest at dusk and peaked at 1000 hours. These opposing cycles probably reflect sorption and desorption of As (an anion), and Mn and Zn (cations) as pH varied throughout the 24-h period. Doubly-peaked cycles of B, Cl, SO₄, and nutrients also were observed; these may result from upstream discharges of septic-system effluent. Both recoverable amd particulate Al, Fe, Mn, and Zn concentrations peaked between 0200 and 0600 hours. The particulate metals cycle, with perturbations at 0400 hours, may be influenced by biological activity.     

Impact of AMD on water quality in critical watershed in the Hudson River drainage basin: Phillips Mine,Hudson Highlands,New York

A sulfur and trace element enriched U–Th-laced tailings pile at the abandoned Phillips Mine in Garrison, New York, releases acid mine drainage (AMD, generally pH < 3, minimum pH 1.78) into the first-order Copper Mine Brook (CMB) that drains into the Hudson River. The pyrrhotite-rich Phillips Mine is located in the Highlands region, a critical water source for the New York metro area. A conceptual model for derivation/dissolution, sequestration, transport and dilution of contaminants is proposed. The acidic water interacts with the tailings, leaching and dissolving the trace metals. AMD evaporation during dry periods concentrates solid phase trace metals and sulfate, forming melanterite (FeSO₄·7H₂O) on sulfide-rich tailings surfaces. Wet periods dissolve these concentrates/precipitates, releasing stored acidity and trace metals into the CMB. Sediments along CMB are enriched in iron hydroxides which act as sinks for metals, indicating progressive sequestration that correlates with dilution and sharp rise in pH when mine water mixes with tributaries. Seasonal variations in metal concentrations were partly attributable to dissolution of the efflorescent salts with their sorbed metals and additional metals from surging acidic seepage induced by precipitation.     

Relative inactivity during the last 140,000 years of a portion of the La Paz fault,southern Baja California Sur,Mexico

Uranium-series dating of corals overlying the undeformed Punta Coyote gravels indicates that the underlying La Paz fault zone has been relatively inactive in this part of the Baja California peninsula during the last 140,000 years, and possibly for a significantly longer period. However, Holocene seismic activities along extensions of the fault zone north of Cabo San Lucas suggest potential seismic hazards for the city of La Paz (population 200,000), which lies about 6 km from the fault.     

Profile of an Average Magnetic Cloud at 1 au for the Quiet Solar Phase: Wind Observations

Using WIND magnetic field (MFI) and plasma (SWE) data, an `average' profile of an interplanetary magnetic cloud was developed in terms of five physical (scalar) quantities based on appropriately selected individual clouds. The period of study was from early 1995 to late in 1998, primarily during the quiet part of a solar cycle. The physical quantities are: magnetic field magnitude, proton density, solar wind bulk speed, proton thermal speed, and proton plasma beta. Selection of the clouds was based on two considerations: (1) their `quality', determined objectively from the application of a static magnetic field model of cloud field structure, had to be good, and (2) distant spacecraft approaches from the cloud axes were not accepted. Nineteen clouds resulted out of 35 original cases. A superposed epoch analysis was performed on the 5 parameters generating summary profiles of a generic magnetic cloud at 1 AU. The density within the generic magnetic cloud reached a distinct minimum near the center and peaked in the trailing part (closest to Sun) after a slow rise. The individual clouds fall into two classes, those that have such an enhanced density feature (about of them) and those that have an overall nearly flat density profile. For the first 85% of the generic magnetic cloud the bulk speed decreased almost uniformly by 45 km s^–1 indicating marked expansion over 1 AU. The field intensity peaked very near the cloud's center but was noticeably asymmetric. Proton thermal speed was quite symmetric with local maxima at the front, center, and rear. Proton plasma beta was low throughout the cloud (0.12 on average), but had a broad minimum at its center. The relative degree of fluctuation level for the parameters ranged from the most quiet for both speed and field magnitude, to the most `noisy' for proton plasma beta, with fluctuations in density and thermal speed at intermediate levels, all being below 0.2, based on a sample-scale of frac1100 of the cloud duration. These profiles may be useful in constraining future structural and thermodynamic models of clouds with regard to their solar birth conditions and interplanetary evolution.     

Introduction of the mining royalty system in Hungary

The new mining act that becarne effective in Hungary in 1993 instituted the payment of royalties for the minerals produced and sold annually. To arrive at the amount of mineral production, the Hungarian Geological Survey (HGS) conducts the National Inventory, which is used by the Mining Bureau of Hungary (MBH) to verify the mining royalty payment obligations. This paper explains the major legal requirements for the mining royalties and how the values of the minerals are calculated. It also describes the first experience with the declaration and payment of the mining royalties and provides the declared and paid 1995 royalties. The Mining Bureau of Hungary reports on the introduction of the mining royalty system that became effective with the Mining Act in 1993. This article is sponsored by the U.S. Hungarian Science and Technology Joint Fund under Project Joint Fund Number 539.     

Implications of particle acceleration in active galactic nuclei for cosmic rays and high energy neutrino astronomy

We consider the production of high energy neutrinos and cosmic rays in radio-quiet active galactic nuclei (AGN) or in the central regions of radio-loud AGN. We use a model in which acceleration of protons takes place at a shock in an accretion flow onto a supermassive black hole, and follow the cascade that results from interactions of the accelerated protons in the AGN environment. We use our results to estimate the diffuse high energy neutrino intensity and cosmic ray intensity due to AGN. We discuss our results in the context of high energy neutrino telescopes under construction, and measurements of the cosmic ray composition in the region of the “knee” in the energy spectrum at 10⁷ GeV.     

Application of the gravimetric method for a world geodetic system

It is desirable to unify the various unconnected geodetic systems of the world into a common earth-centered world datum. This can be achieved by gravimetric means. The gravimetric deflection components have been determined at a certain number of stations in different areas. Utilizing the differences between the gravimetric and astro-geodetic deflection components, the reduction of the major geodetic datums into a common world geodetic system has been accomplished. Geophysical Studies Section Aeronautical Chart and Information Center Presented at the Twelfth General Assembly of the International Union of Geodesy and Geophysics Helsinki, Finland     

Occurrence and geochemistry of radium in water from principal drinking-water aquifer systems of the United States

A total of 1270 raw-water samples (before treatment) were collected from 15 principal and other major aquifer systems (PAs) used for drinking water in 45 states in all major physiographic provinces of the USA and analyzed for concentrations of the Ra isotopes ²²⁴Ra, ²²⁶Ra and ²²⁸Ra establishing the framework for evaluating Ra occurrence. The US Environmental Protection Agency Maximum Contaminant Level (MCL) of 0.185 Bq/L (5 pCi/L) for combined Ra (²²⁶Ra plus ²²⁸Ra) for drinking water was exceeded in 4.02% (39 of 971) of samples for which both ²²⁶Ra and ²²⁸Ra were determined, or in 3.15% (40 of 1266) of the samples in which at least one isotope concentration (²²⁶Ra or ²²⁸Ra) was determined. The maximum concentration of combined Ra was 0.755 Bq/L (20.4 pCi/L) in water from the North Atlantic Coastal Plain quartzose sand aquifer system. All the exceedences of the MCL for combined Ra occurred in water samples from the following 7 PAs (in order of decreasing relative frequency of occurrence): the Midcontinent and Ozark Plateau Cambro-Ordovician dolomites and sandstones, the North Atlantic Coastal Plain, the Floridan, the crystalline rocks (granitic, metamorphic) of New England, the Mesozoic basins of the Appalachian Piedmont, the Gulf Coastal Plain, and the glacial sands and gravels (highest concentrations in New England).