Differential biomagnification of PCB, PBDE, Hg and Radiocesium in the food web of the European hake from the NW Mediterranean

Consumption of marine organisms represents one of the main exposure sources of contaminants for human populations. To obtain a global view of the contamination in commercial fish in the NW Mediterranean Sea, we analysed four types of priority contaminants (PCBs, PBDEs, Hg and (137)Cs) in the European hake, Merluccius merluccius, from the Gulf of Lions in relation with organism's trophic level (δ(15)N). All contaminants presented a significant increase in concentration in hake muscle with trophic level. However, obvious differences between contaminants were evidenced. Biomagnification factors (BMF and FWMF) along the hake food web were higher for Hg and CB-153 than for BDE-47 and (137)Cs, and increase in contaminant concentration with trophic level occurred at different rates depending on contaminants. Such differences of biomagnification patterns can be related to physico-chemical properties of the different contaminants.     

Dependence of air pollution on meteorological conditions based on magnetic susceptibility measurements: a case study from Warsaw

This study reports systematic analysis of air pollution concentration by particulate matter (PM) in relation to annual changes of metrological conditions. The concentration of PM collected on filters was evaluated by magnetic properties. Long series of filters collected during 1977, 1980, 1981 and 1985 in Warsaw have been used for measurement. Such long time series allowed a better determination of correlation between seasonal susceptibility changes and meteorological conditions and to verify the repeatability of annual behavior. The magnetic susceptibility normalized by mass (??) has been used as a proxy of pollution. Monthly variations of ?? (??_m) demonstrated slow and small seasonal changes disturbed by quick, high peaks. The filters with high susceptibilities contain a mixture of magnetic single and multidomain grains which is characteristic for anthropogenic pollution, with the frequency-dependent susceptibility ??_fd being less than 4%. The low susceptibility samples are characterized by admixture of small amount of pseudo-single domain (PSD) and possible small amount of superparamagnetic (SP) grains. Detailed analysis of reduced mean monthly susceptibility ??_R revealed that temperature and absolute humidity correlate positively in cold period of year and negatively in warm months. The linear correlation coefficients range from 0.7 to 0.9 and from 0.3 to 0.4 for negative and positive linear correlation, respectively. The dispersion of pollutants in a city depends on the way of ventilation. The big cities like Warsaw are urban heat islands which act the most effective way for the warm period and for the cold time. The correlation of ??_R with absolute humidity is similar to that for temperature but for different reasons. The presence of big amount of water vapor particles in the atmosphere can favor the adhesion of smaller ferromagnetic grains to their surface which can accelerate the process of falling down of such agglomerates. Such a process can take place during wintertime. We do not observe clear correlation between ??_R and precipitation.     

Seismic Monitoring of Poland–Description and Results of Temporary Seismic Project with Mobile Seismic Network

The paper describes a temporary seismic project aimed at developing the national database of natural seismic activity for seismic hazard assessment, officially called “Monitoring of Seismic Hazard of Territory of Poland” (MSHTP). Due to low seismicity of Poland, the project was focused on events of magnitude range 1–3 in selected regions in order to maximize the chance of recording any natural event. The project used mobile seismic stations and was divided into two stages.Five-year measurements brought over one hundred natural seismic events of magnitudes M_L range 0.5–3.8. Most of them were located in the Podhale region in the Carpathians. Together with previously recorded events this made it possible to conduct a preliminary study on ground motion prediction equation for this region. Only one natural event, of magnitude M_L = 3.8, was recorded outside the Carpathians in a surprising location in central-west Poland.     

Assessment of the Global and Regional Land Hydrosphere and Its Impact on the Balance of the Geophysical Excitation Function of Polar Motion

The impact of continental hydrological loading from land water, snow and ice on polar motion excitation, calculated as hydrological angular momentum (HAM), is difficult to estimate, and not as much is known about it as about atmospheric angular momentum (AAM) and oceanic angular momentum (OAM). In this paper, regional hydrological excitations to polar motion are investigated using monthly terrestrial water storage data derived from the Gravity Recovery and Climate Experiment (GRACE) mission and from the five models of land hydrology. The results show that the areas where the variance shows large variability are similar for the different models of land hydrology and for the GRACE data. Areas which have a small amplitude on the maps make an important contribution to the global hydrological excitation function of polar motion. The comparison of geodetic residuals and global hydrological excitation functions of polar motion shows that none of the hydrological excitation has enough energy to significantly improve the agreement between the observed geodetic excitation and geophysical ones.     

Local‐ and regional‐scale biomorphodynamics due to tree uprooting in semi‐natural and managed montane forests of the Sudetes Mountains,Central Europe

In this work, direct and indirect geomorphic consequences of wind‐related tree uprooting are examined, using an extensive dataset from the mountain range of the Sudetes, Poland. The role of local conditions in influencing the geomorphic efficacy of tree uprooting is examined, as well as issues of upscaling individual observations from experimental sites. This problem is approached at a range of spatial and observational scales, from monitoring of root plate degradation over time through to examination of wind effects at a slope scale and region‐wide analysis. In our study area the mean root plate volume is between 0.4 and 4.2 m³ for spruce and 2.4 m³ for beech, and their degradation may last tens of years. The density of relict pit‐and‐mound microtopography varies from 2.7 up to 40 pairs per hectare and the maximum coverage of terrain is 4.7%. The volume of treethrow mounds varies from 0.5 to 3.1 m³ and mounds seem to outlive the pits formed in the same episode of disturbance. However, in specific lithological and topographic conditions, pit‐and‐mound topography does not form. The maximum biogenic transport attributable to a single windstorm event is c. 80 m³ ha^?1, while soil turnover times are calculated in the order of 1000–10 000 years. Rock fragment ‘mining’ is an important biogeomorphic process, both in terms of impact on hillslope surfaces and on soil properties. Gravel armours and small‐scale stepped topography may form instead of typical pit–mound associations in specific circumstances. Managed forests appear more prone to wind damage and associated geomorphic consequences. In the Sudetes Mountains, the variable role of tree uprooting in local and regional hillslope denudation is governed by forest stand structure, topography and regolith properties, with the former significantly influenced by human activity. Copyright © 2016 John Wiley & Sons, Ltd.     

SIMS Bias on Isotope Ratios in Ca‐Mg‐Fe Carbonates (Part III): δ18O and δ13C Matrix Effects Along the Magnesite–Siderite Solid‐Solution Series

This study explores the effects of cation composition on mass bias (i.e., the matrix effect), which is a major component of instrumental mass fractionation (IMF) in the microanalyses of δ¹³C and δ¹⁸O by SIMS in carbonates of the magnesite–siderite solid‐solution series (MgCO₃–FeCO₃). A suite of twelve calibration reference materials (RMs) was developed and documented (calibrated range: Fe# = 0.002–0.997, where Fe# = molar Fe/[Mg + Fe]), along with empirical expressions for regressing calibration data (affording residuals < 0.5‰ relative to certified reference material NIST‐19). The calibration curves of both isotope systems are non‐linear and have, over a 2‐year period, fallen into one of two distinct but largely self‐consistent shape categories (data from ten measurement sessions), despite adherence to well‐established analytical protocols for carbonate δ¹³C and δ¹⁸O analyses at WiscSIMS (CAMECA IMS 1280). Mass bias was consistently most sensitive to changes in composition near the magnesite end‐member (Fe# 0–0.2), deviating by up to 4.5‰ (δ¹³C) and 14‰ (δ¹⁸O) with increasing Fe content. The cause of variability in calibration curve shapes is not well understood at present and demonstrates the importance of having available a sufficient number of well‐characterised RMs so that potential complexities of curvature can be adequately delineated and accounted for on a session‐by‐session basis.     

Anisotropic Kepler and anisotropic two fixed centres problems

In this paper we show that the anisotropic Kepler problem is dynamically equivalent to a system of two point masses which move in perpendicular lines (or planes) and interact according to Newton’s law of universal gravitation. Moreover, we prove that generalised version of anisotropic Kepler problem as well as anisotropic two centres problem are non-integrable. This was achieved thanks to investigation of differential Galois groups of variational equations along certain particular solutions. Properties of these groups yield very strong necessary integrability conditions.     

Contribution of early impact events to metal‐silicate separation,thermal annealing,and volatile redistribution: Evidence in the Pułtusk H chondrite

Three‐dimensional X‐ray tomographic reconstructions and petrologic studies reveal voluminous accumulations of metal in Pu?tusk H chondrite. At the contact of these accumulations, the chondritic rock is enriched in troilite. The rock contains plagioclase‐rich bands, with textures suggesting crystallization from melt. Unusually large phosphates are associated with the plagioclase and consist of assemblages of merrillite, and fluorapatite and chlorapatite. The metal accumulations were formed by impact melting, rapid segregation of metal‐sulfide melt and the incorporation of this melt into the fractured crater basement. The impact most likely occurred in the early evolution of the H chondrite parent body, when post‐impact heat overlapped with radiogenic heat. This enabled slow cooling and separation of the metallic melt into metal‐rich and sulfide‐rich fractions. This led to recrystallization of chondritic rock in contact with the metal accumulations and the crystallization of shock melts. Phosphorus was liberated from the metal and subsumed by the silicate shock melt, owing to oxidative conditions upon slow cooling. The melt was also a host for volatiles. Upon further cooling, phosphorus reacted with silicates leading to the formation of merrillite, while volatiles partitioned into the residual halogen‐rich, dry fluid. In the late stages, the fluid altered merrillite to patchy Cl/F‐apatite. The above sequence of alterations demonstrates that impact during the early evolution of chondritic parent bodies might have contributed to local metal segregation and silicate melting. In addition, postshock conditions supported secondary processes: compositional/textural equilibration, redistribution of volatiles, and fluid alterations.     

Long-term evolution of Baltic Sea wave climate near a coastal segment in Poland; its drivers and impacts

The paper analyses long-term variability of wave climate near Poland for the 1958–2002 period. With spectral and cross-spectral analysis, linear regression and singular spectrum analysis the modes of long-term variability were quantified for the most energetic months (November–February). For monthly indices of North Atlantic Oscillation from 1950 until 2006, it was established that the long-term trends of NAO and significant wave height demonstrate a gentle coupling. For Januaries this relationship is strongest and dates back to 1960, for Februaries a certain consistency appears since 1975. For Novembers and Decembers no statistically discernible coupling was found. Thus, the Baltic Sea appears to be the easternmost NAO-affected region, despite its separation from the Atlantic. The hydrodynamic variability also includes a non-trivial oscillation in the January wave energy records with T=8 years. The same periodicity was identified with the multi-channel SSA technique in the long-term shoreline data of a neighboring beach. The study shows that even almost entirely isolated water bodies are becoming exposed to global climatic phenomena and accelerated erosion of sandy beaches, typical for the South Baltic region. On the other hand, the 8-year hydrodynamic cycle can be viewed as the driver of long-term shoreline evolution.     

Health risk assessment related to an effect of sample size fractions: methodological remarks

Contents of As, Cd, Co, Cr, Cu, Ni, Pb and Zn were determined in the material collected in sandboxes of seven spa resorts located in S Poland (CCE) and their results used to establish a health risk of children. After sieving out grains > 2 mm, the bulk samples were quantitatively separated into four grain fractions: 2000–1000, 1000–200, 200–63 and < 63 µm. In each of them were determined: the mineral composition, the total contents of the elements, and the distribution of the elements among the fractions distribution factor. In the bulk material < 2 mm, the totals of the elements are 5–64 times lower than in the finest fractions (< 63 µm). Considering that the finest fractions are enriched in clay minerals such as clinochlore, illite and kaolinite, which can adsorb and desorb metals, this material is most dangerous for children, staying both permanently and temporarily in the spas. The total health risks HI resulting from non-carcinogenic elements present in the fractions < 63 µm are 1.26 and 0.94, for the children-residents 3 and 6 years old, respectively. The figures are disturbing as one of them exceeds and the other is close to a permissible limit of 1. The highest contribution (93.4%) into the total HI is caused by inadvertent swallowing the soil “dirt”: the ingestion path HQ _ing for the 3 years old residents is 1.17, and for the 6-year olds 0.88. With respect to the elements, the highest is the risk resulting from Pb: HQ _in values of the residents are 4.71E−01 and 3.54E−01 for the 3-year olds and the 6-year olds. Slightly lower are the HQ _ing values calculated for both age groups: in the case of Cr—3.12E−01 and 2.34E−01 and As—2.92E−01 and 2.19E−01). The dermal path (HQ _dermal ) contributes to the total HI much less as it equals 6.5%, while the contribution of the inhalation path (HQ _inhal ) is considerably the lowest and equals only 0.1%. The Risk indexes determined in the case of cancerogenic components for both age groups of the spa residents are lower than the permissible limit 10E−5 and equal 6.48E−06 and 9.72E−06, respectively. Considering the children that only visit the spas, all the calculated indexes, i.e., HI and Risk, are significantly lower than those determined for the children-residents.