Early Carboniferous (Viséan) emplacement of the collisional Kłodzko–Złoty Stok granitoids (Sudetes, SW Poland): constraints from geochemical data and zircon U–Pb ages

Sensitive high-resolution ion microprobe zircon U–Pb dating and geochemical data of igneous rocks from the composite K?odzko–Z?oty Stok (KZS) Granite Pluton, Sudetic Block, indicate that the granitoids represent an Early Carboniferous Viséan phase of Variscan metaluminous, high-K, I-type, syn-collisional granite magmatism within the Saxothuringian Zone of the Central European Variscides. Igneous zircon records hypabyssal magmatism that produced various granitoids and lamprophyre (spessartite) emplaced from ca. 340 to 331 Ma. The KZS granitoids have compositions ranging from granodiorite to monzonite, low A/CNK ratios (<1), and are associated with abundant mafic members. Most of them are alkaline, highly potassic, and moderately evolved. The major and trace element contents of the KZS granitoids suggest geochemical heterogeneity, and the hybrid nature of magmas derived from a range of sources in the middle crust, with a strong input of material from the upper mantle. Mixing of magmas of mantle origin with high-K material from partly melted continental crust was probably a more important factor than fractional crystallization, in controlling the evolution of the magmas. The mean Pb–U ages of the main population of igneous zircon from a quartz monzodiorite (?elazno) and hornblende monzonite (Droszków) are 340.2 ± 2.5 Ma and 339.5 ± 3.1 Ma, respectively. A slightly younger biotite-hornblende granodiorite from Chwalis?aw, 336.7 ± 2.5 Ma, was cut by a spessartite dyke at 333.1 ± 3.1 Ma. This indicates that mafic magmas were immediately intruded into fractured, probably incompletely solidified, granodiorites. The lamprophyric dyke also contains igneous zircon of Neoproterozoic age, 566.3 ± 6.4 Ma, typical of the crust in the Saxothuringian Zone. Tonalite from Ptasznik Hill near Droszków is of similar age to the spessartite, 331.5 ± 2.6 Ma. High REE contents in the tonalite and its igneous zircon indicate advanced differentiation of granitic magma, producing a more leucocratic melt associated with post-magmatic activity including abundant late crosscutting pegmatites and quartz veins, and contact metasomatic mineralization. The KZS granitoids have rather similar petrographic and geochemical characteristics to granitoids from other parts of the Central European Variscides, where a thickened orogenic root caused a substantial rise in crustal temperatures, producing granitoid magmas closely correlated with regional tectonic activity between the Saxothuringian and Brunovistulia Terranes at the NE margin of the Bohemian Massif.     

Systematic Methodology for Velocity-dependent Gravity Modelling of Density Crustal Cross-Sections, using an Optimization Procedure

The paper describes a new method of gravity modelling of the density cross section along a DSS profile. We propose a systematic procedure of gravity interpretation using structural information contained both in the velocity distribution of the seismic model and the geometry of its layers. The procedure is based on the optimisation of the density parameters of the model. The values of the parameters are limited by relationships between the seismic velocity and the density (optimisation with inequalities). The formulation of the method allows for discussion of the presence of isostasy and the distribution of compensating masses. The discussion is very important for the considered crust-lithosphere system. The presented calculations are done for one Carpathian profile (CEL01). The analysis of the properties of the fitting procedure provides the characteristic depth of subcrustal compensating density structures, the position of crucial tectonic boundaries along the profiles, locations of the crustal areas having exceptional lithology, the regional density differences of subcrustal matter and the estimation of regional deviations from the isostatic equilibrium.     

Comparison of source parameters estimated in the frequency and time domains for seismic events at the Rudna copper mine,Poland

Source parameters estimated in the frequency domain for 100 selected seismic events from the Rudna copper mine, with moment magnitude ranging from 1.4 to 3.6, were collected to study their scaling relations and to compare them with the parameters estimated in the time domain. The apparent stress and static stress drop, corrected for the limited bandwidth recording, increase slightly in a similar manner with increasing seismic moment. The ratio of apparent stress to static stress drop, a measure of radiation efficiency, is practically constant and its mean value is close to 0.1. For 37 seismic events, with moment magnitude between 1.9 and 3.4, source parameters were estimated in the time domain from relative source time functions, that displayed unilateral rupture propagation, and their rupture velocity could be estimated. It ranges from 0.23 to 0.80 of shear wave velocity and is almost independent of seismic moment. The fault length, estimated from the average source pulse width and rupture velocity, is clearly dependent on seismic moment and is smaller than the source radius estimated from the corner frequency on the average by about 25 percent. There is no correlation between the values of static stress drop estimated in the frequency and time domains, but the time domain stress drop is in general similar to that estimated in the frequency domain. The apparent stress increases with increasing rupture velocity, and the ratio of apparent stress to static stress drop seems also to depend on rupture velocity.     

A high‐resolution Lateglacial and Holocene palaeoceanographic record from the Greenland Sea

We present an unprecedented multicentennial sediment record from the foot of Vesterisbanken Seamount, central Greenland Sea, covering the past 22.3 thousand years (ka). Based on planktic foraminiferal total abundances, species assemblages, and stable oxygen and carbon isotopes, the palaeoenvironments in this region of modern deepwater renewal were reconstructed. Results show that during the Last Glacial Maximum the area was affected by harsh polar conditions with only episodic improvements during warm summer seasons. Since 18 ka extreme freshwater discharges from nearby sources occurred, influencing the surface water environment. The last major freshwater event took place during the Younger Dryas. The onset of the Holocene was characterized by an improvement of environmental conditions suggesting warming and increasing ventilation of the upper water layers. The early Holocene saw a stronger Atlantic waters advection to the area, which began around 10.5 and ended quite rapidly at 5.5 ka, followed by the onset of Neoglacial cooling. Surface water ventilation reached a maximum in the middle Holocene. Around 3 ka the surface water stratification increased leading to subsequent amplification of the warming induced the North Atlantic Oscillation at 2 ka.     

Deglacial to postglacial palaeoenvironments of the Celtic Sea: lacustrine conditions versus a continuous marine sequence

Recent work on the last glaciation of the British Isles has led to an improved understanding of the nature and timing of the retreat of the British?Irish Ice Sheet (BIIS) from its southern maximum (Isles of Scilly), northwards into the Celtic and Irish seas. However, the nature of the deglacial environments across the Celtic Sea shelf, the extent of subaerial exposure and the existence (or otherwise) of a contiguous terrestrial linkage between Britain and Ireland following ice retreat remains ambiguous. Multiproxy research, based on analysis of 12 BGS vibrocores from the Celtic Deep Basin (CDB), seeks to address these issues. CDB cores exhibit a shell‐rich upward fining sequence of Holocene marine sand above an erosional contact cut in laminated muds with infrequent lonestones. Molluscs, in situ Foraminifera and marine diatoms are absent from the basal muds, but rare damaged freshwater diatoms and foraminiferal linings occur. Dinoflagellate cysts and other non‐pollen palynomorphs evidence diverse, environmentally incompatible floras with temperate, boreal and Arctic glaciomarine taxa co‐occurring. Such multiproxy records can be interpreted as representing a retreating ice margin, with reworking of marine sediments into a lacustrine basin. Equally, the same record may be interpreted as recording similar conditions within a semi‐enclosed marine embayment dominated by meltwater export and deposition of reworked microfossils. As assemblages from these cores contrast markedly with proven glaciomarine sequences from outside the CDB, a glaciolacustrine interpretation is favoured for the laminated sequence, truncated by a Late Weichselian transgressive sequence fining upwards into fully marine conditions. Reworked rare intertidal molluscs from immediately above the regional unconformity provide a minimum date c. 13.9 cal. ka BP for commencement of widespread marine erosion. Although suggestive of glaciolacustrine conditions, the exact nature and timing of laminated sediment deposition within the CDB, and the implications this has on (pen)insularity of Ireland following deglaciation, remain elusive.     

High‐precision U–Pb age and duration of the latest Devonian (Famennian) Hangenberg event,and its implications

Precise U–Pb zircon dates from three volcanic ash beds that bracket the Hangenberg Shale in the Holy Cross Mountains, Poland, constrain the age and duration of one of the most significant palaeobiological events of the Palaeozoic Era, the Hangenberg Event. It is linked to a terminal Devonian global shift from greenhouse to icehouse climate conditions, a global transgression, and widespread black shale deposition. Our results constrain the Hangenberg Event to between 358.97 ± 0.11 Ma and 358.89 ± 0.20 Ma, with a calculated duration of 0.05 +0.14/?0.05 Ma. A third, underlying ash bed yielded a distinctly older age of 359.97 ± 0.46 Ma. The duration of ~50–100 ka. for the event is comparable to those of Quaternary glaciations, and is consistent with both a glacio‐eustatic origin for the eustatic fluctuations and changes in ocean chemistry that led to this major reorganization of the biosphere.     

Coupled Reactive Transport Modeling of Redox Processes in a Nitrate-Polluted Sandy Aquifer

The reactive transport modeling of a complicated suite of reactions apparent in the aquifer during the application of N-containing fertilizers is reported. The unconfined sandy aquifer can be subdivided into an oxic zone which contains groundwater with oxygen and nitrate and an anoxic zone characterized by elevated iron and sulfate concentrations in groundwater. Oxygen and nitrate are being reduced by pyrite and organic matter that commonly apparent in the aquifer. The oxidation of pyrite is modeled using the local equilibrium approach, whereas decomposition of organic matter, with the adoption of kinetic approach. The system is buffered by dissolution of aluminum and iron oxides. The modeling process is a two-step procedure. First, the processes are modeled in the one-dimensional (1D) column using PHREEQC code. Subsequently, the calibrated and verified data were copied and used in two-dimensional (2D) PHAST model. Prior to the performance of reactive transport modeling operations with PHAST, a reliable flow model was executed. Finally, predictions are made for the distribution of water chemistry for the year 2008. Model predicts that sulfate derived from the ongoing pyrite oxidation is reduced by the dissolved organic carbon at the higher depth and forms pyrite by the reaction with iron. The results of this study highlight the importance of understanding the interplay between the transport and chemical reactions that occur during the input of nitrate to the aquifer. Reactive transport modeling incorporating the use of a newly developed code PHAST have proved to be a powerful tool for analyzing and quantifying such interactions.     

Pre-Variscan basement rocks in southern Poland: Where is the southeastern margin of eastern Avalonia (Cadomia)?

Summary Pre-Variscan basement in southern Poland is poorly exposed and thus known mostly from subsurface data. The availability of the latter is reviewed for terrains located between the Sudetes and the East European Platform. In these terrains the following relationships have been documented: Cadomian granitoids capped by Variscan flysch, Palaeozoic platform strata, Palaeozic folded and partly thermally altered successions, and low-grade metamorphic rocks overlain by Middle Cambrian strata. In view of their interrelationships the location of the Avalonia-Baltica suture in southeastern Poland is uncertain.     

[WR] nuclei of planetary nebulae: Inferences from statistical studies of the nebulae

There are about 50 galactic planetary nebulae know to have [WR] type nuclei. We have compared their nebular properties with those of the other planetary nebulae in the Galaxy. We have found that the nebular morphological types are similarly distributed in the two groups. Bipolar nebulae constitute only 20% of the total in each group. The distribution of the nebular electron densities and abundance ratios N/O, He/H and C/O are the same in the two groups. The only marked difference is that nebular expansion velocities are larger in the group of planetary nebulae with [WR] central stars. We argue that the WR phenomenon does not preferentially occur in more massive central stars of planetary nebulae, contrary to what has been suggested in some former studies. We demonstrate that, for most of the observed [WR] type objects, the WR phenomenon cannot be triggered by a late helium shell flash event.The results of our investigation are published inAstronomy & Astrophysics 303, 893 (1995) and in the proceedings of the 2nd International Colloquium on Hydrogen-deficient Stars, C.S. Jeffery & U. Heber (eds), Astronomical Society of the Pacific Conference Series, Vol. 96, p. 209 (1996).