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11.
Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise 下载免费PDF全文
Maciej J. Bojanowski Elżbieta Jaroszewicz Adrijan Košir Maciej Łoziński Leszek Marynowski Anna Wysocka Arkadiusz Derkowski 《Sedimentology》2016,63(3):523-551
Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ13C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ13C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures. 相似文献
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K.?Rybczyńska-TkaczykEmail author T.?Korni??owicz-Kowalska 《International Journal of Environmental Science and Technology》2016,13(12):2837-2846
The aim of this study was to evaluate the biosorption capacity of selected strains of microscopic fungi. We optimized the biosorption process and used the Freundlich isotherm for three strains: H. haematococca BwIII43, K37 and T. harzianum BsIII33 to describe the biosorption equilibrium of anthraquinone dye, Alizarin Blue Black B (ABBB) and alkali lignin (AL). In optimal conditions (1 g of mycelium biomass, pH = 7.0, 28 °C) for ABBB and AL sorption, the live biomass of H. haematococca BwIII43 was characterized by a higher sorption capacity, amounting to 247.47 and 161.00 mg g?1, respectively. The highest sorption properties toward anthraquinone dye (K F = 19.96 mg g?1) were shown for the biomass of H. haematococca K37. In the presence of alkali lignin, the highest sorption capacity and bond strength exhibited the biomass of H. haematococca BwIII43 (K F = 28.20 mg g?1, n = 3.46). Effective decolorization of ABBB and AL by the selected strains of microscopic fungi indicated that the biosorption process additionally enhanced the removal of color compounds from the solution. 相似文献
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J. Tomaszewska P. Smektała I. Zgłobicka J. Michalski K. J. Kurzydłowski P. Krzemiński C. Escudero-Oñate 《International Journal of Environmental Science and Technology》2018,15(9):1831-1842
Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L?1, at pH 6.5 and with a sorbent dose of 5 g L?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided. 相似文献
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Dumańska-Słowik Magdalena Pieczka Adam Natkaniec-Nowak Lucyna Kunecki Piotr Gaweł Adam Heflik Wiesław Smoliński Wojciech Kozub-Budzyń Gabriela 《Mineralogy and Petrology》2018,112(3):381-392
Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,... 相似文献
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Jacek Andrzej Urbański Gabriela GruszaNatalia Chlebus Lucyna Kryla 《Estuarine, Coastal and Shelf Science》2008
Our GIS based project aims at producing a classification scheme to develop a typology of the bottom of the Bay of Gdansk in the southern Baltic. The typology was based on the abiotic factors which are used to define water body types by the European Water Framework Directive (WFD). Significance analysis of particular factors has shown that within the discussed area wave exposure seems to play the most important role. All other factors are to a greater or lesser degree correlated with these two. Taking into consideration the shallows and the varied coastline of the investigated area it was decided to make use of the SWAN numerical wave model to determine the influence of wave impact upon the bottom. The model was used to produce raster maps of orbital velocity near the bottom for each wind scenario. With the help of the GIS analysis the maps were turned into layers: the mean velocity and the maximum velocity at the bottom. To produce the layer of yearly amount of solar radiation a GIS model was built which main parameters were the layer of depth and three layers of turbidity for three seasons. The layers of the maximum orbital velocity and of the solar radiation at the bottom were then used in a classificatory procedure consisted in an iterative sequence of the three following steps: cluster formation, dendrogram analysis and classification using the maximum likelihood method. Ecological importance of the classification has been obtained by means of the aggregation of a part of classes based upon the statistics calculated for them within the GIS system with the help of the zonal function out of the following parameters: salinity, depth, mean and maximum orbital velocity at the bottom, temperature differences between warm and cold seasons, solar radiation, and type of sediments. The method proposed here makes it possible to produce high resolution thematic maps of the bottom even with incomplete data cover of the investigated area. 相似文献
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During a cruise of r/v ‘Oceania’ in May 2006, seven vertical dissolved organic carbon (DOC) concentration profiles were produced against a background of CTD, chlorophyll a (chl a) and phaeopigment concentration profiles. The results indicate distinct vertical and spatial DOC fluctuations, ranging from 248 ± 7 μmol C dm−3 at 70 m depth at the westernmost station G/06 to 398 ± 5 μmol C dm−3 at 5 m depth at station A/06 in the western Gulf of Gdańsk. DOC concentrations were the highest at 10 m depth, where phytoplankton activity was relatively intensive, as reflected by the active chl a concentration distribution. DOC concentrations decreased towards the sea bottom. 相似文献
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Ocean Science Journal - The abundance of bacteria inhabiting the sediment-water interface and their taxonomic composition were determined with the fluorescence in situ hybridization (FISH) method... 相似文献