An alternative approach to understanding groundwater flow in sparse channel networks supported by evidence from ‘background’ fractured crystalline rocks

Size and shape of individual flow-features, and not their ‘organization’ in sets of predominant orientation, are the major influences on the ability of groundwater to percolate through sparse channel networks. Measurements in background fractured crystalline rocks proposed for nuclear waste repositories provide useful insight. Flow-features are observed as locations of increased transmissivity during packer or flow testing in boreholes. They are conceived here as channels on fracture surfaces. Findings are based on numerical modelling and a general formula by Barker (2018) for the percolation of two-dimensional (2D) objects in 3D space. Equidimensional shapes are found to be the least efficient at forming percolating networks. As discs are evolved into highly eccentric ellipses, percolation thresholds for number, area and intersection density decrease. At the same time, the percentage of features forming the active flow path declines from about 10% for discs to a few per cent for 50:1 ellipses. Compiling recent field measurements of area density of flow-features reveals low values within a limited range (0.01–0.8 m^?1). When this range is combined with practical values of likely channel width, long narrow flow-features are the only reasonable components of a sparse percolating network. Conventional equidimensional discrete fracture networks are considered unlikely. Innovative field investigation and modelling methods based only on hydrogeological measurements are suggested. It is concluded that this consideration of shape supports the approach, broadly termed the ‘long channel’ concept. Barker J.A. (2018) Intersection statistics and percolation criteria for fractures of mixed shapes and sizes. Comput Geosci 112:47–53.     

Geochemistry and tectonic significance of peridotites from the South Sandwich arc–basin system, South Atlantic

Petrographic and geochemical studies of peridotites from the South Sandwich forearc region provide new evidence for the evolution of the South Sandwich arc–basin system and for the nature of interactions between arc magma and oceanic lithosphere. Peridotites from the inner trench wall in the north-east corner of the forearc vary from clinopyroxene-bearing harzburgites, through samples transitional between harzburgites and dunites or wehrlites, to dunites. The harzburgites are LREE depleted with low incompatible element abundances and have chromites with intermediate Cr# (ca. 0.40). Modelling shows that they represent the residues from 15–20% melting at oxygen fugacities close to the QFM buffer. The dunites have U-shaped REE patterns, low incompatible element abundances and high Cr# (0.66–0.77). Petrography and geochemistry indicate that the latter are the product of intense interaction between peridotite and melt saturated with olivine under conditions of high oxygen fugacity (QFM + 2). The transitional samples are the product of lesser interaction between peridotite and melt saturated with olivine ± clinopyroxene. The data demonstrate that the harzburgites originated as the residue from melting at a ridge (probably the early East Scotia Sea spreading centre), and were subsequently modified to transitional peridotites and dunites by interaction with South Sandwich arc magmas. The second dredge locality, near the South Sandwich Trench–Fracture Zone intersection, yielded rocks ranging from lherzolite to harzburgite that could similarly have resulted from a two-stage melting and enrichment process, but involving a more fertile mantle residue and a reacting melt that is transitional between MORB and island arc tholeiite. The South Sandwich peridotites have a similar petrogenetic history to those from Conical Seamount in the Mariana forearc in the sense that both involved interaction between arc magma and pre-existing mantle lithosphere of different provenance. However, the precise compositions of the magma and mantle components vary from location to location according to the precise tectonic setting and tectonic history. Overall, therefore, data from the South Sandwich and Izu–Bonin–Mariana systems emphasise the potential significance of peridotite geochemistry in unravelling the complex tectonic histories of forearcs past and present. Received: 31 August 1999 / Accepted: 3 December 1999     

Hydrogeology of a coal-seam gas exploration area, southeastern British Columbia, Canada: Part 2. Modeling potential hydrogeological impacts associated with depressurizing

A three-dimensional, finite-element flow model was used to assess the hydrogeological effects of depressurizing coalbeds lying in the Weary Creek exploration block, Elk River valley, southeastern British Columbia, Canada. The simulation results permit, at an early stage, assessment of the environmental and economic implications of how the flow system may respond to depressurization. Estimated reservoir conditions for the coal-seam gas targets lying within the Upper Jurassic–Lower Cretaceous Mist Mountain Formation indicate that the coalbeds must be depressurized by up to 350 m to attain the critical gas desorption pressure. The simulations suggest that depressurizing has little effect on groundwater flux to the Elk River. Simulated water production for three depressurizing wells operating under steady-state, single-phase flow for initial reservoir conditions of 13 and 16.5 cm³/g is 645 m³/d (4,057 barrels/d) and 355 m³/d (2,233 barrels/d), respectively. Groundwaters collected from monitoring wells have relatively low salinity, ranging from about 250–1,300 mg/L. The groundwater is supersaturated with respect to Ca–Mg–Fe carbonates (calcite, dolomite, and siderite) and Al-bearing silicates, including kaolinite and illite. Dissolved trace-metal concentrations are low; only Fe, Cd, Cr, and Zn exceed Canadian water-quality guidelines for aquatic life. Groundwaters were devoid of the more soluble monocyclic aromatic organic compounds, including benzene, toluene, ethylbenzene, and polycyclic aromatic compounds, including naphthalene. Electronic Publication     

Assimilation and Simulation of Typhoon Rusa （2002） Using the WRF System

Using the recently developed Weather Research and Forecasting (WRF) 3DVAR and the WRF model, numerical experiments are conducted for the initialization and simulation of typhoon Rusa (2002).The observational data used in the WRF 3DVAR are conventional Global Telecommunications System (GTS) data and Korean Automatic Weather Station (AWS) surface observations. The Background Error Statistics (BES) via the National Meteorological Center (NMC) method has two different resolutions, that is, a 210-km horizontal grid space from the NCEP global model and a 10-km horizontal resolution from Korean operational forecasts. To improve the performance of the WRF simulation initialized from the WRF 3DVAR analyses, the scale-lengths used in the horizontal background error covariances via recursive filter are tuned in terms of the WRF 3DVAR control variables, streamfunction, velocity potential, unbalanced pressure and specific humidity. The experiments with respect to different background error statistics and different observational data indicate that the subsequent 24-h the WRF model forecasts of typhoon Rusa‘s track and precipitation are significantly impacted upon the initial fields. Assimilation of the AWS data with the tuned background error statistics obtains improved predictions of the typhoon track and its precipitation.     

Biodegradability of trimethylbenzene isomers under the strictly anaerobic conditions in groundwater contaminated by gasoline

Trimethylbenzene (TMB), as a constituent of gasoline, is often expected to be used as a conservative tracer in anaerobic BTEX-contaminated groundwater site to correct for attenuation due to dispersion, dilution and sorption along a flow path. To evaluate the suitability of using TMB as a tracer and to better understand biodegradability of TMB in contaminated groundwater by gasoline under anaerobic conditions, laboratory microcosms were conducted with mixed nitrate/iron/sulfate electron-acceptor amendments, using aquifer materials collected from Canadian Forces Base (CFB), Borden, Ontario, Canada. The results showed that under denitrifying conditions, biodegradation of 1,3,5-TMB, 1,2,4-TMB and 1,2,3-TMB were relatively slow and after 204 days of incubation approximately 27, 24, and 16% of the initial concentrations, respectively, were degraded in the microcosms. Under sulfate-reducing conditions, TMB isomers were recalcitrant. In contrast, significant biodegradation of TMB was observed under iron-reducing conditions. 1,3,5-TMB, 1,2,4-TMB and 1,2,3-TMB were degraded to 44, 47, and 24% of initial concentrations with first-order biodegradation rate constants of 0.003, 0.006 and 0.013 d⁻¹, respectively. This study indicates that TMB biodegradation is insignificant under nitrate and sulfate-reducing conditions but significant under iron-reducing conditions. Therefore, the use of TMB as a tracer for interpreting removal of other biodegradable gasoline constituents such as BTEX requires caution, especially in the presence of iron-reducing conditions.     

A 5 million year record of compositional variations in mantle sources to magmatism on Santiago, southern Cape Verde archipelago

High-precision Pb isotope data and Sr–Nd–Hf isotope data are presented together with major and trace element data for samples spanning the 4.6 Ma history of volcanism at Santiago, in the southern Cape Verde islands. Pb isotope data confirm the positive Δ8/4 signature of the southern islands indicating that the north–south compositional heterogeneity in the Cape Verde archipelago has persisted for at least 4.6 Ma. The Santiago volcanics show distinct compositional differences between the old, intermediate and young volcanics, and suggest greater involvement of an enriched mantle (EM1)-like source over time. Isotopic variations in the Santiago volcanics indicate convergence towards a homogeneous EM1-like end-member and distinct temporal variations in the FOZO-like end-member. Santiago and Santo Antão (a northern island, Holm et al. 2006), show a simultaneous decrease in ²⁰⁸Pb/²⁰⁴Pb of the high ²⁰⁶Pb/²⁰⁴Pb FOZO-like source with time. Such systematic archipelago-wide variations in the FOZO-like component suggest that this component is more likely to be present as a coherent package of recycled ocean crust rather than as multiple small heterogeneities dispersed in the upwelling mantle. The temporal variations in ²⁰⁸Pb/²⁰⁴Pb reflect minor lateral variations in Th/U of this recycled ocean crust package entering the melting zone beneath the islands. The location of the EM1-like component is more equivocal. A shallow lithospheric location is possible, but this would require a coincidence between spatial compositional variations in the lithosphere (EM1 is spatially restricted to the southern islands) and flow lines in the upwelling mantle revealed by seismic anisotropy. Therefore, we favour a deeper asthenospheric mantle source for the EM1-like source.     

Volcanic and structural evolution of Pico do Fogo,Cape Verde

In recent months the media have drawn attention to the Cape Verde archipelago, with particular focus on the island of Fogo, the only island presently active and with an eruption that began on 23 November 2014, finally ceasing on 7 February 2015. The Monte Amarelo conical shield forms most of the 476 km² almost circular island of Fogo. After attaining a critical elevation of about 3500 m, the Monte Amarelo shield volcano was decapitated by a giant landslide that formed a caldera‐like depression (Cha das Caldeiras), which was subsequently partially filled by basaltic nested volcanism. This younger eruptive activity culminated in the construction of the 2829 m‐high Pico do Fogo stratocone, apparently entirely made of layers of basaltic lapilli. Continued growth of the Pico do Fogo summit eruptions was interrupted in 1750, most likely after the stratocone reached a critical height. Since then, at least eight eruptions have taken place inside the landslide depression at the periphery of the Pico do Fogo cone, including the 2014–2015 eruptive event. Strong geological similarities with the Canary Islands, 1400 km to the north, have been frequently noted, probably as a consequence of a common process of origin and evolution associated with a mantle hot‐spot. These similarities are particularly evident when comparing Fogo with the Teide Volcanic Complex on Tenerife, where a lateral collapse of the Las Cañadas stratovolcano also formed a large depression (the Caldera de Las Cañadas), now partially filled with the 3718 m‐high Teide stratocone. However, important geological differences also exist and probably relate to the contrasting evolutionary stages of both islands. The Las Cañadas volcano on Tenerife formed at a late post‐erosional stage, with predominantly evolved (trachyte and phonolite) magmas, while at Fogo basaltic volcanism is still dominant.     

Methane Production and Isotopic Fingerprinting in Ethanol Fuel Contaminated Sites

Biodegradation of organic compounds in groundwater can be a significant source of methane in contaminated sites. Methane might accumulate in indoor spaces posing a hazard. The increasing use of ethanol as a gasoline additive is a concern with respect to methane production since it is easily biodegraded and has a high oxygen demand, favoring the development of anaerobic conditions. This study evaluated the use of stable carbon isotopes to distinguish the methane origin between gasoline and ethanol biodegradation, and assessed the occurrence of methane in ethanol fuel contaminated sites. Two microcosm tests were performed under anaerobic conditions: one test using ethanol and the other using toluene as the sole carbon source. The isotopic tool was then applied to seven field sites known to be impacted by ethanol fuels. In the microcosm tests, it was verified that methane from ethanol (δ¹³C = −11.1‰) is more enriched in ¹³C, with δ¹³C values ranging from −20‰ to −30‰, while the methane from toluene (δ¹³C = −28.5‰) had a carbon isotopic signature of −55‰. The field samples had δ¹³C values varying over a wide range (−10‰ to −80‰), and the δ¹³C values allowed the methane source to be clearly identified in five of the seven ethanol/gasoline sites. In the other two sites, methane appears to have been produced from both sources. Both gasoline and ethanol were sources of methane in potentially hazardous concentrations and methane could be produced from organic acids originating from ethanol along the groundwater flow system even after all the ethanol has been completed biodegraded.