Evaluation of the removal of heavy metals in a natural wetland impacted by mining activities in Mexico

This research is focused on evaluating heavy metals (Cd, Cu, Fe, Mn, Pb, and Zn) uptake and removal by Eleocharis ovata, Cyperus manimae, Typha dominguensis, and Pteridium aquilinum in a natural wetland impacted by mining activities. We analyzed heavy metals content and distribution in native plants, soils, and water of a semipermanent natural wetland in Taxco de Alarcón, Guerrero, and we also determined the physicochemical characteristics of the water. Translocation factor (TF) and bioconcentration factor (BCF) were evaluated. Results showed that physical and chemical conditions are favorable for plants development. Correlation analysis showed a good and positive relation (0.95) between Cu and Pb in soils and plants. In the analyzed matrices: Zn (0.62–2.20 mg/L) exceeded the permissible limits in water, high concentrations of Pb and Zn (26.57–525.67 and 266.67–983.33 mg/kg, respectively) were detected in the studied soils, and Pb exceeded the normal range for E. ovata and P. aquilinum in the analyzed plants. Uptake of heavy metals in the tissues of different species was found in the following order: root > leaf. Data of TF and BCF showed that E. ovata is a tolerant plant with respect to heavy metals exposure since TF value was greater than 1. This study showed that E. ovata could be considered as a bioaccumulator of heavy metals in contaminated soils.     

Silver in Tokyo Bay estuarine waters and Japanese rivers

Dissolved and particulate concentrations of silver in Tokyo Bay estuarine waters and Japanese rivers were determined in this study. The dissolved silver concentrations in the surface water of Tokyo Bay range from 5.9 to 15.1 pmol kg⁻¹, which is comparable to those in the surface water of the Japan Sea, but two or three times higher than those in the surface water of the open ocean. However, elevated concentrations of dissolved silver are not found in Tokyo Bay compared with those in other highly urbanized estuaries, such as San Francisco Bay (20∼243 pmol kg⁻¹). In the Tokyo Bay estuary, silver typically exhibits non-conservative mixing behavior, which is a common feature in the other estuaries reported previously. Dissolved silver concentrations decrease with salinity from the rivers to the mouth of Tokyo Bay. Silver is efficiently scavenged by suspended particulates, as evidenced by the high conditional distribution coefficients for silver throughout the estuary (log K_d > 5.0 ± 0.6). The silver fluxes into Tokyo Bay via inflowing rivers and atmospheric deposition were estimated as 83 kg y⁻¹ and 15 kg y⁻¹, respectively. A simple budget calculation shows that the silver supplied from rivers and atmosphere must be rapidly scavenged within the Tokyo Bay estuary.     

New insights into the high-pressure polymorphism of SiO<Subscript>2</Subscript> cristobalite

Single-crystal X-ray diffraction experiments with SiO₂ α-cristobalite reveal that the well-known reversible displacive phase transition to cristobalite-II, which occurs at approximately 1.8 GPa, can be suppressed by rapid pressure increase, leading to an overpressurized metastable state, persisting to pressure as high as 10 GPa. In another, slow pressure increase experiment, the monoclinic high-pressure phase-II was observed to form at ~1.8 GPa, in agreement with earlier in situ studies, and its crystal structure has been unambiguously determined. Single-crystal data have been used to refine the structure models of both phases over the range of pressure up to the threshold of formation of cristobalite X-I at ~12 GPa, providing important constraints on the feasibility of the two competing silica densification models proposed in the literature, based on quantum mechanical calculations. Preliminary diffraction data obtained for cristobalite X-I reveal a monoclinic unit cell that contradicts the currently assumed model.     

Morphotectonic Appraisal of Yamuna River Basin in Headwater Region: A Relative Active Tectonics Purview

In the present paper integrated appraisals of landform evolution and their geomorphic features, drainage networks across the upper part of Yamuna river basin have been attempted by using various geomorphic indices such as watershed, drainage density (D), drainage texture, stream-gradient index (SL), hypsometric integral (HI), drainage basin asymmetry (AF), mountain front sinuosity (Smf), sinuosity index (SI), valley floor height and width ratio (Vf) and data of historical earthquakes in characterizing the basin in view of relative index of active tectonics (RIAT) on DEM in geographic information systems (GIS) environment to assess the influence of recent tectonics on geomorphologic growth of the basin.The substantiated RIAT classes through some field observations and corroborated by recent seismicity reveal the recent activation of Yamuna tear faults in the basin with delineation of four RIAT classes such as class-1 (inactive 9.8% of the area), class-2 (low active; 16.40% of the area), class-3 (moderately active; 42.38% of the area) and class-4 (very active; 31.62%). The results suggest that the Himalayan frontal thrust (HFT) and Yamuna tear (YT) located in the basin is morphogenic in nature and got activated several times as evidenced by number of seismic activities in the basin and adjoining regions. The incision, and sharp turning of rivers, crenulations and warping of cross beddings/laminations and silt/clay beds and lenses, megascopic and mesoscopic faulting in sediment sequences suggest a very active nature of the HFT and YT till date in association with three prolific microseismogenic weak zones These active discontinuities appear to support the formation and development of different deformational features in sediment sequences which may be indirectly related to subduction and underthrusting of Indian plate under Eurasian plate below the Himalayan mountain chain.     

An Introduction to MODISI and SCMOD Methods for Correction of the MODIS Snow Assessment Algorithm

Detection, monitoring and precise assessment of the snow covered regions is an important issue. Snow cover area and consequently the amount of runoff generated from snowmelt have a significant effect on water supply management. To precisely detect and monitor the snow covered area we need satellite images with suitable spatial and temporal resolutions where we usually lose one for the other. In this study, products of two sensors MODIS and ASTER both on board of TERRA platform having low and high spatial resolution respectively were used. The objective of the study was to modify the snow products of MODIS by using simultaneous images of ASTER. For this, MODIS snow index image with high temporal resolution were compared with that of ASTER, using regression and correlation analysis. To improve NDSI index two methods were developed. The first method generated from direct comparison of ASTER averaged NDSI with those of MODIS (MODISI). The second method generated by dividing MODIS NDSI index into 10 codes according to their percentage of surface cover and then compared the results with the difference between ASTER averaged and MODIS snow indices (SCMOD). Both methods were tested against some 16 MODIS pixels. It is found that the precision of the MODISI method was more than 96%. This for SCMOD was about 98%. The RMSE of both methods were as good as 0.02.     

Universal time from VLBI single-baseline observations during CONT08

The IVS Intensive sessions are single-baseline, 1-h VLBI sessions carried out everyday in order to determine Universal Time (UT1). We investigate different possibilities to improve the results of such sessions. We do this investigation by extracting 2-h single-baseline sessions from the CONT08 data set. These are analysed like normal Intensives, and the results are compared to the results of the analysis of the full CONT08 data set. We find that tropospheric asymmetry is the major error source for the single-baseline sessions. It is possible to improve the accuracy of the estimated UT1 either by using accurate a priori tropospheric gradients or by estimating gradients in the data analysis.     

Study of subsurface geology in locating arsenic-free groundwater in Bengal delta,West Bengal,India

Over a large area of the Bengal delta in West Bengal, India, arsenic distribution patterns in groundwater were studied. One hundred and ten boreholes at different target locations were made, subsurface sediments were logged and analysed, and arsenic values in sediments vis-à-vis groundwater were compared. The study elucidates the subsurface geology of the western part of Bengal delta and characterises the sediments that were intersected in different boreholes with contrasting values of arsenic in groundwater. It reveals an existence of multiple aquifers stacked over each other. Depending on the color and nature of aquifer-sands and their overlying clay beds six aquifer types (Type-1 to Type-6) are classified and described. Sediment-arsenic for all the varieties of aquifer sands are near similar but the groundwater-arsenic of these six aquifers varies widely. Type-2 and Type-5 aquifers host arsenic-contaminated groundwater whereas the other four aquifers are arsenic-free. Type-2 and Type-5 aquifers are capped by a grey to dark grey soft organic matter-rich clay unit which makes these aquifers semi-confined to leaky-confined. These contribute in releasing arsenic from the sediments. The results of this study are employed in a proposed georemedial measure against this hazardous toxic element.     

Composition and origin of the Çaldağ oxide nickel laterite,W. Turkey

The Çalda? nickel laterite deposit located in the Aegean region of W. Turkey contains a reserve of 33 million tons of Ni ore with an average grade of 1.14% Ni. The deposit is developed on an ophiolitic serpentinite body which was obducted onto Triassic dolomites in the Late Cretaceous. The deposit weathering profile is both laterally and vertically variable. A limonite zone, which is the main ore horizon, is located at the base of the profile. A hematite horizon is located above the limonite, which in the south of the deposit is capped by Eocene freshwater limestones and in the north by a siliceous horizon. The deposit is unusual in lacking a significant saprolite zone with little development of Ni-silicates. The boundary between the limonite zone and serpentinite below is sharp with a marked decrease in concentrations of MgO from 13 to 1 wt.% over a distance of 2 mm representing the ‘Mg discontinuity’. Ni concentrations within goethite, the main ore mineral, reach a maximum of ~3 wt.% near the base of the limonite zone. Silica concentrations are high throughout most of the laterite with up to 80 wt.% silica in the upper portion of some profiles. The combination of a serpentinite protolith and a high water table at Çalda?, in association with an aggressive weathering environment in a tropical climate, resulted in the formation of an oxide-dominated deposit. The precipitation of silica may coincide with a change in climate with silica precipitation linked to an increase in seasonality. Additional variations within profile morphology are attributed to transportation during and after laterite development as a result of faulting, pocket type laterite formation and slumping, each of which produces a contrasting set of textural and geochemical features.     

Seven-Day Intensity and Intensity Spread Predictions in Bifurcation Situations with Guidance-On-Guidance for Western North Pacific Tropical Cyclones

An objective technique to detect and predict intensity bifurcation situations in a five-day Weighted Analog Intensity forecast technique for the western North Pacific (WAIP) has been extended to seven days. A hierarchical cluster analysis is applied to the N analog intensities to separate them into two clusters, which are considered to represent a substantial intensity bifurcation if a threshold maximum velocity difference of 15 kt is satisfied. Two important modifications have been made to develop the bifurcation version for seven-day WAIP forecasts. First, the number of track analogs has been increased from 10 analogs to 16 analogs, which results in larger sample sizes and better performance. Second, separate intensity bias corrections are calculated for the two cluster WAIP forecasts rather than using the same 16-analog intensity bias correction. If an always perfect selection of the correct cluster WAIP forecast of each bifurcation situation is made, a substantial improvement in the intensity mean absolute errors is achieved relative to the original WAIP forecasts based on all 16 of the best analogs. These perfect-cluster selection WAIP forecasts have smaller bias errors and are more highly correlated with the verifying intensities at all forecast intervals through 168 h. Furthermore, the Probability of Detection is improved for the perfect-cluster selection and more realistic intensity spreads are specified. A simple guidance-on-guidance technique is demonstrated to assist the forecasters in selecting the correct WAIP cluster forecast in bifurcation situations.     

Flexible–inflexible: socio-demographic,spatial and temporal dimensions of flat sharing in Leipzig (Germany)

Flat sharers are one of the most distinct representatives of the ‘new’ household types, but have received only very limited attention from researchers. Back in the 1960s shared flats were usually founded with a strong ideological impetus, whereas flat sharing nowadays is just one household type among many others. Typically, this housing arrangement consists of at least two young adult individuals without children. Sharing the flat and the housing costs is the basis of their relationship but living with others is an additional motive. As a rule, flat sharing bridges two distinct events in the course of one’s life: the leaving of the parental home and the foundation of the first independent household. Thus for a restricted period in time, it is a flexible household type adapted to the situational needs of its members. Germany has one of the strongest and longest traditions of flat sharing in Europe, especially among university students. An explorative study was conducted in Leipzig to come to a deeper understanding of what flat sharing means in its ambivalence of being both an economic unit and a social arrangement. Based on qualitative and quantitative evidence from group discussions and Internet adverts, we shed light on the highly under-researched social practice of flat sharing. We will show that despite the structural flexibility of this household type, there is also evidence for its socio-demographic selectivity, spatial concentration and temporal limitation over the individual life courses.