Functional Performance of Three Invasive <Emphasis Type="Italic">Marenzelleria</Emphasis> Species Under Contrasting Ecological Conditions Within the Baltic Sea

A 4-week laboratory experiment investigated the behaviour (survival and bioirrigation) and impact of the invasive polychaetes Marenzelleria viridis, M. neglecta and M. arctia on sediment-water solutes exchange, porewater chemistry, and Fe and P interactions in high-salinity sandy sediment (HSS) and low-salinity muddy sediment (LSM) from the Baltic Sea. M. viridis showed deep burrowing with efficient bioirrigation (11 L m^?2 day^?1) and high survival (71%) in HSS, while M. arctia exhibited shallow burrowing with high bioirrigation (12 L m^?2 day^?1) and survival (88%) in LSM. M. neglecta behaved poorly in both ecological settings (bioirrigation, 5–6 L m^?2 day^?1; survival, 21–44%). The deep M. viridis bioirrigation enhanced total microbial CO₂ (TCO₂) production in HSS by 175% with a net efflux of NH₄⁺ and PO₄^3?, at rates 3- to 27-fold higher than for the other species. Although the shallow and intense bioirrigation of M. arctia in LSM stimulated microbial TCO₂ production to some extent (61% enhancement), the nutrient fluxes close to zero indicate that it effectively prevented the P release. Porewater Fe:PO₄^3? ratios revealed that the oxidizing effect of M. arctia bioirrigation increased the PO₄^3? adsorption capacity of LSM twofold relative to defaunated controls while no buffering of PO₄^3? was detected in M. viridis HSS treatment. Therefore, the different behaviour of the three species in various environments and the sharp contrast between M. viridis and M. arctia effects on C, N and P cycling must be considered carefully when the ecological role of Marenzelleria species in the Baltic Sea is evaluated.     

Testing Nano-Powder and Fused-Glass Mineral Reference Materials for In Situ Rb-Sr Dating of Glauconite,Phlogopite, Biotite and Feldspar via LA-ICP-MS/MS

Reference materials (RMs) with well-characterised composition are necessary for reliable quantification and quality control of isotopic analyses of geological samples. For in situ Rb-Sr analysis of silicate minerals via laser ablation inductively coupled plasma tandem mass spectrometry (LA-ICP-MS/MS) with a collision/reaction cell, there is a general lack of mineral-specific and matrix-matched RMs, which limits wider application of this new laser-based dating technique to certain minerals. In this work, pressed nano-powder pellets (NP) of four RMs, GL-O (glauconite), Mica-Mg (phlogopite), Mica-Fe (biotite) and FK-N (K-feldspar), were analysed and tested for in situ Rb-Sr dating, complemented by isotope dilution (ID) MC-ICP-MS Rb-Sr analyses of GL-O and Mica-Mg. In addition, we attempted to develop alternative flux-free and fused ‘mineral glasses’ from the above RMs for in situ Rb-Sr dating applications. Overall, the results of this study showed that among the above RMs only two NP (Mica-Mg-NP and GL-O-NP) were suitable and robust for in situ dating applications. These two nano-powder reference materials, Mica-Mg-NP and GL-O-NP, were thus used as primary RMs to normalise and determine Rb-Sr ages for three natural minerals: MDC phlogopite and GL-O glauconite grains, and also Mica-Fe-NP (biotite). Our in situ analyses of the above RMs yielded Rb-Sr ages that are in good agreement (within 8%) of published ages, which suggests that both Mica-Mg-NP and GL-O-NP are suitable RMs for in situ Rb-Sr dating of phlogopite, glauconite and biotite. However, using secondary RMs is recommended to monitor the quality of the obtained ages.     

Characterizing supraglacial meltwater channel hydraulics on the Greenland Ice Sheet from in situ observations

Supraglacial rivers on the Greenland Ice Sheet (GrIS) transport large volumes of surface meltwater toward the ocean, yet have received relatively little direct research. This study presents field observations of channel width, depth, velocity, and water surface slope for nine supraglacial channels on the south‐western GrIS collected between July 23 and August 20, 2012. Field sites are located up to 74 km inland and span 494–1485 m elevation, and contain measured discharges larger than any previous in situ study: from 0.006 to 23.12 m³/s in channels 0.20 to 20.62 m wide. All channels were deeply incised with near vertical banks, and hydraulic geometry results indicate that supraglacial channels primarily accommodate greater discharges by increasing velocity. Smaller streams had steeper water surface slopes (0.74–8.83%) than typical in terrestrial settings, yielding correspondingly high velocities (0.40–2.60 m/s) and Froude numbers (0.45–3.11) with supercritical flow observed in 54% of measurements. Derived Manning's n values were larger and more variable than anticipated from channels of uniform substrate, ranging from 0.009 to 0.154 with a mean value of 0.035 ± 0.027 despite the absence of sediment, debris, or other roughness elements. Ubiquitous micro‐depressions in shallow sections of the channel bed may explain some of these roughness values. However, we find that other, unobserved sources of flow resistance likely contributed to these elevated Manning's n values: future work should explicitly consider additional sources of flow resistance beyond bed roughness in supraglacial channels. We conclude that hydraulic modeling for these channels must allow for both subcritical and supercritical flow, and most importantly must refrain from assuming that all ice‐substrate channels exhibit similar hydraulic behavior, especially for Froude numbers and Manning's n. Finally, this study highlights that further theoretical and empirical work on supraglacial channel hydraulics is necessary before broad scale understanding of ice sheet hydrology can be achieved. Copyright © 2016 John Wiley & Sons, Ltd.     

A regional and global analysis of carbon dioxide physiological forcing and its impact on climate

An increase in atmospheric carbon dioxide concentration has both a radiative (greenhouse) effect and a physiological effect on climate. The physiological effect forces climate as plant stomata do not open as wide under enhanced CO₂ levels and this alters the surface energy balance by reducing the evapotranspiration flux to the atmosphere, a process referred to as ‘carbon dioxide physiological forcing’. Here the climate impact of the carbon dioxide physiological forcing is isolated using an ensemble of twelve 5-year experiments with the Met Office Hadley Centre HadCM3LC fully coupled atmosphere–ocean model where atmospheric carbon dioxide levels are instantaneously quadrupled and thereafter held constant. Fast responses (within a few months) to carbon dioxide physiological forcing are analyzed at a global and regional scale. Results show a strong influence of the physiological forcing on the land surface energy budget, hydrological cycle and near surface climate. For example, global precipitation rate reduces by ~3% with significant decreases over most land-regions, mainly from reductions to convective rainfall. This fast hydrological response is still evident after 5 years of model integration. Decreased evapotranspiration over land also leads to land surface warming and a drying of near surface air, both of which lead to significant reductions in near surface relative humidity (~6%) and cloud fraction (~3%). Patterns of fast responses consistently show that results are largest in the Amazon and central African forest, and to a lesser extent in the boreal and temperate forest. Carbon dioxide physiological forcing could be a source of uncertainty in many model predicted quantities, such as climate sensitivity, transient climate response and the hydrological sensitivity. These results highlight the importance of including biological components of the Earth system in climate change studies.     

The use of site investigation data for the preparation of engineering geological maps and reports for use by planners and civil engineers

Forster, A. and Culshaw, M.G., 1990. The use of site investigation data for the preparation of engineering geological maps and reports for use by planners and civil engineers. Eng. Geol., 29: 347–354.

In modern cities hundreds of site investigations have been carried out before the construction of roads, offices, factories and housing estates. The results of these investigations represent a large resource of geological and geotechnical information worth millions of pounds. Much of this information is lost, or is not accessible, because of confidentiality; that which is available will be of variable content and quality. The geographical and stratigraphical distribution will also be uneven. However, maps, and resumés of the engineering behaviour of the geological materials in an area, can be produced to guide planners and to help engineers at the earliest stage of development.

In this paper the authors discuss the use of the data contained in site investigation reports to prepare engineering geological maps and illustrate this by reference to recent applied geological mapping projects carried out by the British Geological Survey.     

Mapping diversified peri-urban agriculture – potential of object-based versus per-field land cover/land use classification

High spatial resolution satellite data contribute to improving land cover/land use (LCLU) classification in agriculture. A classification procedure based on Quickbird satellite image data was developed to map LCLU of diversified agriculture at sub-communal and communal level (7 km²). Segmentation performance of the panchromatic band in combination with high pass filters (HPF) was tested first. Accuracy of field boundary delineation was evaluated by an object-based segmentation, a per-field and a manual classification, along with a quantitative accuracy assessment. Sub-communal classification revealed an overall accuracy of 84% with a κ coefficient of 0.77 for the per-field vector segmentation compared to an overall accuracy of 56–60% and a κ coefficient of 0.37–0.42 for object-based approaches. Per-field vector segmentation was thus superior and used for LCLU classification at communal level. Overall accuracy scored 83% and the κ coefficient 0.7. In diversified agriculture, per-field vector segmentation and classification achieved higher classification results.     

Loess in the Czech Republic: Magnetic properties and paleoclimate

Summary We have studied 454 oriented samples from seven loess outcrops in the Czech Republic for comparison and correlation of the magnetic properties with those of the loess profiles in China and Central Asia. Three sections at Sedlec (Prague), Zeměchy and Dolní Věstonice cover the time span of the last glacial-interglacial cycle. Loess from the middle Pleistocene period including pedocomplexes V and VI was studied at Sedlešovice (Znojmo) and Karlštejn. Loess of uncertain — possibly lower to middle Pleistocene age — was sampled at Sedlec near Mikulov. At Červeny Kopec (Red Hill, Brno) we investigated the oldest loess near the Matuyama/Brunhes (M/B) boundary. The characteristic remanence (ChRM) determined after magnetic clearning is of normal polarity throughout all sections except at Červeny Kopec. There, two polarity changes from reversed to normal were found within two sections initially thought to represent two successive stratigraphic intervals. However, the marked similarities between lithological, susceptibility, declination and inclination profiles lead us to suggest that the two polarity changes are in fact one and the same. The two sections are therefore laterally equivalent and both have recorded the M/B field reversal. The susceptibility variations were used to mutually correlate the Czech sections and to construct a composite profile across the present day loess outcrops in the Czech Republic. They also serve as a paleoclimate proxy which can be compared and correlated with the paleoclimatic records observed in the Chinese and Central Asian loess. The origin of the low field susceptibility variations was studied by measuring the frequency dependence of susceptibility which revealed that the enhancement within the pedocomplexes is controlled by the amount of fine-grained ferromagnetic minerals present.