Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

珠江流域1961-2007年气候变化及2011-2060年预估分析

 根据珠江流域1961-2007年气温、降水量观测资料和ECHAM5/MPI-OM模式2011-2060年预估结果,分析了流域过去47 a的气温和降水量变化,并预估未来50 a变化趋势。结果表明,在全球变暖的背景下,过去47 a温度呈上升趋势,约升高1.8℃。冬季增温最明显,夏季最弱。未来50 a流域温度仍呈上升趋势,A1B情景下升幅约1.9℃,并且年际变化增强。A2和B1两种排放情景下秋季升温最显著,冬季最弱,A1B排放情景与此相反。过去47 a秋季降水量呈减少趋势;春、夏、冬季和年降水量均呈增加趋势。未来50 a降水总体呈增加趋势,A1B排放情景降水增加最多,约为230 mm。A2、A1B和B1情景下降水季节分配未发生显著变化。年降水和冬季降水的年际变率增强,秋季减弱。     

两种反映东亚夏季风异常的指数的比较研究

本文利用文献^ [4]提出的一种新的反映东亚夏季风异常的海陆温差指数分析了夏季风异常时我国气温、降水异常以及东亚环流状况，通过分析指出，东亚夏季风偏强，则中国东部夏季气温偏高，江淮干旱，华北多雨；夏季风偏弱则夏季气温偏低，江淮多雨，易涝，华北少雨。通过两种夏季风指数的对比，海陆温差指数能更好地反映东亚夏季环流及天气气候异常。文中还指出，海陆温差指数能更好的反映夏季风异常的原因是它的定义方法更科学，更全面的反映东亚海陆热力差异，既包含了东亚纬向海陆热力差异的影响，又考虑了东亚经向海陆热力差异的因素，并用地表气温和海表温度差来表示海陆热力差，好于以往用海平面气压差来反映海陆热力差。     

地图概括中空间目标几何信息传递模型研究

地图概括是实现多比例尺地图生产和更新的一种重要理论方法。目前,国际国内制图学界对地图概括的研究主要集中在发展地图概括算法方面,在地图概括的质量评价方面的研究还很少。为此,本文以信息论为理论基础,以地图概括中空间目标几何信息的传递问题为研究对象,以相应空间目标几何信息的传递效率来度量地图概括中单个空间目标的概括质量。首先,建立了地图概括的空间信息传递模型,描述不同比例尺地图之间空间信息的传递过程。进而提出了地图概括过程中空间目标(即:线和面目标)几何信息的传递模型,并且对地图概括中空间目标几何信息的传递状况进行了评估,给出了具体的计算和实现方法。最后,通过实验初步验证了地图概括中空间目标几何信息传递模型的可行性。     

塔里木盆地顺北地区11号走滑断裂带变形及其活动特征

塔里木盆地顺北地区发育大量走滑断裂带,并对油气的运聚成藏有重要控制作用.以顺北西部地区地震资料为基础,对顺北11号走滑断裂带的几何变形特征、活动性、活动期次及其形成机制等进行了分析.顺北11号走滑断裂带整体呈NNW走向延伸,具有垂向分层性和平面分段性.断裂带北段主体为压扭和张扭交互段,中段为两条次级断层控制的拉分地堑,...     

末次冰盛期-全新世东海陆坡滑塌沉积的地质年代与沉积学证据

基于东海陆坡区OT12-01孔长度为5.35 m沉积物AMS 14C测年、高分辨率粒度分析和XRF岩芯元素扫描数据,识别出了末次冰盛期(LGM)至全新世期间发生的多次滑塌事件。研究发现,OT12-01孔全新世晚期沉积层缺失,LGM至全新世期间呈现AMS 14C年龄模式频繁倒转、沉积物粒度、元素比值垂向上多处突变或"错动"等特征,保存了LGM至全新世非连续的沉积记录。OT12-01孔沉积物主要来源于低海平面时期的长江/黄河物质,OT12-01孔是由中国大陆陆源物质在东海陆架经水动力分选,细颗粒被搬运至东海陆坡后,发生多次滑塌形成。LGM时期物源供给是OT12-01孔形成滑塌沉积的重要因素,末次冰消期海平面快速上升可能是高频滑塌沉积的触发原因,而低海平面时期甲烷水合物溢出、频繁的地震和火山喷发可能是海底滑坡作用发生的诱因。     

云南白秧坪银多金属矿床微量元素地球化学特征

云南白秧坪银多金属矿床是滇西兰坪盆地内新发现的矿床,属东特提斯喜马拉雅成矿域的一部分。矿床主要产于下白垩统景星组石英砂岩、粉砂岩中。本文从微量元素地球化学研究入手,与滇西喜马拉雅期富碱岩体相比较,它们具有相同的物质来源区,这种源区被认为是壳幔物质混合的一种"EMⅡ型"富集地幔源。     

降雨诱发浅层黄土滑坡变形破坏机制

由降雨引发的浅层黄土滑坡灾害具有致灾性强、范围广、影响面积大等特点,是黄土高原地区危害严重的地质灾害类型。经典算法采用安全系数描述坡体稳定性,难以对坡体变形破坏的起始位置和实际失效面加以识别,限制了滑坡变形过程的描述和滑坡有效预测。以非饱和土吸应力理论为指导,基于Hydrus中的Slope Cube模块,建立黄土斜坡水-力耦合模型,结合黄土地区易滑坡形态统计数据,针对凸型、凹型、直线型3种坡型与30°、40°、50°三种坡度组合,计算了不同降雨条件下的坡体稳定性响应。结果表明,不同坡型的黄土斜坡对降雨条件具有明显的响应。相同降雨量、相同坡度条件下直线型坡发生浅表层破坏的可能性最低,凹型坡次之、凸型坡的稳定性最差。与之相对应的,相同条件下凸型坡失稳时间最短、凹型坡次之、直线型坡最长。本研究可为浅层滑坡的早期识别和预报提供支撑。     

近震震源深度测定精度的理论误差分析

2012年4月2日上海徐汇区发生M_L1.9地震,位于徐汇区、闵行区和浦东新区等地区部分房屋有晃动,部分人群有感。本文分析了上海有感地震的原因,在此基础上从地震精确定位、震源深度、地震烈度、地震发生时间以及人口密度和社会影响等对该次地震的有感原因进行了详细的分析。由于目前地震还不能准确预报,而地震的发生有很大的随机性,因此,提高民众防震减灾意识尤为重要。     

Shallow sediment deformation styles in north-western Campeche Knolls,Gulf of Mexico and their controls on the occurrence of hydrocarbon seepage

During German R/V Meteor M67/2 expedition to Campeche Knolls, southern Gulf of Mexico, a set of 2D high resolution seismic data was acquired to study the near-surface sediment structure and its relationship with hydrocarbon seepages in this salt province. The comprehensive survey covered 20 individual bathymetric highs or ridges and identified three principle structural types: Passive Type, Chaopopte Type, and Asymmetric Flap Type. The first type is the result of passive diapirism, whereas the latter two were initialized by a regional compressional event in the Miocene, but are later differently modified by salt tectonism. Chapopote Type structures appear as symmetrical domes, with uplifted coarse-grained Miocene sediments in their cores and rather thin syn-kinematic sediments covering the crests. Asymmetric Flap Type structures are also first folded as domes or ridges, but one flap later subsided together with salt evacuation, resulting in single uplifted monoclines. With the coarse-grained pre-kinematic sediments as reservoir units, both structural types can focus and accumulate hydrocarbons. The geometries of the structures suggest that hydrocarbons are accumulated in the center of the Chapopote Type structures and in the subsided flaps of the Asymmetric Flap Type structures. Hydrocarbon leakage from these thinly sealed reservoirs is regarded as the principle mechanism for the seepage in the study area, and accordingly the most seepage-prone positions are above these reservoirs. The seep locations suggested by analysis of sea-surface oil slick images of SAR satellite data are also examined in this study. These independently derived seep locations confirm the seepage-prone positions to be above the shallow buried reservoirs. This study suggest that the shallow sediment structures control the distribution of the hydrocarbon seeps of the north-western Campeche Knolls, although the hydrocarbons are sourced from the greater depth.