Geochemical reconstruction of late Holocene drainage and mixing in Kluane Lake,Yukon Territory

The level of Kluane Lake in southwest Yukon Territory, Canada, has fluctuated tens of metres during the late Holocene. Contributions of sediment from different watersheds in the basin over the past 5,000 years were inferred from the elemental geochemistry of Kluane Lake sediment cores. Elements associated with organic material and oxyhydroxides were used to reconstruct redox fluctuations in the hypolimnion of the lake. The data reveal complex relationships between climate and river discharge during the late Holocene. A period of influx of Duke River sediment coincides with a relatively warm climate around 1,300 years BP. Discharge of Slims River into Kluane Lake occurred when Kaskawulsh Glacier advanced to the present drainage divide separating flow to the Pacific Ocean via Kaskawulsh and Alsek rivers from flow to Bering Sea via tributaries of Yukon River. During periods when neither Duke nor Slims river discharged into Kluane Lake, the level of the lake was low and stable thermal stratification developed, with anoxic and eventually euxinic conditions in the hypolimnion.     

Application of saddlepoint approximation in reliability analysis of dynamic systems

The application of the saddlepoint approximation to reliability analysis of dynamic systems is investigated. The failure event in reliability problems is formulated as the exceedance of a single performance variable over a prescribed threshold level. The saddlepoint approximation technique provides a choice to estimate the cumulative distribution function (CDF) of the performance variable. The failure probability is obtained as the value of the complement CDF at a specif ied threshold. The method requires computing the saddlepoint from a simple algebraic equation that depends on the cumulant generating function (CGF) of the performance variable. A method for calculating the saddlepoint using random samples of the performance variable is presented. The applicable region of the saddlepoint approximation is discussed in detail. A 10-story shear building model with white noise excitation illustrates the accuracy and effi ciency of the proposed methodology.     

Lateral continuity of basement seismic reflections in 15 Ma ultrafast-spreading crust at ODP Site 1256

The Ocean Drilling Program (ODP) initiated drilling at Site 1256D in the Guatemala Basin, about 1,000 km off the East Pacific Rise to penetrate plutonic rocks, anticipated to be relatively shallow in this region, formed at an ultra-fast spreading rate. IODP Expedition E312 successfully drilled into gabbros at ~1,150 m in basement. Multi-channel seismic traces show weak laterally coherent sub-basement reflections at borehole depths. Synthetic reflectivity seismograms were computed using a Ricker wavelet and impedance profiles from borehole sonic logs. These seismograms show significant sub-basement amplitude peaks. A zero-offset vertical seismic profile, shot on E312, was processed to investigate the authenticity of these reflections and their relationship to borehole geology. A dual scheme of the median filtering and F–K dip filtering was used. Tests with synthetic seismograms indicate the approach is effective at reasonable SNR levels. Downgoing energy is clearly identified but negligible upgoing energy is visible over random noise. These results indicate that lava flows and igneous contacts in upper ocean crust have significant topography on lateral scales less than the Fresnel Zone (~300 m) due to igneous and tectonic processes.     

Environmental Geochemistry and Acid Mine Drainage Evaluation of an Abandoned Coal Waste Pile at the Alborz-Sharghi Coal Washing Plant,NE Iran

In this paper, an abandoned waste coal pile, which is resulted from Alborz-Sharghi coal washing plant, NE of Iran was mineralogically and geochemically characterized to evaluate pyrite oxidation, acid mine drainage (AMD) generation, and trace element mobility. After digging ten trenches and vertical sampling, a quantitative method including the atomic absorption test, and the quality-based methods including optical study were carried out for determination of pyrite fractions in the waste pile. The geochemical results revealed that the fraction of remaining pyrite increased with depth, indicating that pyrite oxidation is limited to the shallower depths of the pile which were confirmed by variations of sulfate, pH, EC, and carbonate with depth of the pile. To evaluate the trend of trace elements and mineralogical constituents of the waste particles, the samples were analyzed by using XRD, ICP-MS, and ICP-OES methods. The results showed the secondary and neutralizing minerals comprising gypsum have been formed below the oxidation zone. Besides, positive values of net neutralization potential indicated that AMD generation has not taken in the waste pile. In addition, variations of trace elements with depth reveal that Pb and Zn exhibited increasing trends from pile surface toward the bottom sampling trenches while another of them such as Cu and Ni had decreasing trends with increasing depth of the waste pile.     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

Mass-front velocity of dry granular flows influenced by the angle of the slope to the runout plane and particle size gradation

The mass-front velocities of granular flows results from the joint action of particle size gradations and the underlying surfaces.However,because of the complexity of friction during flow movement,details such as the slope-toe impedance effects and momentum-transfer mechanisms have not been completely explained by theoretical analyses,numerical simulations,or field investigations.To study the mass-front velocity of dry granular flows influenced by the angle of the slope to the runout plane and particle size gradations we conducted model experiments that recorded the motion of rapid and long-runout rockslides or avalanches.Flume tests were conducted using slope angles of 25°,35°,45°,and 55° and three particle size gradations.The resulting mass-front motions consisted of three stages:acceleration,velocity maintenance,and deceleration.The existing methods of velocity prediction could not explain the slowing effect of the slope toe or the momentum-transfer steady velocity stage.When the slope angle increased from 25° to 55°,the mass-front velocities dropped significantly to between 44.4% and59.6% of the peak velocities and energy lossesincreased from 69.1% to 83.7% of the initial,respectively.The velocity maintenance stages occurred after the slope-toe and mass-front velocity fluctuations.During this stage,travel distances increased as the angles increased,but the average velocity was greatest at 45°.At a slope angle of 45°,as the median particle size increased,energy loss around the slope toe decreased,the efficiency of momentum transfer increased,and the distance of the velocity maintenance stage increased.We presented an improved average velocity formula for granular flow and a geometrical model of the energy along the flow line.     

Practical Incorporation of Multivariate Parameter Uncertainty in Geostatistical Resource Modeling

There is a need to bridge theory and practice for incorporating parameter uncertainty in geostatistical simulation modeling workflows. Simulation workflows are a standard practice in natural resource and recovery modeling, but the incorporation of multivariate parameter uncertainty into those workflows is challenging. However, the objectives can be met without considerable extra effort and programming. The sampling distributions of statistics comprise the core theoretical notion with the addition of the spatial degrees of freedom to account for the redundancy in the spatially correlated data. Prior parameter uncertainty is estimated from multivariate spatial resampling. Simulation-based transfer of prior parameter uncertainty results in posterior distributions which are updated by data conditioning and the model domain extents and configuration. The results are theoretically tractable and practical to achieve, providing realistic assessments of uncertainty by accounting for large-scale parameter uncertainty, which is often the most important component impacting a project. A simulation-based multivariate workflow demonstrates joint modeling of intrinsic shale properties and uncertainty in estimated ultimate recovery in a shale gas project. The multivariate workflow accounts for joint prior parameter uncertainty given the current well locations and results in posterior estimates on global distributions of all modeled properties. This is achieved by transferring the joint prior parameter uncertainty through conditional simulations.