Simultaneous oxidation of arsenic and antimony at low and circumneutral pH,with and without microbial catalysis

Arsenic and Sb are common mine-water pollutants and their toxicity and fate are strongly influenced by redox processes. In this study, simultaneous Fe(II), As(III) and Sb(III) oxidation experiments were conducted to obtain rates under laboratory conditions similar to those found in the field for mine waters of both low and circumneutral pH. Additional experiments were performed under abiotic sterile conditions to determine the biotic and abiotic contributions to the oxidation processes. The results showed that under abiotic conditions in aerated Fe(III)–H₂SO₄ solutions, Sb(III) oxidizes slightly faster than As(III). The oxidation rates of both elements were accelerated by increasing As(III), Sb(III), Fe(III), and Cl⁻ concentrations in the presence of light. For unfiltered circumneutral water from the Giant Mine (Yellowknife, NWT, Canada), As(III) oxidized at 15–78 μmol/L/h whereas Sb(III) oxidized at 0.03–0.05 μmol/L/h during microbial exponential growth. In contrast, As(III) and Sb(III) oxidation rates of 0.01–0.03 and 0.01–0.02 μmol/L/h, respectively, were obtained in experiments performed with acid unfiltered mine waters from the Iberian Pyritic Belt (SW Spain). These results suggest that the Fe(III) formed from microbial oxidation abiotically oxidized As(III) and Sb(III). After sterile filtration of both mine water samples, neither As(III), Sb(III), nor Fe(II) oxidation was observed. Hence, under the experimental conditions, bacteria were catalyzing As and Sb oxidation in the Giant Mine waters and Fe oxidation in the acid waters of the Iberian Pyrite Belt.     

Power Fluctuations in Meteor Head Echoes Observed with the EISCAT VHF Radar

We present observations and preliminary results from a meteor experiment carried out with the 224 MHz EISCAT VHF radar in Tromsø, Norway, which was run for 6 h on November 26, 2003. The data set contains echoes with peculiar pulsations in received power in the frequency range 20–200 Hz, limited by instrumental parameters. The process causing the echo power pulsations has not yet been identified. Plasma effects are the most likely cause, a possible mechanism is for instance asymmetrical dust grains in rotation causing a modulation of the ionization rate.     

Forecasting the demand for services of a New Port

Forecasting the demand for a port's services is usually the first step in planning a new port. The objective of this paper is to assess the available forecasting methodology. First, techniques for estimating potential foreign trade volume are surveyed. Next, we turn to the port traffic allocation model, which allows for quantitative estimates based on reasonable assumptions. Third, long run forecasting problems are discussed in detail. Finally, we survey the problems and advantages of formal modelling effort. It is concluded that, although the state-of-the-arts in modelling is not well developed, modelling remains an important part of port planning and development.     

Reliability-based optimal design of nonlinear viscous dampers for the seismic protection of structural systems

Viscous dampers are widely employed for enhancing the seismic performance of structural systems, and their design is often carried out using simplified approaches to account for the uncertainty in the seismic input. This paper introduces a novel and rigorous approach that allows to explicitly consider the variability of the intensity and characteristics of the seismic input in designing the optimal viscous constant and velocity exponent of the dampers based on performance-based criteria. The optimal solution permits controlling the probability of structural failure, while minimizing the damper cost, related to the sum of the damper forces. The solution to the optimization problem is efficiently sought via the constrained optimization by linear approximation (COBYLA) method, while Subset simulation together with auxiliary response method are employed for the performance assessment at each iteration of the optimization process. A 3-storey steel moment-resisting building frame is considered to illustrate the application of the proposed design methodology and to evaluate and compare the performances that can be achieved with different damper nonlinearity levels. Comparisons are also made with the results obtained by applying simplifying approaches, often employed in design practice, as those aiming to minimize the sum of the viscous damping constant and/or considering a single hazard level for the performance assessment.     

Influence of the nonlinear behavior of viscous dampers on the seismic demand hazard of building frames

This paper analyzes the influence of damper properties on the probabilistic seismic performance of building frames equipped with viscous dampers. In particular, a probabilistic methodology is employed to evaluate the influence of the damper nonlinearity, measured by the damper exponent, on the performance of structural and nonstructural components of building frames, as described by the response hazard curves of the relevant engineering demand parameters. The performance variations due to changes in the damper nonlinearity level are evaluated and highlighted by considering two realistic design scenarios and by comparing the results of a set of cases involving dampers with different exponents designed to provide the same deterministic performance. By this way, it is possible to evaluate the influence of the nonlinear response and of its dispersion on the demand hazard. It is shown that the damper nonlinearity level strongly affects the seismic performance and different trends are observed for the demand parameters of interest. A comparison with code provisions shows that further investigation is necessary to provide more reliable design formulas accounting for the damping nonlinearity level. Copyright © 2015 John Wiley & Sons, Ltd.     

Schwierigkeiten bei der Bestimmung vonMicrocystisarten

Ohne Zusammenfassung     

Symposium über Fragen der Cyanophytentaxonomie im Seenforschungsinstitut der ETHZ/EAWAG in Kastanienbaum (Schweiz), 2.–15. August 1979 Verhandlungsbericht

The 8th Symposium of the International Association for Cyanophyte Research IAC was attended by 29 specialists from 11 countries. The 19 oral presentations and discussions centered on the following themes: The basic principles of cyanophyte taxonomy (3 lectures), systematic problems of certain taxonomic groups (5 lectures), morphology (6 lectures) and ecology (5 lectures). The intensive discussions between representatives of the classical (european) taxonomic treatment of cyanophytes (based on morphological and ecological characteristics) and those representing the bacteriological study of ‘cyanobacteria’ were especially valuable. The central theme of the meeting was, however, the mutual microscopic study and discussion of problematic blue-greens from natural habitats, that were mostly collected during the three field trips into different areas of central Switzerland (Grimsel-Gotthard-Nufenen. Klewenalp. Gerzensee).      

Effect of oils on cell membrane permeability in Fucus serratus and Laminaria digitata

Leakage of electrolytes from discs of treated fronds of Laminaria digitata and Fucus serratus was the criterion used to study the effect of oils over 24 h on cell membrane permeability. Motor fuel oil increased cell membrane permeability in both algae at 1 h, or longer, after treatment. Laminaria changed to a green colour after 3 h, but Fucus was unaffected visibly by the oil. White spirit, diesel oil, or aviation fuel did not alter cell membrane permeability or visibly affect either alga over 24 h.