A Laboratory and Theoretical Study on the Uptake of SO2 Gas by Large and Small Water Drops Containing Heavy Metal Ions

Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO₂ by water drops containing heavy metal ions for both, large and small water drops did agree with the model results.     

Spatial-Correlation Based Persistent Scatterer Interferometric Study for Ground Deformation

Interferometric Synthetic Aperture Radar (InSAR), nowadays, is a precise technique for monitoring and detecting ground deformation at a millimetric level over large areas using multi-temporal SAR images. Persistent Scatterer Interferometric SAR (PSInSAR), an advanced version of InSAR, is an effective tool for measuring ground deformation using temporally stable reference points or persistent scatterers. We have applied both PSInSAR and Small Baseline Subset (SBAS) methods, based on the spatial correlation of interferometric phase, to estimate the ground deformation and time-series analysis. In this study, we select Las Vegas, Nevada, USA as our test area to detect the ground deformation along satellite line-of-sight (LOS) during November 1992–September 2000 using 44 C-band SAR images of the European Remote Sensing (ERS-1 and ERS-2) satellites. We observe the ground displacement rate of Las Vegas is in the range of ?19 to 8 mm/year in the same period. We also cross-compare PSInSAR and SBAS using mean LOS velocity and time-series. The comparison shows a correlation coefficient of 0.9467 in the case of mean LOS velocity. Along this study, we validate the ground deformation results from the satellite with the ground water depth of Las Vegas using time-series analysis, and the InSAR measurements show similar patterns with ground water data.     

Influence of forest fire episodes on the distribution of gaseous air pollutants over Uttarakhand,India

ABSTRACT

Widespread forest fire events occurred in the foothills of North Western Himalaya during 24 April to 2 May 2016 (Event-1) and 20–30 May 2018 (Event-2). Their impacts were investigated on the distribution of pollutant gases ozone (O₃), carbon monoxide (CO), and oxides of nitrogen (NOx) over Uttarakhand using simulations of Weather Research and Forecasting model coupled with chemistry (WRF-Chem) and in-situ observations of these gases over Dehradun, the capital of Uttarakhand. During Event-1, the observed CO mixing ratio over Dehradun increased from 25 April 2016 onwards, attained maximum (705.8 ± 258 ppbv) on 2 May 2016 and subsequently decreased. The rate of increase of daily baseline CO was 29 ppbv/day during HFAP (High Fire Activity Period). During Event-2, daily average concentrations of CO, O₃, and NOx showed systematic increase over Dehradun during HFAP period. The rate of increase of CO was 9 ppbv/day, while it was very small for NOx and O₃. To quantitatively estimate the influence of forest fire emissions, two WRF-Chem simulations were made: one with biomass burning (BB) emissions and other without BB emissions. These simulations showed 52% (34%) enhancement in CO, 52% (32%) enhancement in NOx, and 11% (9%) enhancement in O₃ during HFAP for Event-1 (Event-2). A clear positive correlation (r = 0.89 for Event-1, r = 0.69 for Event-2) was found between ?O₃ (O_{3with BB} minus O_{3without BB}) and ?CO (CO_{with BB} minus CO_{without BB}), indicating rapid production of ozone in the fire plumes. For both the events, the vertical distribution of ?O₃, ?CO, and ?NOx showed that forest fire emissions influenced the air quality upto 6.5 km altitude. Peaks in ?O₃, ?CO, and ?NOx during different days suggested the role of varying dispersion and horizontal mixing of fire plumes.     

Spectrophotometric Determination of Cationic Surfactants Based on Their Effect on the Complexes of Chrome Azurol S with Be2+ and Al3+ Cations

Simple, rapid, and sensitive spectrophotometric methods have been proposed for the determination of cationic surfactants (CS) as cetyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium (DTAB), and cetylpyridinium bromide (CPB). The methods are based on the effects of CSs on the complexes of Al³⁺ and Be²⁺ with Chrome Azurol S (CAS). The optimum reaction conditions such as CAS concentration, metal ion concentration, and pH have been studied and found to be 2.0 × 10^?4 mol L^?1 CAS, 0.5 mg L^?1 Al³⁺ or 0.4 mg L^?1 Be²⁺ and pH 5.4. The analytical characteristics of the methods such as limit of detections, limit of quantifications, and linear ranges have been obtained. CTAB, CPB, and DTAB could be determined by the Al–CAS complex in the ranges of 0.50–40.00, 0.20–10.00, and 0.40–10.00 µmol L^?1, and for the Be–CAS complex in the ranges of 0.08–5.00, 0.08–3.00, and 0.20–6.00 µmol L^?1, respectively. The limit of the detections of the method for the determination of CTAB, CPB, and DTAB for the Be–CAS complex has been found as 0.025, 0.024, and 0.061 µmol L^?1, respectively. The interfering effect of some anions and cations was also tested. The method was applied to the determination of CS CTAB in conditioner shampoo and water samples.     

Absorption and desorption of dichloromethane vapor by water drops in air. An experimental test of scavenging theory

An experimental study of the scavenging of dichloromethane vapor by water drops falling at terminal velocity, has been carried out in the UCLA precipitation shaft, in order to test the predictions of theoretical washout models. Whereas good agreement between theory and experiment was found for drops of radius 0.332 mm, computed gas uptake rates for 1.253 and 2.21 mm radius drops were much slower than those measured, just as reported previously for the washout of both sulfur dioxide and acetaldehyde. An analysis shows that theory can be reconciled with all of the experimental data by replacing the compound specific aqueous phase Fickian molecular diffusion coefficient used in the theory, by an effective diffusivity, having a constant value, (3×10^-4 cm² s^-1), independent of the physical and chemical nature of the absorbed species, for all drops of equivalent radii greater than 0.9 mm.     

Eddy diffusion in the upper atmosphere by global deposition of meteoroids

A theory for the production of eddy diffusion in the upper atmosphere by the global deposition of meteoroids is presented. It is based on the assumption that meteoroids falling on the Earth carry, on the average, a greater amount of orbital angular momentum per unit mass than that corresponding to the Earth's orbit. This excess of orbital angular momentum of the meteoroids is deposited in some or the other form during their interaction with the Earth's atmosphere. The softer material deposits the excess of its orbital angular momentum in a region slightly higher than the harder material and is held responsible for the superrotation observed in the atmosphere. It is shown that the other population of meteoroids which is metallic in nature deposits the excess orbital angular momentum below 100 km altitude and produces eddies. The size and velocity of the eddies so formed give the value of the vertical eddy diffusion coefficient in agreement with the upper limit set by Johnson and Wilkins (1965) from the study of downward heat transport in the atmosphere.     

Mixed boundary value problem in an elastic quarter-space

Summary The stress and displacement throughout a homogeneous, isotropic, elastic quarterspace have been evaluated when the stress is prescribed on one of the plane boundaries and the displacement on the other. The variations of the displacement and stress on the boundaries with time and distance from the origin have been shown graphically.     

On the scavenging of SO2 by cloud and raindrops: II. An experimental study of SO2 absorption and desorption for water drops in air

For the purpose of testing our previously described theory of SO₂ scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO₂ concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO ₂ absorption.The SO₂ concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO₂ in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO₂ in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO ₂ desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO₂ absorption was studied by means of drops containing various amounts of H₂O₂. For comparable exposure times to SO₂, the S concentration in drops with H₂O₂ was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.     

The impact of northern Indian Ocean rivers on the Bay of Bengal using NEMO global ocean model

The effect of river runoff over the northern Indian Ocean(NIO) especially over the Bay of Bengal(Bo B) has been studied using global Nucleus for European Modelling of the Ocean(NEMO). Two sensitivity experiments, with and without river runoff are conducted and the influence of river runoff on the Indian Ocean hydrography,stratification and circulation features are studied. It is found that due to river runoff surface salinity over the northern Bo B decreases by more than 5 and the East India Coastal Current strengthens by 2 cm/s during post monsoon season. The fresh river water reaches up to 15°N in the Bo B and is the main cause for low salinity there.Sea surface temperature in the northwestern Bo B increases by more than 0.2℃ due to the river runoff in summer monsoon while surface cooling upto 0.2℃ is seen in north-west part of Bo B in winter season. The seasonal mixed layer depth in the region is found to be dependent on river runoff. The effect of vertical shear and Brunt Vaisala frequency on stratification is also examined. The ocean water becomes highly stratified up to 3 035 m due to the river runoff. It is found that the energy required for mixing is high in the northern and coastal Bo B.