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1.
Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO2) in marine waters is described. An extractor—stripper removes CO2 that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH? ions for the titration of the acid formed by the reaction of CO2 and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO2 determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO3 into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l?1 was found for 17 samples of Bermuda coastal waters having a mean TCO2 of 2007.2 μmol l?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO2. 相似文献
2.
Arthur Kosowsky 《New Astronomy Reviews》2003,47(11-12):939
The proposed Atacama Cosmology Telescope (ACT) project is described. This multi-institution collaboration aims to produce arcminute-resolution and micro-Kelvin sensitivity maps of the microwave background temperature over 200 square degree of the sky in three frequency bands. We give a brief overview of the scientific motivations for such a map, followed by a design outline of our 6-m custom telescope, an overview of our proposed bolometer array detector technology, and site considerations and scan strategy. We also describe associated optical and X-ray galaxy cluster surveys. 相似文献
3.
Ecological characteristics of Walleye pollock eggs and larvae in the southeastern Bering Sea during the late 1970s 总被引:1,自引:0,他引:1
Kyung-Mi Jung Sukyung Kang Suam Kim Arthur W. Kendall Jr. 《Journal of Oceanography》2006,62(6):859-871
Walleye pollock (Theragra chalcogramma) is an ecologically and economically important groundfish in the eastern Bering Sea. Its population size fluctuates widely,
driving and being driven by changes in other components of the ecosystem. It is becoming apparent that dramatic shifts in
climate occur on a decadal scale, and these “regime shifts” strongly affect the biota. This paper examines quantitative collections
of planktonic eggs and larvae of pollock from the southeastern Bering Sea during 1976–1979. Mortality, advection, and growth
rates were estimated, and compared among the years encompassing the 1970s’ regime shift. These data indicate that pollock
spawning starts in late February over the basin north of Bogoslof Island. Over the shelf, most spawning occurs north of Unimak
Island near the 100 m isobath in early or mid April. Pollock eggs are advected to the northwest from the main spawning area
at 5–10 cm/sec. Larvae are found over the basin north of Bogoslof Island in April, and over the shelf between Unimak Island
and the Priblof Islands in May. Compared to 1977, the spawning period appeared to be later in 1976 (a cold year) and earlier
in 1978 (a warm year) in the study area. At the lower temperatures in 1976, egg duration would be longer and thus egg mortality
would operate over a longer period than in the other years. Mean larval growth appeared to be lower in 1976 than in 1977 and
1979. Estimated egg mortality rate in 1977 was 0.6 in April and 0.3 in early May. 相似文献
4.
Roles of Continental Shelves and Marginal Seas in the Biogeochemical Cycles of the North Pacific Ocean 总被引:4,自引:0,他引:4
Chen-Tung Arthur Chen Andrey Andreev Kyung-Ryul Kim Michiyo Yamamoto 《Journal of Oceanography》2004,60(1):17-44
Most marginal seas in the North Pacific are fed by nutrients supported mainly by upwelling and many are undersaturated with
respect to atmospheric CO2 in the surface water mainly as a result of the biological pump and winter cooling. These seas absorb CO2 at an average rate of 1.1 ± 0.3 mol C m−2yr−1 but release N2/N2O at an average rate of 0.07 ± 0.03 mol N m−2yr−1. Most of primary production, however, is regenerated on the shelves, and only less than 15% is transported to the open oceans
as dissolved and particulate organic carbon (POC) with a small amount of POC deposited in the sediments. It is estimated that
seawater in the marginal seas in the North Pacific alone may have taken up 1.6 ± 0.3 Gt (1015 g) of excess carbon, including 0.21 ± 0.05 Gt for the Bering Sea, 0.18 ± 0.08 Gt for the Okhotsk Sea; 0.31 ± 0.05 Gt for
the Japan/East Sea; 0.07 ± 0.02 Gt for the East China and Yellow Seas; 0.80 ± 0.15 Gt for the South China Sea; and 0.015 ±
0.005 Gt for the Gulf of California. More importantly, high latitude marginal seas such as the Bering and Okhotsk Seas may
act as conveyer belts in exporting 0.1 ± 0.08 Gt C anthropogenic, excess CO2 into the North Pacific Intermediate Water per year. The upward migration of calcite and aragonite saturation horizons due
to the penetration of excess CO2 may also make the shelf deposits on the Bering and Okhotsk Seas more susceptible to dissolution, which would then neutralize
excess CO2 in the near future. Further, because most nutrients come from upwelling, increased water consumption on land and damming
of major rivers may reduce freshwater output and the buoyancy effect on the shelves. As a result, upwelling, nutrient input
and biological productivity may all be reduced in the future. As a final note, the Japan/East Sea has started to show responses
to global warming. Warmer surface layer has reduced upwelling of nutrient-rich subsurface water, resulting in a decline of
spring phytoplankton biomass. Less bottom water formation because of less winter cooling may lead to the disappearance of
the bottom water as early as 2040. Or else, an anoxic condition may form as early as 2200 AD.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
5.
Toshiro Saino Alexander Bychkov Chen-Tung Arthur Chen Paul J. Harrison 《Journal of Oceanography》2004,60(1):1-4
This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean
Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific
Synthesis Group, with the aim of quantifying CO2 drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual
variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and
differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the
future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief
overview of the papers from view points of CO2 drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales
is made, followed by suggestions for the directions of future research.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm−2 sec−1, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca2+, Mg2+) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine). 相似文献
7.
The simplest, conventional, and original form of the circular restricted problem of three bodies is briefly described in sidereal and synodic systems using dimensional and non-dimensional variables. This dynamical system is generalized to n2 primary bodies (from n=2) with masses Mi, 1in, interacting with arbitrary force laws (instead of only gravitational forces). The number of bodies of small mass mMi not perturbing the primaries is increased from =1 to 1 where 1 and the minor bodies are allowed to interact with one another under arbitrary force laws. While the minor bodies (m) do not affect the motions of the primaries (Mi), the primaries influence the motions of the minor bodies with arbitrary force laws.For the case where n=2, 1, and only gravitational forces act on the system, an integral of the system is derived. It is shown that the energy integral of the general problem of N bodies and the Jacobian integral of the classical restricted problem of three bodies are limiting cases of this integral. The role of the integral in bounding the motion of the minor bodies is discussed. Several applications of this system are given. 相似文献
8.
A study of the background corona near solar minimum 总被引:2,自引:0,他引:2
The white light coronagraph data from Skylab is used to investigate the equatorial and polarK andF coronal components during the declining phase of the solar cycle near solar minimum. Measurements of coronal brightness and polarization brightness product between 2.5 and 5.5R
during the period of observation (May 1973 to February 1974) lead to the conclusions that: (1) the equatorial corona is dominated by either streamers or coronal holes seen in projections on the limb approximately 50% and 30% of the time, respectively; (2) despite the domination by streamers and holes, two periods of time were found which were free from the influences of streamers or holes (neither streamers nor holes were within 30° in longitude of the limb); (3) the derived equatorial background density model is less than 15% below the minimum equatorial models of Newkirk (1967) and Saito (1970); (4) a spherically symmetric density model for equatorial coronal holes yields densities one half those of the background density model; and (5) the inferred brightness of theF-corona is constant to within ±10% and ±5% for the equatorial and polar values, respectively, over the observation period. While theF-corona is symmetric at 2R
it begins to show increasing asymmetry beyond this radius such that at 5R
the equatorialF-coronal brightness is 25% greater than the polar brightness.The National Center for Atmospheric Research is sponsored by the National Science Foundation. 相似文献
9.
10.
Only a few very young landforms are the result of currently operating geomorphic processes. Because the time scale for landscape evolution is much longer than the time scale for late Cenozoic climate changes, almost all landscapes are palimpsests, written over repeatedly by various combinations of climate-determined processes. Relict glacial and periglacial landforms are widely identified in mid-latitude regions that have been traditionally described as having been shaped by the “normal” processes of fluvial erosion. Less confidently, deeply weathered regolith and associated relict landforms in the middle and high latitudes are attributed to early Tertiary warmth. However, assemblages of geomorphic processes specific to certain climatic regions, like faunal and floral assemblages, cannot be translated across latitude, so in spite of the many books about the geomorphology of specific modern climate regions, there are few sources that discuss former warm high-latitude, or cold low-latitude, low-altitude geomorphic processes that have no modern analogs. Students and teachers alike who attempt to interpret landforms by extrapolating modern climatic conditions to other latitudinal zones will find their outlook broadened, and they become better prepared to consider the geomorphic impacts of global climate change. 相似文献