Ultrahigh pressure macro diamonds from Copeton (New South Wales, Australia), based on Raman spectroscopy of inclusions

Mining of Cenozoic alluvial deposits at Copeton and Bingara (Eastern Australia) has produced two million macrodiamonds (0.25 ct median size). Raman spectroscopy is used to identify included minerals within uncut Copeton diamonds, with sealed chamber remnant pressures of 31.7 to 35.6 kbar for coesite, 13.6 and 22.7 kbar for clinopyroxene, and 7.6 kbar for grossular garnet. Assuming elastic behaviour, these values generate inclusion entrapment PT loci which intersect, restricting diamond formation conditions: from 250 °C, 43 kbar to 800 °C, 52 kbar. Larger than error (± 100 °C and ± 4 kbar), this range shows a systematic variation in inclusion composition with diamond zoning and N properties. Published research shows 1) Copeton and Bingara diamonds are unique, and 2) modern alluvium in the Bingara district carries mantle-formed garnet, captured by post-tectonic alkali basalt from an extensive diamondiferous ultrahigh pressure (UHP) terrane that stalled at depth because it is dominated by mafic eclogite. The combined Raman and geological results indicate two sets of subduction UHP diamond formation conditions/protolith are required, firstly cooler oceanic slab and secondly including higher temperature continental crust. The Copeton and Bingara stones are UHP macrodiamonds, and Carboniferous ⁴⁰Ar/³⁹Ar age dates on clinopyroxene inclusions should be interpreted as ages of crystallisation, representing the termination of subduction. The characteristic features of ruptured inclusions and etched percussion marks on Copeton and Bingara diamond indicate volcanic delivery to the earth's surface. Alluvial deposits elsewhere in Eastern Australia may carry similar diamond along with diamond of different origin.     

Organic carbon deposition and phosphorus accumulation during Oceanic Anoxic Event 2 in Tarfaya, Morocco

With a multi-proxy approach, an attempt was made to constrain productivity and bottom-water redox conditions and their effects on the phosphorus accumulation rate at the Mohammed Plage section on the Tarfaya coast, Morocco, during the Cenomanian-Turonian Anoxic Event (OAE 2). A distinct δ¹³C_org isotope excursion of +2.5‰ occurs close to the top of the section. The unusually abrupt shift of the isotope excursion and disappearance of several planktonic foraminiferal species (e.g. Rotalipora cushmani and Rotalipora greenhornensis) in this level suggests a hiatus of between 40–60 kyrs at the excursion onset. Nevertheless, it was possible to determine both the long-term environmental history as well as the processes that took place immediately prior to and during OAE 2. TOC% values increase gradually from the base of the section to the top (from 2.5% to 10%). This is interpreted as the consequence of a long-term eustatic sea-level rise and subsidence causing the encroachment of less oxic waters into the Tarfaya Basin. Similarly a reduction in the mineralogically constructed ‘detrital index’ can be explained by the decrease in the continental flux of terrigenous material due to a relative sea-level rise. A speciation of phosphorus in the upper part of the section, which spans the start and mid-stages of OAE 2, shows overall higher abundances of P_reactive mass accumulation rates before the isotope excursion onset and lower values during the plateau. Due to the probable short hiatus, the onset of the decrease in phosphorus content relative to the isotope excursion is uncertain, although the excursion plateau already contains lower concentrations. The C_org/P_total and V/Al ratios suggest that this reduction was mostly likely caused by a decrease in the available bottom oxygen content (probably as a result of higher productivity) and a corresponding fall in the phosphorus retention ability of the sediment. Productivity appears to have remained high during the isotope plateau possibly due to a combination of ocean-surface fertilisation via increased aridity (increased K/Al and Ti/Al ratios) and/or higher dissolved inorganic phosphorus content in the water column as a result of the decrease in sediment P retention. The evidence for decreased P-burial has been observed in many other palaeoenvironments during OAE 2. Tarfaya's unique upwelling paleosituation provides strong evidence that the nutrient recycling was a global phenomenon and therefore a critical factor in starting and sustaining OAE 2.     

Temporal characteristics of aerosol physical properties at Visakhapatnam on the east coast of India during ICARB — Signatures of transport onto Bay of Bengal

Realizing the importance of aerosol physical properties at the adjoining continental and coastal locations in the airmass pathways onto the oceanic region, extensive measurements of aerosol physical properties were made at Visakhapatnam (17.7°N, 83.3°E), an eastern coastal location in peninsular India during the ICARB period. The temporal variations of aerosol optical depth, near surface aerosol mass size distributions and BC mass concentrations show significantly higher aerosol optical depth and near surface mass concentrations during the first and last weeks of April 2007. The mean BC mass fraction in the fine mode aerosol was around 11%. The aerosol back scatter profiles derived from Micro Pulse Lidar indicate a clear airmass subsidence on the days with higher aerosol optical depths and near surface mass fraction. A comparison of the temporal variation of the aerosol properties at Visakhapatnam with the MODIS derived aerosol optical depth along the cruise locations indicates a resemblance in the temporal variation suggesting that the aerosol transport from the eastern coastal regions of peninsular India could significantly affect the aerosol optical properties at the near coastal oceanic regions and that the affect significantly reduced at the farther regions.     

Observations of unusual whistlers during daytime at Jammu

In this paper, we report observations of unusual whistlers recorded at Jammu (geomag. lat. = 22°26′N; L = 1.17), India on March 8, 1999 during the daytime. They are interpreted as one-hop ducted whistlers having propagated along higher L-values in closely spaced narrow ducts from the opposite hemispheres. After leakage from the duct, the waves might have propagated in the earth-ionosphere waveguide towards the equator in surface mode. Tentative explanation of the dynamic spectra of these events is briefly presented.     

New evidence of the Littorina transgressions in the Kattegat: Optically Stimulated Luminescence dating of a beach ridge system on Anholt, Denmark

Recent geomorphological and sedimentological investigation of the raised beach ridge plain on Anholt in the Kattegat Sea, Denmark, has demonstrated how these deposits, when combined with Optically Stimulated Luminescence (OSL) dating, can provide information about past changes in relative sea level. The southwest–northeast trending plain is divided into three topographic levels, one of which has been surveyed using Ground-Penetrating Radar (GPR). Samples retrieved from the survey line indicate that the initial part of the beach ridge plain formed about 7700 years ago in response to a mid-Holocene Littorina transgression. The raised marine deposits document a subsequent rise in relative sea level of about 9 m, and OSL dates indicate that this transgression took place about 6650 years ago. The flooding of the Kattegat Sea 7700 years ago might possibly be related to a rapid global sea-level rise peaking around 7500 years ago.     

A comparative study of four vulnerability mapping methods in a detritic aquifer under mediterranean climatic conditions

This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods, GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space, with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes (“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila aquifer.     

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.     

Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.     

Design of shallow foundations under tensile loading for transmission line towers: An overview

Tensioned foundations are common in civil engineering applications such as transmission towers, harbors, offshore structures, basement slabs under pressure, industrial equipment, etc. Procedures for the design of tensioned foundations are discussed in this paper, including specific recommendations for more common transmission tower foundations. Starting from a distinction between shallow and deep modes of failure, the paper presents the most common failure mechanisms for shallow failure in tension, including procedures for calculation of foundation tensile capacity under vertical and inclined loading. Emphasis is given to the influence of the strength of the compacted backfill compared to the strength of the natural soil, including presentation of results of full-scale loading tests.     

Saturation of groundwaters with respect to minerals of the host rocks

Calculations of the saturation of groundwaters with respect to minerals of the rocks hosting these waters indicate that most of the analyzed groundwaters were saturates with respect to calcite, dolomite, and quartz. Brines of chloride-calcic composition were determined to be saturated with respect to calcite, whereas brines of chloride-sodic composition are saturated with respect to dolomite and quartz. The solution was simultaneously saturated with respect to six minerals for the association ankerite-calcite-dolomite-pyrite-quartz-strontianite. An increase in the number of minerals with respect to which solution is saturated is correlated with an increase in the diversity of types of groundwaters and an increase in the runoff rate. The paper proposes possible avenues for searches for relations between hydrogeological and geochemical parameters that make it possible to adapt the thermodynamic models to real geological-hydrogeological conditions. The research was centered on the testing of groundwaters for their saturation with respect to minerals of the rocks hosting these waters. This parameter plays a significant part in forming the geochemical type of natural waters because it reflects the crystallization of a mineral from a solution and, consequently, the removal of an element from the aqueous solution.