Effect of freezing and thawing on the permeability and structure of soils

The permeability and structure of four fine-grained soils were observed to be changed by freezing and thawing. In all cases freezing and thawing caused a reduction in void ratio and an increase in vertical permeability. The increase in permeability is attributed to the formation of polygonal shrinkage cracks and/or to the reduction of the volume of fines in the pores of the coarse fraction, the mechanism controlling the process depending on material type. No definite relationships are established; however, it appears that the largest increase in permeability occurs for the soil of highest plasticity.     

Second order elasticity theory: An improved formulation of the Grüneisen parameter at high pressure

The second order theory of elasticity, in which terms to second order in strain are retained in calculating atomic bond length changes and elastic moduli, is extended to describe thermal vibration of a face-centred cubic crystal. Coupled with equations relating the pressure dependences of elastic constants, this yields a new formulation of the thermal Grüneisen parameter γ in terms of pressure P, incompressibility K and rigidity, μ

$\text{λ}\text{1}\text{2}\text{d}\text{K}\text{d}\text{P}\text{?}\text{1}\text{2}\text{+}\text{1}\text{9}\text{P}\text{K}\text{?}\text{1}\text{3}\text{?}\text{1}\text{9}\text{P}\text{K}\text{f}\text{1?}\text{2}\text{3}\text{P}\text{K}\text{?}\text{2}\text{3}\text{P}\text{K}\text{f}$

where f = 24 (3 K ? 2 P)/(3 K + 115 μ + 90 P). The factor f arises from bond interactions and the case f = 1, representing independent bonds (no interactions), yields the free-volume γ- Since we have shown earlier that the second order elasticity theory provides a convincing explanation of the elasticity of the inner core, we believe that the new formula is appropriate for the inner core. It is, however, inadequate to describe the lower mantle γ, in which atomic bond angle rigidity, not considered here, may be appreciable.     

Assessment of textural variational pattern and electrical conduction of economic and accessible Quaternary hydrolithofacies via geoelectric and laboratory methods in SE Nigeria: A case study of select locations in Akwa Ibom State

Textural variational pattern of economic and accessible Quaternary aquifer repositories and its conductivity in the south-eastern Nigeria have been assessed through the integration of vertical electrical sounding and laboratory measurements. The results have shown the lithological attributes, pore-water and amount of residual clay minerals in the assumed clean sand; mechanism of charge fixation at the fluid - surface interface; intricate geometry of pores and pore channels; formation’s ability to transmit pore-water and cation exchange capacity.The connections of electrical and hydraulic properties and their distributions have been established. The average interface conductivity contributed by residual clay minerals in assumed clean sands of the aquifer repositories in the study area have been estimated as 30µS/m. Intrinsic average porosity and formation factor have been respectively deduced as 12% and 14.75. Comparing the simulated aquifer formation factor obtained from the observed porosity data with the observed aquifer formation factor, indicates the that study area has 0.5 ≤ a ≤ 0.8 pore geometry factor and 1.5 ≤ m ≤ 2.0 cementation factor as the best fitting values. The interrelations between aquifer parameters have been established through different plots and the aquifer have been empirically proved to be associated with residual clay minerals as the interface conductivity C_q is not equal to zero. The wide ranges of parameters estimated are an indication of variations in grain size. The estimated intrinsic average porosity, formation factor and the average BQ_v are viable in characterizing the aquifer flow dynamics and contaminant modelling in the associated aquifer sands For low pore geometry factors a (0.2) and low cementation factor m (0.5) the formation factor remains fairly constant. However, marked variability is noticed at higher a (1.0) and m (2.5). Despite the observed variability in formation factors at the indicated porosities, the spatial or geometrical spread of the formation factor remains unchanged in the aquifer units. The Tables for geoelectric and petrophysical parameters and the associated mathematical models generated in this study can be used for groundwater contaminant modelling and simulation of pore space parameters with reasonable accuracy.     

Inferring salinity from temperature or depth for dynamic height computations in the north pacific

Abstract

A computational method is developed where salinities inferred from mean salinity profiles (computed from all available data) are used to calculate 0/500 db dynamic height from temperature profiles. Using data from Ocean Weather Station P (50°N, 145°W), the method yielded a much smaller uncertainty in inferred 0/500 db dynamic height (～3 dyn cm) than that found using a mean temperature‐salinity relationship (～10 dyn cm). Applied to historical hydrographic data averaged over 5° squares in the North Pacific (north of 30°N), the method led to inferred dynamic‐height uncertainties typically less than 4 dyn cm in the region north of the Subarctic Front (～40°N). In this same region, dynamic heights inferred from mean temperature‐salinity curves had large uncertainties. South of the Subarctic Front, the dynamic‐height uncertainties associated with the temperature‐salinity curves were smaller than those computed with the mean salinity profiles. A combination of these two methods was used to compute inferred dynamic height from a climatology of temperature structure in the region from 30–50°N, 130°W‐150°E.     

Current approaches to MRV in South Africa: a scoping study

It is shown that there are MRV-related activities underway in South Africa, particularly focusing on measuring electricity consumption and monitoring GHG emissions. Yet currently many of these activities happen in parallel systems within multi-polar governance structures. A bottom-up perspective of MRV in South Africa, informed by interviews, workshops, desktop research, and stakeholder consultations, is provided and the systems, data, methodologies, and the institutional environment relevant to a South African MRV system are examined. The development of the local monitoring and evaluation system, and its relevance within the international MRV context, is also discussed. Some recommendations are made: most importantly, there is a need for a coherent approach to be developed, one that is coordinated by government and built on existing MRV systems.     

Reply to ‘Comment on “The beginnings of hydrous mantle wedge melting” by Till et al.’ by Green, Rosenthal and Kovacs

The comment of Green et al. debates the interpretation of the temperature of the H₂O-saturated peridotite solidus and presence of silicate melt in the experiments of Till et al. (Contrib Mineral Petrol 163:669–688, 2012) at <1,000?°C. The criticisms presented in their comment do not invalidate any of the most compelling observations of Till et al. (Contrib Mineral Petrol 163:669–688, 2012) as discussed in the following response, including the changing minor element and Mg# composition of the solid phases with increasing temperature in our experiments with 14.5?wt% H₂O at 3.2?GPa, as well as the results of our chlorite peridotite melting experiments with 0.7?wt% H₂O. The point remains that Till et al. (Contrib Mineral Petrol 163:669–688, 2012) present data that call into question the H₂O-saturated peridotite solidus temperature preferred by Green (Tectonophysics 13(1–4):47–71, 1972; Earth Planet Sci Lett 19(1):37–53, 1973; Can Miner 14:255–268, 1976); Millhollen et al. (J Geol 82(5):575–587, 1974); Mengel and Green (Stability of amphibole and phlogopite in metasomatized peridotite under water-saturated and water-undersaturated conditions, Geological Society of Australia Special Publication, Blackwell, pp 571-581, 1989); Wallace and Green (Mineral Petrol 44:1–19, 1991) and Green et al. (Nature 467(7314):448–451, 2010).     

Two-dimensional modelling of some CFC replacement compounds

The Cambridge 2-D Eulerian model has been used to study the potential atmospheric distributions and lifetimes of a number of CFC replacement compounds and their degradation products. The study has focused on HFC 134a and HCFCs 123, 141b and 142b and the major products formed by their atmospheric degradation. The loss of these compounds and their products by hydroxyl radical attack, photolysis and in-cloud hydrolysis have been investigated. The study has shown that HCFCs 141b and 142b have sufficiently long lifetimes to enter the stratosphere in significant quantities, where degradation leads to an increase in the total stratospheric chlorine concentration. The study has also highlighted areas where further experimental work would be valuable, in particular characterisation of the product channels for the degradation reactions and determination of the removal rates of the products in the aqueous phase.     

A Ca ii H&K survey of γ Doradus candidates

In an investigation of the starspot hypothesis as it applies to the 'slowly variable' F-type dwarfs, we spectroscopically observed eight promising γ Doradus candidates to search for Ca  ii H&K emission. We found that there are no significant emission reversals in the cores of these resonance lines. Based on the ceiling flux calculations of the Ca  ii K line and on calculations of the Rossby number, we conclude that there is no support for the presence of strong magnetic activity and the starspot hypothesis in these objects.