Reversing Water Exchange Patterns at the Entrance to a Semiarid Coastal Lagoon

Water velocity and density profiles were obtained in late-spring and late-winter to document reversing mean circulation patterns at the entrance to a semiarid coastal lagoon, the Bay of Guaymas, in the Gulf of California, Mexico. The lagoon is shallow but the bathymetry at its entrance is similar to that of temperate estuaries with an asymmetrically positioned channel flanked by shoals. In late-spring the mean circulation at the entrance to the lagoon was driven by horizontal density gradients that arose from excess evaporation over precipitation in the area as evidenced by water density profiles. The lagoon exported relatively warm (25·8 °C) and salty (36·2) water to the Gulf of California through the channel. This export was consistent with inverse estuarine circulation influenced by bathymetry. In late-winter, the circulation at the entrance of the lagoon was mostly driven by wind stress that blew from the northwest, roughly along the main axis of the lagoon. Relatively cool (16·0) °C) and less salty (35·1) water from the Gulf of California was driven into the lagoon within the channel. Density gradients inside the lagoon seem to have played a secondary role in driving the circulation. The late-winter circulation was then estuarine-like, with outflow in the direction of the wind over the shallow areas and a compensatory inflow appearing in the channel as expected from theory of wind-driven flow over bathymetry. This estuarine-like circulation developed despite the lack of measurable freshwater input to the lagoon and was the opposite to that observed in late-spring. These observations then document a reversal in water exchange patterns from season to season in a semiarid coastal lagoon. The observations also constitute one of the few reported examples of flow over shoals driven in the same direction as the wind stress with a compensatory flow in the channel.     

Effects of pulp bleach plant effluents on hepatic xenobiotic biotransformation enzymes in fish: Laboratory and field studies

The present preliminary report on studies of the influence of pulp bleach plant effluents on hepatic biotransformation enzymes in fish is a part of a major characterisation of biochemical and physiological effects of effluents from pulp industries in Sweden. Our studies on the xenobiotic biotransformation enzymes demonstrate, so far, that the pulp effluents have the potential to strongly induce 7-ethoxyresorufin-O-deethylase activity (EROD) in fish liver and that fish living in the receiving water of an effluent from a pulp bleach plant have induced hepatic EROD activities as well as higher hepatic UDP glucuronyltransferase activities than those living in an unpolluted area. It is thus apparent that measures of induction of biotransformation enzymes in fish liver may be a useful approach in monitoring the presence of potential hazardous compounds released from pulp industries.     

Tectonic control over topography and channel sedimentation across the forearc slope of the southern Kurile Trench

A high-resolution seismic survey covering more than 2,000 km² has revealed the processes responsible for the slope morphology and channel sedimentation across the forearc slope-basin of the Kurile Arc–NE Japan Arc collision zone, offshore from Tokachi (Hokkaido, Japan). The dominant slope contours parallel the trench but, in the middle and lower reaches of the southern slope, contours are convex-shaped with an offshore trend. This sector of the slope is traversed diagonally by the Hiroo submarine channel. The offshore-trending convex contours and the channel course have developed through the interplay of tectonic and sedimentary processes, including the development of anticlines, anticline-induced lobe sedimentation and channel avulsion. In its upper reaches, the channel is restricted by a topographic low associated with NNW–SSE-trending anticlines which developed within the upper and middle slope sectors during late Miocene uplift. The uplift timing and trend of these anticlines indicate that they resulted from collision, the channel sedimentology and slope morphology of the middle and lower slopes having been influenced by Pliocene uplift of NE–SW-trending anticlines. The trends of these anticlines parallel those of the Kurile Trench. The Pliocene and early Pleistocene strata of the middle and lower slopes consist of ponded lobe sediments deposited along the palaeo-Hiroo submarine channel on the landward side of the anticlines. As a lobe pile accumulated, the channel thalweg shifted to the north of the stack, allowing the channel to bypass the topographic high formed by the growing stack. Thick levee deposits built up along the channel course during the late Pleistocene and Holocene. These levees, along with the Pliocene and early Pleistocene lobes, are reflected in the present-day sigmoid-shaped, convex offshore-trending contours. Thus, the interplay of subduction- and collision-related anticlines, tectonic-related channel ponding, and avulsion has contributed to the slope morphology of the southern Kurile Trench.     

Prolonged Magmatic and Tectonic Development of the Caribbean Igneous Province Revealed by a Diving Submersible Survey

Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by ⁴⁰Ar/³⁹Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces.     

Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Evaluation of drift current parameters using an analytical model

The paper is concerned with the evaluation of the drift current parameters derived through the use of an analytical model. In this model, effective when stratification is stable and indifferent, the vertical turbulence coefficient profile is prescribed by the power function, and hydrodynamic quantities are prescribed using the external parameters of the problem (wind stress, the Coriolis parameter, and the dimensionless stratification parameter). Model data are compared with the observations of the upper mixed layer in the vicinity of the oceanic Station C, conducted during one year. It is shown that, under the spring-summer-time warming conditions, the model at issue is capable of adequately simulating the upper ocean layer dynamics. Translated by Vladimir A. Puchkin.     

Seasonal course of theT,S-characteristics in the north-eastern Tropical Atlantic

The problem of the seasonal variations of temperature and salinity in the intermediate zone located between the West African and the Gulf of Guinea upwellings is considered. The vertical distribution of the phase-amplitude characteristics of the annual and semi-annual variations is examined in good detail and their parameters are defined from the monthly means using the least-squares fit technique. The contribution of isopycnic advection to the formation of seasonal thermohaline variations is studied.Translated by Vladimir A. Puchkin.