The dark side of Iapetus

This paper presents new photometric and spectrophotometric observations of the dark (leading) hemisphere of Saturn's satellite Iapetus. Spectrophotometry from 0.3–1.0 um (May 1979) shows the dark hemisphere to be very red, similar to a few asteroids and the Moon, but with no spectral features attributable to olivine or pyroxene. Near-infrared spectrophometry in the regions 1.4–2.5 um (May 1981) and 3.0–3.8 um (February 1981) reveals water ice absorption bands, probably resulting from the polar caps intruding onto the dark hemisphere. The reflectance of Iapetus is unlike that of carbonaceous chondrites or C-type asteroids and most closely resembles the reflectance (and low albedo) of carbonaceous (organic) residue from the Murchison C2 carbonaceous chondrite. The Murchison material has the same red slope and a probable spectral feature near 0.6 um seen in Iapetus data. Three hypotheses for the formation of the dark hemisphere are discussed in light of the observational data. The favored hypothesis is that debris from Phoebe or other unknown outer satellites of Saturn impacts the dark hemisphere of Iapetus as Poynting-Robertson drag causes the debris to spiral toward Saturn. The high-velocity impacts preferentially remove ice from the satellite's surface, causing enrichment of included carbonaceous material intrinsic to Iapetus. The reflectance of Phoebe itself is significantly different from that of Iapetus, suggesting that relatively little Phoebe debris lies on the dark hemisphere. There remains the possibility that the impacting debris originates from another body of composition similar to the Murchison residue and that this material is exposed on the surface of Iapetus.     

On the accuracy of mode superposition analysis in structural dynamics

It is pointed out that the number of modes which should be included in a mode superposition dynamic response analysis depends on both the frequency content and the distribution of the loading. If the loading frequency is low the effect of the higher modes can be approximated by a static analysis. A technique is described for calculating this static contribution from the higher modes; the total response is then represented by the sum of the lower mode dynamic response and the higher mode static effects. The effectiveness of the procedure is demonstrated by a numerical example.     

A 2000‐year lipid biomarker record preserved in a stalagmite from north‐west Scotland

Previous studies on lipid biomarkers preserved in Chinese stalagmites have indicated that ratios of low‐molecular‐weight (LMW) to high‐molecular‐weight (HMW) n‐alkanes, n‐alkan‐2‐ones, n‐alkanols and n‐alkanoic acids can be used as an index of vegetation versus microbial organic matter input to the system and, by extension, a marker of climatic changes, with increases in the proportion of LMW compounds coinciding with colder periods. Here we test whether this hypothesis is equally applicable to a different geographical region (north‐west Scotland), by examining a stalagmite record of the past 200 years, and a wider range of lipid markers. We also test the applicability of other lipid proxies in this context, including the use of n‐alkane ratios, to interpret vegetation changes, and unsaturated alkanoic acid ratios as climatic indicators. The results show that lipid proxies preserved in stalagmites, and especially those related to vegetation, are potentially extremely useful in palaeoenvironmental research. Of particular value is the use of C₂₇/C₃₁ n‐alkane ratios as a proxy for vegetation change, clearly indicating variations between herbaceous and arboreal cover. This proxy has now been successfully applied to samples from diverse environments, and can be considered sufficiently robust to be of use in analysing future stalagmite records. It will be of particular value in areas where reliable pollen records are not available, as is often the case with deeper cave deposits. However, the division between LMW and HMW aliphatic compounds is not a clear‐cut case of microbial versus plant activity, with the changes in LMW compounds relating more closely to those in their HMW analogues than in specific bacterial biomarkers. The use of unsaturated alkanoic acid ratios here gives conflicting results, with the observed variation through time depending on the isomer measured. The discrepancies between the findings of this study and previous work are likely to be due to the varying controls on the lipids (original organic matter input, and compound degradation), which in turn will be affected by whether the main climatic limiting factor on the soil is temperature or precipitation. This suggests that lipid proxies preserved in stalagmites must be interpreted with care, particularly in the case of bacterial compounds which may be derived from within the cave or from the soil. However, many of these issues can be resolved by the use of multi‐proxy studies. Copyright © 2011 John Wiley & Sons, Ltd.     

Corrections for Wind-Speed Errors from Sodar and Lidar in Complex Terrain

The quality of lidar and sodar wind estimates is generally judged through comparisons with mast-mounted instruments, and the resulting regressions. Evaluation of the relative merits of lidars versus sodars is complicated by the fact that lidars are generally placed close to a mast whereas sodars are generally placed some distance from a mast so that acoustic reflections off the mast are reduced. This leads to the two technologies, lidar and sodar, not being compared in similar situations. Differences arising from the two geometries can be expected to be larger in complex terrain, where the wind regime can vary significantly spatially. The current work explores these differences in moderately complex terrain. Lidar–mast comparisons are performed with the lidar close to an 80 m mast, and sodar–mast comparisons performed with the sodar 300 m from the mast. Systematic variations in estimated wind speed are found to occur with height, consistent with predictions from a simple flow model. When the lidar was moved to the sodar location, further from the mast, there were significant changes in the estimated wind speeds and a reduction in correlation with the mast-based wind speeds, as expected. However, the correlation between collocated lidar and sodar winds was high. This finding emphasizes that any comparison of two remote sensing instruments needs to be through similar experiments, and that differences in accuracy often reported for the lidar and sodar technologies are likely to be contaminated due to poor comparison configurations. A method was devised to simulate the sodar being collocated with the mast, by using the lidar–sodar measurements and the lidar–mast measurements. It was found that there was then no statistically detectable difference between lidar–mast regressions and sodar–mast regressions for the particular lidar and sodar tested. Both remote sensing instruments were also found to be good estimators of Weibull parameters, as compared with those derived from mast data. The conclusion is that the sodar measured the winds above the sodar with a similar accuracy to the lidar measuring winds above the lidar.     

Optical and chemical analysis of iron in Luna 20 plagioclase

The iron content of Luna 20 anorthitic plagioclase ranges from a few hundredths to a few tenths of a weight per cent from crystal to crystal. Rather than being related to the original composition of the parent magma or magmas, the optical and chemical properties of the iron appear to be caused by postcrystallization migration and exsolution.Oriented inclusions of iron alloy present as needle-like crystals are observed, and the host plagioclases are irregularly chemically zoned in iron. It is not known whether thermal metamorphism or another process of chemical reduction related to impact and shock is responsible for the observed phenomena. Postcrystallization effects may obscure evidence of the original oxidation state and iron concentration of these crystals.     

Commonwealth Urban Policy in Australia: the case of inner urban regeneration in Sydney, 1973–75

Urban regeneration has intermittently been identified within Commonwealth policy circles as central to the functioning of Australian cities since the 1940s. This paper adds to existing knowledge by exploring the role of the Commonwealth Department of Urban and Regional Development (DURD) in the 1970s in facilitating a series of urban regeneration projects in Sydney. Drawing upon ministerial correspondence and minutes recently out of confidential embargo, the genesis of a holistic urban regeneration agenda is explored. The paper traces the approaches to Commonwealth intervention at a time marked by disillusionment with the comprehensive redevelopment paradigm. It explores the relationships and tensions apparent between and within different levels of government in establishing a Commonwealth presence, focusing on three inner city neighbourhoods: Waterloo, Glebe and Woolloomooloo. The significance of the interventions is considered to lie primarily in the pioneering of an all-of-government approach to urban governance.     

Development of Specimen Curing Procedures that Account for the Influence of Effective Stress During Curing on the Strength of Cemented Mine Backfill

Paste backfill used to provide ground support in underground mining is generated from full-stream tailings and is almost always placed underground with cement. For the backfill, both the rate of strength development and the final strength are important considerations for design, particularly when the backfill is subsequently exposed in the stope-mining sequence. There is strong evidence that strengths measured on specimens obtained from coring the in situ cemented backfill are much greater than laboratory-cured specimens with the same cement content. The paper reviews some of the experimental evidence showing that one of the major reasons for the different strength is the difference in effective stress acting on the backfill during curing. Laboratory specimens are (almost) always cured under zero total stress, so no effective stress develops. In contrast, backfill in a stope may cure under high effective stress, which develops due to either “conventional” consolidation in free-draining backfills, or to the so-called “self-desiccation” mechanism in fine-grained fills. Evidence is presented showing how the final strength is affected by applying stress to specimens at different stages of curing and at different rates. It is shown that a fully-coupled analysis of the filling behaviour is required to determine the appropriate effective stress regime to apply in curing laboratory specimens, where “fully-coupled” in this context means taking account of the interaction of consolidation/drainage rate, filling rate and cement hydration rate. Curing protocols for laboratory specimens are proposed, which would ensure that the strengths obtained are representative of in situ conditions.     

Setting new thermal standards for transitional and coastal (TraC) waters

The construction of a new generation of coastal power stations in the UK and other western European countries has highlighted the absence of robust standards for thermal discharges to transitional and coastal waters. The proposed discharge volumes are greater than hitherto, yet there has been little independent critical examination of their potential impact, whilst much of the existing guidance has been adapted from freshwater practice. This review considers the available knowledge on the tolerance and behaviour of fish and other marine biota to heated effluents. Appropriate ways are suggested of grouping fish species to reflect their sensitivity to thermal effects. The plethora of existing standards are considered and their validity assessed in a framework of predicted seawater temperature rise. Those species or groups of organisms most likely to be affected are identified and finally specific recommendations for thermal standards consistent with long term sustainability are proposed.     

Arsenic within the secondary environment resulting from geogenic inputs,Harlech Dome,United Kingdom

There has been a growing awareness of As in the environment due to both anthropogenic and geogenic loading. This study quantifies the presence of As in river water, river sediment and groundwater within the Harlech Dome region of the UK, an area underlain by Cambro–Ordovician aged mineralization. Published data regarding As levels in UK groundwater are relatively rare compared to elsewhere. Arsenic levels in groundwater (0.1–18 µg l^?1) and river sediment (1.5–142 mg kg^?1) exceed environmental quality guidelines and indicate the release of As into the secondary environment from predominantly geogenic sources. Modelling of dissolved As speciation using ORP–pH diagrams predicts the presence of As in both arsenate (As⁵⁺) and arsenous acid (As³⁺) species, which possess differing solubilities and mobilities. Calculation of enrichment factors (EFs) for As in river sediments, using Al as a reference element, indicates highest EFs, and therefore As release, occurs in streams draining the Coed-y-Brenin region in the south-east of the Harlech Dome. This area is underlain by an as yet unexploited porphyry copper deposit. Data indicate that the presence of potentially harmful elements within the environment may occur with or without the presence of major anthropogenic activity.     

Normal fault growth influenced by basement fabrics: The importance of preferential nucleation from pre‐existing structures

Reactivation of pre‐existing intra‐basement structures can influence the evolution of rift basins, yet the detailed kinematic relationship between these structures and overlying rift‐related faults remains poorly understood. Understanding the kinematic as well as geometric relationship between intra‐basement structures and rift‐related fault networks is important, with the extension direction in many rifted provinces typically thought to lie normal to fault strike. We here investigate this problem using a borehole‐constrained, 3D seismic reflection dataset from the Taranaki Basin, offshore New Zealand. Excellent imaging of intra‐basement structures and a relatively weakly deformed, stratigraphically simple sedimentary cover allow us to: (a) identify a range of interaction styles between intra‐basement structures and overlying, Plio‐Pleistocene rift‐related normal faults; and (b) examine the cover fault kinematics associated with each interaction style. Some of the normal faults parallel and are physically connected to intra‐basement reflections, which are interpreted as mylonitic reverse faults formed during Mesozoic subduction and basement terrane accretion. These geometric relationships indicate pre‐existing intra‐basement structures locally controlled the position and attitude of Plio‐Pleistocene rift‐related normal faults. However, through detailed 3D kinematic analysis of selected normal faults, we show that: (a) normal faults only nucleated above intra‐basement structures that experienced late Miocene compressional reactivation, (b) despite playing an important role during subsequent rifting, intra‐basement structures have not been significantly extensionally reactivated, and (c) preferential nucleation and propagation of normal faults within late Miocene reverse faults and folds appears to be the key genetic relationship between contractionally reactivated intra‐basement structures and rift‐related normal faults. Our analysis shows that km‐scale, intra‐basement structures can control the nucleation and development of newly formed, rift‐related normal faults, most likely due to a local perturbation of the regional stress field. Because of this, simply inverting fault strike for causal extension direction may be incorrect, especially in provinces where pre‐existing, intra‐basement structures occur. We also show that a detailed kinematic analysis is key to deciphering the temporal as well as simply the spatial or geometric relationship between structures developed at multiple structural levels.