Particle‐size evidence of barrier estuary regime as a new proxy for ENSO climate variability

We investigate a new proxy for ENSO climate variability based on particle‐size data from long‐term, coastal sediment records preserved in a barrier estuary setting. Corresponding ~4–8 year periodicities identified from Wavelet analysis of particle‐size data from Pescadero Marsh in Central Coast California and rainfall data from San Francisco reflect established ENSO periodicity, as further evidenced in the Multivariate ENSO Index (MEI), and thus confirms an important ENSO control on both precipitation and barrier regime variability. Despite the fact that barrier estuary mean particle size is influenced by coastal erosion, precipitation and streamflow, balanced against barrier morphology and volume, it is encouraging that considerable correspondence can also be observed in the time series of MEI, regional rainfall and site‐based mean particle size over the period 1871–2008. This correspondence is, however, weakened after c.1970 by temporal variation in sedimentation rate and event‐based deposition. These confounding effects are more likely when: (i) accommodation space may be a limiting factor; and (ii) particularly strong El Niños, e.g. 1982/1983 and 1997/1998, deposit discrete >cm‐thick units during winter storms. The efficacy of the sediment record of climate variability appears not to be compromised by location within the back‐barrier setting, but it is limited to those El Niños that lead to barrier breakdown. For wider application of this particle size index of ENSO variability, it is important to establish a well‐resolved chronology and to sample the record at the appropriate interval to characterize deposition at a sub‐annual scale. Further, the sample site must be selected to limit the influence of decreasing accommodation space through time (infilling) and event‐based deposition. It is concluded that particle‐size data from back‐barrier sediment records have proven potential for preserving evidence of sub‐decadal climate variability, allowing researchers to explore temporal and spatial patterns in phenomena such as ENSO. Copyright © 2017 John Wiley & Sons, Ltd.     

Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.     

The dissolution of synthetic Na-boltwoodite in sodium carbonate solutions

Uranyl silicates such as uranophane and Na-boltwoodite appear to control the solubility of uranium in certain contaminated sediments at the US Department of Energy Hanford site [Liu, C., Zachara, J.M., Qafoku, O., McKinley, J.P., Heald, S.M., Wang, Z. 2004. Dissolution of uranyl microprecipitates in subsurface sediments at Hanford Site, USA. Geochim. Cosmochim. Acta68, 4519-4537.]. Consequently, the solubility of synthetic Na-boltwoodite, Na(UO₂)(SiO₃OH) · 1.5H₂O, was determined over a wide range of bicarbonate concentrations, from circumneutral to alkaline pH, that are representative of porewater and groundwater compositions at the Hanford site and calcareous environments generally. Experiments were open to air. Results show that Na-boltwoodite dissolution was nearly congruent and its solubility and dissolution kinetics increased with increasing bicarbonate concentration and pH. A consistent set of solubility constants were determined from circumneutral pH (0 added bicarbonate) to alkaline pH (50 mM added bicarbonate). Average or 5.85 ± 0.0.26; using the Pitzer ion-interaction model or Davies equation, respectively. These values are close to the one determined by [Nguyen, S.N., Silva, R.J., Weed, H.C., Andrews, Jr., J.E., 1992. Standard Gibbs free energies of formation at the temperature 303.15 K of four uranyl silicates: soddyite, uranophane, sodium boltwoodite, and sodium weeksite. J. Chem. Thermodynamics24, 359-376.] under very different conditions (pH 4.5, Ar atmosphere).     

Mechanical Behaviour of the Interface Between Cemented Tailings Backfill and Retaining Structures Under Shear Loads

Understanding the shear behaviour of the interface between cemented tailings backfill and retaining wall structures (barricades, bulkheads) is important for the optimal design of barricades or bulkheads, and for mine operators to balance strength and safety against cost. However, our understanding of the shear behaviour of the aforementioned interface is limited. This paper is aimed at investigating the interfacial behaviour and properties of cemented tailings backfill-retaining wall structures, including stress–strain behaviour, cohesion, friction angle and shear stiffness through direct shear tests. Two different types of barricade or bulkhead materials (brick and concrete) are used in this study. Interface shear tests are performed at various curing times of the cemented backfill. Valuable results are obtained with regards to the interface shear behaviour of backfill-retaining structures. Based on these results, interfacial properties between cemented tailings backfill and barricades or bulkheads show a significant time-dependent variation.     

MARLI: a mobile application for regional landslide inventories in Ecuador

The regions of Central and South America most susceptible to the occurrence of landslides will become even more vulnerable in the context of climate change. The Josefina disaster, in 1993, demonstrated both the vulnerability of local infrastructures and communities in the Paute River basin (Ecuador). Since this natural phenomena, several landslide inventories and susceptibility studies were developed, revealing the vulnerability of the Paute River basin to unstable terrain and the need for further studies throughout the basin. Despite this, no studies have been done since then to update the information generated. This paper describes a Mobile Application for Regional Landslide Inventories (MARLI), a simple but efficient open-access platform to report landslide events using the Open Data Kit system. Its design makes reporting fast, simple and cost-effective with an added benefit, and a specialized knowledge is not required for its use. MARLI was tested for the collection of landslides in Cuenca (Ecuador). From the data taken in the field, it was possible to analyze the performance and suitability of collected data and compare the results with regional inventories in the same area. Additionally, these results can be used for the elaboration and update of large-scale inventories or the training of automatic identification systems of landslides and later evaluation of their precision in a small-medium scale. Likewise, this product constitutes a fundamental input for the formulation of mitigation strategies, to formulate the appropriate response and in time, also the elaboration of reconstruction plans before the increase in the occurrence of such phenomena.

     

Factors influencing public beliefs regarding the cause of induced earthquakes

Natural Hazards - The central USA has experienced an increase in the frequency and magnitude of human-induced earthquakes. The earthquakes are caused by the deep-well injection of water produced...     

Mesofossil flora from the Late Cretaceous of New Zealand

This study presents the first report of mesofossils of flowers, fruits and seeds found in the Cretaceous of New Zealand. The specimens were recovered from the Late Cretaceous (Maastrichtian, ca. 70 Ma) at Kai Point Mine, South Island in a sequence of floodplain sediments sampled just below the Barclay Coal Seam. Angiosperm flowers, fruits and seeds occur in the sample. The most common form is an actinomorphic flower with two whorls of three tepals. Anther bases are preserved and the ovary develops into a drupe, all features that are consistent with placement in the Lauraceae. Reproductive structures including seeds of conifers are also described, with some allied to the Podocarpaceae. This contrasts with interpretations of the flora based on macrofossils that indicate abundant Araucariaceae and highlights the different perspectives that mesofossil floras give to any assemblage. The results of the present study support a Late Cretaceous flora at this site mainly dominated by conifers with affinities to Podocarpaceae but also including lauraceous angiosperms.     

Upstream—Downstream Shifts in Peak Recruitment of the Native Olympia Oyster in San Francisco Bay During Wet and Dry Years

Understanding the conditions that drive variation in recruitment of key estuarine species can be important for effective conservation and management of their populations. The Olympia oyster (Ostrea lurida) is native to the Pacific coast of North America and has been a target of conservation efforts, though relatively little information on larval recruitment exists across much of its range. This study examined the recruitment of Olympia oysters at biweekly to monthly intervals at four sites in northern San Francisco Bay from 2010 to 2015 (except 2013). Mean monthly temperatures warmed at all sites during the study, while winter (January–April) mean monthly salinity decreased significantly during a wet year (2011), but otherwise remained high as a result of a drought. A recurring peak in oyster recruitment was identified in mid-estuary, in conditions corresponding to a salinity range of 25–30 and >16 °C at the time of settlement (April–November). Higher average salinities and temperatures were positively correlated with greater peak recruitment. Interannual variation in the timing of favorable conditions for recruitment at each site appears to explain geographic and temporal variation in recruitment onset. Higher winter/spring salinities and warmer temperatures at the time of recruitment corresponded with earlier recruitment onset within individual sites. Across all sites, higher winter/spring salinities were also correlated with earlier onset and earlier peak recruitment. Lower winter salinities during 2011 also resulted in a downstream shift in the location of peak recruitment.