Dynamics of an outburst flood originating from a small and high-altitude glacier in the Arid Andes of Chile

The rise of total water levels at the coast is caused primarily by three factors that encompass storm surges, tides and wind waves. The accuracy of total water elevation (TWE) forecast depends not only on the cyclonic track and its intensity, but also on the spatial distribution of winds which include its speed and direction. In the present study, the cyclonic winds are validated using buoy winds for the recent cyclones formed in the Bay of Bengal since 2010 using Jelesnianski wind scheme. It is found that the cyclonic winds computed from the scheme show an underestimate in the magnitude and also a mismatch in its direction. Hence, the wind scheme is suitably modified based on the buoy observations available at different locations using a power law which reduces the exponential decay of winds by about 30%. Moreover, the cyclonic wind direction is also corrected by suitably modifying its inflow angle. The significance of modified exponential factor and inflow angle in the computation cyclonic winds is highlighted using statistical analysis. A hydrodynamic finite element-based Advanced Circulation 2D depth integrated (ADCIRC-2DDI) model is used here to compute TWE as a response to combined effect of cyclonic winds and astronomical tides. As contribution of wave setup plays an important role near the coast, a coupled ADCIRC + SWAN is used to perceive the contribution of wind waves on the TWE. The experiments are performed to validate computed surge residuals with available tide gauge data. On comparison of observed surge residuals with the simulations using modified winds from the uncoupled and coupled models, it is found that the simulated surge residuals are better compared, especially with the inclusion of wave effect through the coupled model.     

Field reconnaissance and overview of the impact of Hurricane Matthew on Haiti’s Tiburon Peninsula

The old potable water network in Byblos city is provided mainly from Ibrahim River nearby. Located in a seismic region, the aging network needs to tolerate seismic threats; thus, damage to the potable water network needs to be assessed. Therefore, first, enhancing infrastructure resilience is briefly discussed, noting briefly the need to bridge specifically between heritage risk management and engineering. Second, Byblos potable water network, seismicity, and geology are detailed. Third, the potable water network damage assessment methodology is presented. It encompasses hazard assessment, network inventory, damage functions, and model development. Data and maps are prepared using the Geographic Information System and then modeled in Ergo platform to obtain the damage to buried pipelines in the event of likely earthquake scenarios. Ergo is updated to consider recommended ground motion prediction equations (GMPEs) for the Middle East region, to consider amplification of the peak ground velocity in hazard maps due to different soil types, and to consider adequate fragility functions. Moreover, different Byblos geotechnical maps, landslide hazard, and liquefaction are investigated and embedded. Damage results to pipelines are dependent on the hazard maps obtained using different GMPEs and geotechnical maps. Asbestos cement pipelines will be most damaged, followed by polyethylene and then by ductile iron. Finally, recommendations are offered to consider an improved sustainable rehabilitation solution. The study provides a better understanding of Byblos potable water network and allows the establishment of a sustainable and resilience-to-earthquake preparedness strategy and recovery plan.     

New rurality and the experience of place: the small rural locality of La Niña,Buenos Aires,Argentina

This paper presents a cultural geographic approach for understanding local social processes of territorial re-appropriation taking place in response to non-local forces and interests. This approach is applied to the small rural locality of La Niña, in Buenos Aires Province, Argentina. The small village of La Niña is currently in a locally-led process of recovering from a recent depopulation trend caused mainly by the irruption of transnational agribusiness. As economic opportunities have dwindled in the last decades, more recently local inhabitants and new settlers have set forth diverse strategies aimed at mitigating the effects of depopulation on the social structure. We focus our attention on the way the living experience of place is involved in all these strategies. We contend that despite economic and cultural homogenization caused by globalization, the experience of place is a permanent though ever-changing aspect of social life. Our research was based on archival and hemerographic surveys and ethnographic field techniques, encompassing participatory observation, semistructured and in-depth interviews with social and government leaders and local producers as well as field landscape appraisals.     

Reduction of Manganese Oxides: Thermodynamic,Kinetic and Mechanistic Considerations for One- Versus Two-Electron Transfer Steps

Manganese oxides, typically similar to δ-MnO₂, form in the aquatic environment at near neutral pH via bacterially promoted oxidation of Mn(II) species by O₂, as the reaction of [Mn(H₂O)₆]²⁺ with O₂ alone is not thermodynamically favorable below pH of ~?9. As manganese oxide species are reduced by the triphenylmethane compound leucoberbelein blue (LBB) to form the colored oxidized form of LBB (λ_max?=?623 nm), their concentration in the aquatic environment can be determined in aqueous environmental samples (e.g., across the oxic–anoxic interface of the Chesapeake Bay, the hemipelagic St. Lawrence Estuary and the Broadkill River estuary surrounded by salt marsh wetlands), and their reaction progress can be followed in kinetic studies. The LBB reaction with oxidized Mn solids can occur via a hydrogen atom transfer (HAT) reaction, which is a one-electron transfer process, but is unfavorable with oxidized Fe solids. HAT thermodynamics are also favorable for nitrite with LBB and MnO₂ with ammonia (NH₃). Reactions are unfavorable for NH₄⁺ and sulfide with oxidized Fe and Mn solids, and NH₃ with oxidized Fe solids. In laboratory studies and aquatic environments, the reduction of manganese oxides leads to the formation of Mn(III)-ligand complexes [Mn(III)L] at significant concentrations even when two-electron reductants react with MnO₂. Key reductants are hydrogen sulfide, Fe(II) and organic ligands, including the siderophore desferioxamine-B. We present laboratory data on the reaction of colloidal MnO₂ solutions (λ_max?~?370 nm) with these reductants. In marine waters, colloidal forms of Mn oxides (<?0.2 µm) have not been detected as Mn oxides are quantitatively trapped on 0.2-µm filters. Thus, the reactivity of Mn oxides with reductants depends on surface reactions and possible surface defects. In the case of MnO₂, Mn(IV) is an inert cation in octahedral coordination; thus, an inner-sphere process is likely for electrons to go into the empty e _g ^* conduction band of its orbitals. Using frontier molecular orbital theory and band theory, we discuss aspects of these surface reactions and possible surface defects that may promote MnO₂ reduction using laboratory and field data for the reaction of MnO₂ with hydrogen sulfide and other reductants.     

Fish-Habitat Relationships Along the Estuarine Gradient of the Sacramento-San Joaquin Delta,California: Implications for Habitat Restoration

Estuaries are highly variable environments where fish are subjected to a diverse suite of habitat features (e.g., water quality gradients, physical structure) that filter local assemblages from a broader, regional species pool. Tidal, climatological, and oceanographic phenomena drive water quality gradients and, ultimately, expose individuals to other habitat features (e.g., stationary physical or biological elements, such as bathymetry or vegetation). Relationships between fish abundances, water quality gradients, and other habitat features in the Sacramento-San Joaquin Delta were examined as a case example to learn how habitat features serve as filters to structure local assemblages in large river-dominated estuaries. Fish communities were sampled in four tidal lakes along the estuarine gradient during summer-fall 2010 and 2011 and relationships with habitat features explored using ordination and generalized linear mixed models (GLMMs). Based on ordination results, landscape-level gradients in salinity, turbidity, and elevation were associated with distinct fish assemblages among tidal lakes. Native fishes were associated with increased salinity and turbidity, and decreased elevation. Within tidal lakes, GLMM results demonstrated that submersed aquatic vegetation density was the dominant driver of individual fish species densities. Both native and non-native species were associated with submersed aquatic vegetation, although native and non-native fish populations only minimally overlapped. These results help to provide a framework for predicting fish species assemblages in novel or changing habitats as they indicate that species assemblages are driven by a combination of location within the estuarine gradient and site-specific habitat features.     

Temporal Changes in Seawater Carbonate Chemistry and Carbon Export from a Southern California Estuary

Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (F_DIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?10³ to 9.5±0.7?×?10³?mol C h^?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?10⁶?mol C year^?1. Following a major rain event (36 mm rain in 3 days), F_DIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?10³?mol C h^?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?10⁶?mol C year^?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small.     

High-resolution monitoring of complex coastal morphology changes: cross-efficiency of SfM and TLS-based survey (Vaches-Noires cliffs,Normandy, France)

High-resolution digital elevation models (HRDEMs) on coastal areas, particularly cliffs, are an important asset for analyzing and quantifying the processes affecting their morphology. The Vaches-Noires coastal cliffs, located at the north-western part of the Pays-d’Auge region (Normandy, France), are an ideal site for the study of subaerial and marine erosion processes. Indeed, the coastline evolves through the accumulation of deposits resulting from rotational landslides and/or mudflows at the base of the cliff which are then undermined by the sea. The 3D modeling of a representative sector of the cliffs appears a suitable solution to monitor and quantify this evolution using HRDEMs. This paper presents the whole of a monitoring protocol, with high spatial resolution and high temporal resolution, on an original location characterized by reliefs of Badlands in coastal environments. The first results of these investigations are described with an evaluation of two methods for the creation of 3D models: a “heavy” method by Terrestrial Laser Scanning (TLS) monitoring, and a “light” method using “Structure from Motion” (SfM) terrestrial photogrammetry. The small investment of time in the field and money is an important asset of the SfM method. The textured rendering quality of the SfM model makes it a powerful tool for geomorphological analysis. According to a recurrent monitoring protocol involving both measurements, it was possible to compare the accuracy of the SfM and TLS models. The results show a high accuracy of the SfM models with an overall average error of 0.05 m. The representations of the zones of accumulation and erosion as well as their spatial succession allow to investigate the dynamics of the involved processes with both methods. Preliminary volume calculation results are conclusive for TLS models.     

GNSS receiver implementations to mitigate the effects of commensurate sampling frequencies on DLL code tracking

The sampling frequency of a digitized intermediate frequency signal has a strong effect on the measurement accuracy of Global Navigation Satellite System (GNSS) receivers. The delay-locked loop tracking error is significant when the sampling frequency is an integer multiple of the code chipping rate, the so-called commensurate sampling frequency, and the number of distinct instantaneous residual code phases is low. This results in distortions of the correlation shape and discriminator functions that lead to a significant accuracy degradation. These effects are most pronounced when the sampling frequency is low. Notwithstanding, it is generally good for receivers to keep the sampling frequency to a minimum owing to the processing load and power consumption. It creates a challenge for existing GNSS signal processing techniques. Random, sine and sawtooth jitters have been found to mitigate these distortions considerably. A software algorithm and two hardware receiver implementations of these solutions are proposed. A register-based architecture can be directly applied to the conventional receiver architecture, while the increase in resource and power consumption is insignificant. A RAM-based design cannot only considerably minimize utilized resources but also slightly reduce the power consumption compared to the conventional architecture.     

Ephemeral landform development following rapid coastal uplift in the southern orogen of Taiwan

Newly emerged landscapes above sea level are characterized by rapidly evolving geomorphic systems where the initial fluvial pattern adapts to a former submarine topography. Such an early formed fluvial system establishes drainage basins and unstable landforms that characterize high topographic asymmetry which are prone to fast removal or reorganization. Transitional landscapes might form depositional systems as lakes or ponds that subsequently are incised, captured and incorporated into drainage basins. In this study we focus on the recently emerged Hengchun Peninsula to survey its paleoenvironment evolution. Three drillings performed in the Gangkou basin with fieldwork revealed several indicators that reconstructed stages of the landscape reorganization. The major finding shows an ephemeral large lake in the central part of the Hengchun Peninsula that was drained to the Pacific c. 6000 bp . The lake belonged to an ephemeral lakeland that was created after the emergence of the peninsula. Currently, several areas as relict landforms indicate this stage of topography evolution that through high rates of incision and subsequent captures, transforms into drainage basins. Furthermore, two drillings show brackish waters at the present estuary of the Gangkou basin. These two different paleoenvironments today build one system – Gangkou catchment. Long-term uplift rates show that a hanging wall of the Hengchun Fault plays a significant role in the creation of a lakeland by tilting the peninsula's surface. The tilt impacts on asymmetrical emergence of the peninsula and catchment development. Our study shows that a new geomorphic system might create depositional ephemeral landforms (lakes) that represent phases of early topography evolution after emergence above a sea level that are subjected to instantaneous rearrangement and evolves through large-scale phases before it reaches a topographic steady-state.     

Use of point scale models to improve conceptual understanding in complex aquifers: An example from a sandstone aquifer in the Eden valley,Cumbria, UK

Understanding catchment functioning is increasingly important to enable water resources to be quantified and used sustainably, flood risk to be minimized, as well as to protect the system from degradation by pollution. Developing conceptual understanding of groundwater systems and their encapsulation in models is an important part of this understanding, but they are resource intensive to create and calibrate. The relative lack of data or the particular complexity of a groundwater system can prevent the development of a satisfactory conceptual understanding of the hydrological behaviour, which can be used to construct an adequate distributed model. A time series of daily groundwater levels from the Permo-Triassic sandstones situated in the River Eden Valley, Cumbria, UK have been analysed. These hydrographs show a range of behaviours and therefore have previously been studied using statistical and time series analysis techniques. This paper describes the application of AquiMOD, impulse response function (IRF) and combined AquiMOD-IRF methods to characterize the daily groundwater hydrographs. The best approach for each characteristic type of response has been determined and related to the geological and hydrogeological framework found at each borehole location. It is clear that AquiMOD, IRF and a combination of AquiMOD with IRF can be deployed to reproduce hydrograph responses in a range of hydrogeological settings. Importantly the choice of different techniques demonstrates the influence of differing processes and hydrogeological settings. Further they can distinguish the influences of differing hydrogeological environments and the impacts these have on the groundwater flow processes. They can be used, as shown in this paper, in a staged approach to help develop reliable and comprehensive conceptual models of groundwater flow. This can then be used as a solid basis for the development of distributed models, particularly as the latter are resource expensive to build and to calibrate effectively. This approach of using simple models and techniques first identifies specific aspects of catchment functioning, for example influence of the river, that can be later tested in a distributed model.