The solution topology of galactic winds

The system of ordinary differential equations derived from the hydrodynamical equations of a radially symmetric flow has a one dimensional manifold of critical points if there is mass loading in the flow or if the heating and cooling rates are taken to be independent of the thermodynamic variables as is usual.     

Calcite Dissolution Kinetics

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.     

Spatial response of two European atmospheric circulation classifications (data 1901–2010)

Air pressure field and circulation pattern frequencies were investigated to (1) locate and compare positions of the underlying pressure fields, (2) analyse the spatial dimension of affected areas, (3) create schematic maps of important circulation types and (4) compare the classification types in their response to the data. Two manual classifications were used, selected for the length of their time series and their applicability to a larger region: the Grosswetterlagen classification (GWLc) and the Vangengeim–Girs classification (VGc). Their time series were correlated with a global set of gridded monthly sea-level pressure data. Results show the different conceptual orientation of VGc (hemispheric) and GWLc (continental). The highest correlation values and the largest affected areas are visible in winter, where patterns frequently extended into northern Africa and western Asia. Schematic maps, illustrating the average location of main pressure centres, are provided for basic classes of both classifications. Re-arranging GWLc subtypes increases the classifications comparability with the VGc. Analysis of moving correlation coefficients reveals high fluctuations in the relation of both classifications over time.     

Modeling of changes in thermal bioclimate: examples based on urban spaces in Freiburg, Germany

The Place of the Old Synagogue is a popular place in the city center of Freiburg, a medium-sized city in southwest Germany. It is going to be redesigned soon. In this paper the impact of urban street design and surface material on human thermal comfort is analyzed using the example of the Place of the Old Synagogue. The models SkyHelios, RayMan, and ENVI-met were applied to quantify and qualify the changes. All three models are freely available. Their combination allows analysis of development in long-term conditions, as well as changes in spatial distribution of thermal comfort, as well as of heat stress in summer. Results show that the models can provide valuable information. About the Place of the Old Synagogue, quantitative results show that the period with heat stress will become longer, while the intensity of heat stress increases. The spatial results show that the most significant changes are due to changes in shading. Nevertheless, an increase in thermal stress up to 10 °C is calculated for areas, where ground coverage changes from grass to pavement.