Stress–strain behavior of cement-improved clays: testing and modeling

The results of a series of laboratory tests on unimproved and cement-improved specimens of two clays are presented, and the ability of a bounding surface elastoplastic constitutive model to predict the observed behavior is investigated. The results of the oedometer, triaxial compression, extension, and cyclic shear tests demonstrated that the unimproved soil behavior is similar to that of soft clays. Cement-improved specimens exhibited peak/residual behavior and dilation, as well as higher strength and stiffness over unimproved samples in triaxial compression. Two methods of accounting for the artificial overconsolidation effect created by cement improvement are detailed. The apparent preconsolidation pressure method is considerably easier to use, but the fitted OCR method gave better results over varied levels of confining stresses. While the bounding surface model predicted the monotonic behavior of unimproved soil very well, the predictions made for cyclic behavior and for improved soils were only of limited success.     

A Biogeochemical View of Estuarine Eutrophication: Seasonal and Spatial Trends and Correlations in the Delaware Estuary

The Delaware River and Bay Estuary is one of the major urbanized estuaries of the world. The 100-km long tidal river portion of the estuary suffered from major summer hypoxia in the past due to municipal and industrial inputs in the urban region; the estuary has seen remarkable water quality improvements from recent municipal sewage treatment upgrades. However, the estuary still has extremely high nutrient loading, which appears to not have much adverse impact. Since the biogeochemistry of the estuary has been relatively similar for the past two decades, our multiple year research database is used in this review paper to address broad spatial and seasonal patterns of conditions in the tidal river and 120 km long saline bay. Dissolved oxygen concentrations show impact from allochthonous urban inputs and meteorological forcing as well as biological influences. Nutrient concentrations, although high, do not stimulate excessive algal biomass due to light and multiple nutrient element limitations. Since the bay does not have strong persistent summer stratification, there is little potential for bottom water hypoxia. Elevated chlorophyll concentrations do not exert much influence on light attenuation since resuspended bottom inorganic sediments dominate the turbidity. Dissolved inorganic carbon and dissolved and particulate organic carbon distributions show significant variability from watershed inputs and lesser impact from urban inputs and biological processes. Ratios of dissolved and particulate carbon, nitrogen, and phosphorus help to understand watershed and urban inputs as well as autochthonous biological influences. Owing to the relatively simple geometry of the system and localized anthropogenic inputs as well as a broad spatial and seasonal database, it is possible to develop these biogeochemical trends and correlations for the Delaware Estuary. We suggest that this biogeochemical perspective allows a revised evaluation of estuarine eutrophication that should have generic value for understanding other estuarine and coastal waters.     

Notes on the origin of inertinite macerals in coals: Observations on the importance of fungi in the origin of macrinite

Macrinite is a, generally, rare inertinite maceral, often incorporating remnants and fragments of other macerals, including vitrinite, liptinite, and other inertinite. The associated inertinites include multiple forms of funginite. Funginite is also commonly found in association with vitrinite of slightly elevated reflectance and with degraded varieties of vitrinite. Together with the highly degraded macrinite, the latter two associations are here inferred to be part of a continuum of fungal and microbial degradation of peat. In any case, the origin of some macrinite is potentially distinct from that of inertinite generated by fire.     

Elevation Dependence of Winter Wheat Production in Eastern Washington State with Climate Change: A Methodological Study

Crop growth models, used in climate change impact assessments to project production on a local scale, can obtain the daily weather information to drive them from models of the Earth's climate. General Circulation Models (GCMs), often used for this purpose, provide weather information for the entire globe but often cannot depict details of regional climates especially where complex topography plays an important role in weather patterns. The U.S. Pacific Northwest is an important wheat growing region where climate patterns are difficult to resolve with a coarse scale GCM. Here, we use the PNNL Regional Climate Model (RCM) which uses a sub-grid parameterization to resolve the complex topography and simulate meteorology to drive the Erosion Productivity Impact Calculator (EPIC) crop model. The climate scenarios were extracted from the PNNL-RCM baseline and 2 × CO₂ simulationsfor each of sixteen 90 km² grid cells of the RCM, with differentiation byelevation and without correction for climate biases. The dominant agricultural soil type and farm management practices were established for each grid cell. Using these climate and management data in EPIC, we simulated winter wheat production in eastern Washington for current climate conditions (baseline) and a 2 × CO₂ `greenhouse' scenario of climate change.Dryland wheat yields for the baseline climate averaged 4.52 Mg ha^–1 across the study region. Yields were zero at high elevations where temperatures were too low to allow the crops to mature. The highest yields (7.32 Mgha^–1) occurred at intermediate elevations with sufficientprecipitation and mild temperatures. Mean yield of dryland winter wheat increased to 5.45 Mg ha^–1 for the 2 × CO₂ climate, which wasmarkedly warmer and wetter. Simulated yields of irrigated wheat were generally higher than dryland yields and followed the same pattern but were, of course, less sensitive to increases in precipitation. Increases in dryland and irrigated wheat yields were due, principally, to decreases in the frequency of temperature and water stress. This study shows that the elevation of a farm is a more important determinant of yield than farm location in eastern Washington and that climate changes would affect wheat yields at all farms in the study.     

Climate Change Impacts for the Conterminous USA: An Integrated Assessment

During this century global warming will lead to changes in global weather and climate, affecting many aspects of our environment. Agriculture is the sector of the United States economy most likely to be directly impacted by climatic changes. We have examined potential changes in dryland agriculture (Part 3) and in water resources necessary for crop production (Part 4) in response to a set of climate change scenarios. In this paper we assess to what extent, under these same scenarios, water supplies will be sufficient to meet the irrigation requirement of major grain crops in the US. In addition, we assess the overall impacts of changes in water supply on national grain production. We apply the 12 climate change scenarios described in Part 1 to the water resources and crop growth simulation models described in Part 2 for the conterminous United States. Drawing on data from Parts 3 and 4 we calculate what the aggregate national production would be in those regions in which grain crops are currently produced by applying irrigation where needed and water supplies allow. The total amount of irrigation water applied to crops declines under all climate change scenarios employed in this study. Under certain of the scenarios and in particular regions, precipitation decreases so much that water supplies are too limited; in other regions precipitation becomes so plentiful that little value is derived from irrigation. Nationwide grain crop production is greater when irrigation is applied as needed. Under irrigation, less corn and soybeans are produced under most of the climate change scenarios than is produced under baseline climate conditions. Winter wheat production under irrigation responds significantly to elevated atmospheric carbon dioxide concentrations [CO₂] and appears likely to increase under climate change.     

The representative concentration pathways: an overview

This paper summarizes the development process and main characteristics of the Representative Concentration Pathways (RCPs), a set of four new pathways developed for the climate modeling community as a basis for long-term and near-term modeling experiments. The four RCPs together span the range of year 2100 radiative forcing values found in the open literature, i.e. from 2.6 to 8.5 W/m². The RCPs are the product of an innovative collaboration between integrated assessment modelers, climate modelers, terrestrial ecosystem modelers and emission inventory experts. The resulting product forms a comprehensive data set with high spatial and sectoral resolutions for the period extending to 2100. Land use and emissions of air pollutants and greenhouse gases are reported mostly at a 0.5?×?0.5 degree spatial resolution, with air pollutants also provided per sector (for well-mixed gases, a coarser resolution is used). The underlying integrated assessment model outputs for land use, atmospheric emissions and concentration data were harmonized across models and scenarios to ensure consistency with historical observations while preserving individual scenario trends. For most variables, the RCPs cover a wide range of the existing literature. The RCPs are supplemented with extensions (Extended Concentration Pathways, ECPs), which allow climate modeling experiments through the year 2300. The RCPs are an important development in climate research and provide a potential foundation for further research and assessment, including emissions mitigation and impact analysis.     

Climate Change Impacts for the Conterminous USA: An Integrated Assessment

As carbon dioxide and other greenhouse gasses accumulate in the atmosphere and contribute to rising global temperatures, it is important to examine how a changing climate may affect natural and managed ecosystems. In this series of papers, we study the impacts of climate change on agriculture, water resources and natural ecosystems in the General Circulation Model (GCM)-derived climate change projections, described in Part 1, to drive the crop production and water resource models EPIC (Erosion Productivity Impact Calculator) and HUMUS (Hydrologic Unit Model of the United States). These models are described and validated in this paper using historical crop yields and streamflow data in the conterminous United States in order to establish their ability to accurately simulate historical crop and water conditions and their capability to simulate crop and water response to the extreme climate conditions predicted by GCMs. EPIC simulated grain and forage crop yields are compared with historical crop yields from the US Department of Agriculture (USDA) and with yields from agricultural experiments. EPIC crop yields correspond more closely with USDA historical county yields than with the higher yields from intensively managed agricultural experiments. The HUMUS model was validated by comparing the simulated water yield from each hydrologic basin with estimates of natural streamflow made by the US Geological Survey. This comparison shows that the model is able to reproduce significant observed relationships and capture major trends in water resources timing and distribution across the country.     

δB, Sr, Mg and B in a modern Porites coral: the relationship between calcification site pH and skeletal chemistry

Sr/Ca, B/Ca, Mg/Ca and δ¹¹B were determined at high spatial resolution across ∼1 year of a modern Hawaiian Porites lobata coral by secondary ion mass spectrometry (SIMS). We observe significant variations in B/Ca, Mg/Ca, Sr/Ca and δ¹¹B over short skeletal distances (nominally equivalent to periods of <20 days). This heterogeneity probably reflects variations in the composition of the extracellular calcifying fluid (ECF) from which the skeleton precipitates. Calcification site pH (total scale) was estimated from skeletal δ¹¹B and ranged from 8.3 to 8.8 (± ∼0.1) with a mean of ∼8.6. Sr/Ca and B/Ca heterogeneity is not simply correlated with calcification site pH, as might be expected if Ca-ATPase activity increases the pH and decreases the Sr/Ca and B(OH)₄⁻/CO₃²⁻ ratios of the ECF. We produced a simple model of the ECF composition and the skeleton deposited from it, over a range of calcium transport and carbonate scenarios, which can account for these observed geochemical variations. The relationship between the pH and Sr/Ca of the ECF is dependent on the concentration of DIC at the calcification site. At higher DIC concentrations the ECF has a high capacity to buffer the [H⁺] changes induced by Ca-ATPase pumping. Conversely, at low DIC concentrations, this buffering capacity is reduced and ECF pH changes more rapidly in response to Ca-ATPase pumping. The absence of a simple correlation between ECF pH and skeletal Sr/Ca implies that calcification occurred under a range of DIC concentrations, reflecting variations in the respiration and photosynthesis of the coral and symbiotic zooxanthellate in the overlying coral tissues. Our observations have important implications for the use of coral skeletons as indicators of palaeo-ocean pH.     

Seasonal variations of the near surfacelayer parameters over the Antarctic ice sheet in Princess Elizabeth Land,East Antarctica

Analysis of sensible heat flux(Qh),latent heat flux(Qe),Richardson number(Ri),bulk transport coefficient(Cd) and katabatic winds are presented by using the meteorological data in the near surface layer from an automatic weather station(AWS) in Princess Elizabeth Land,East Antarctica ice sheet and the data of corresponding period at Zhongshan station in 2002.It shows that annual mean air temperature at LGB69 is-25.6°C,which is 16.4°C lower than that at Zhongshan,where the elevation is lower and located on the coast.The temperature lapse rate is about 1.0°C/110 m for the initial from coast to inland.The turbulence heat flux at LGB69 displays obvious seasonal variations with the average sensible heat flux-17.9 W/m2 and latent heat flux-0.9 W/m2.The intensity(Qh Qe) of coolling source is-18.8 W/m2 meaning the snow surface layer obtains heat from atmosphere.The near surface atmosphere is near-neutral stratified with bulk transport coefficients(Cd) around 2.8×10-3,and it is near constant when the wind speed higher than 8 m/s.The speed and the frequency of easterly Katabatic winds at LGB69 were higher than that at Zhongshan Station.     

Climate Change Impacts for the Conterminous USA: An Integrated Assessment

Global climate change will impact the hydrologic cycle by increasing the capacity of the atmosphere to hold moisture. Anticipated impacts are generally increased evaporation at low latitudes and increased precipitation at middle and high latitudes. General Circulation Models (GCMs) used to simulate climate disagree on whether the U.S. as a whole and its constituent regions will receive more or less precipitation as global warming occurs. The impacts on specific regions will depend on changes in weather patterns and are certain to be complex. Here we apply the suite of 12 potential climate change scenarios, previously described in Part 1, to the Hydrologic Unit Model of the United States (HUMUS) to simulate water supply in the conterminous United States in reference to a baseline scenario. We examine the sufficiency of this water supply to meet changing demands of irrigated agriculture. The changes in water supply driven by changes in climate will likely be most consequential in the semi-arid western parts of the country where water yield is currently scarce and the resource is intensively managed. Changes of greater than ±50% with respect to present day water yield are projected in parts of the Midwest and Southwest U.S. Interannual variability in the water supply is likely to increase where conditions become drier and to decrease under wetter conditions.