The building blocks of continental crust: Evidence for a major change in the tectonic setting of continental growth at the end of the Archean

Oceanic arcs are commonly cited as primary building blocks of continents, yet modern oceanic arcs are mostly subducted. Also, lithosphere buoyancy considerations show that oceanic arcs (even those with a felsic component) should readily subduct. With the exception of the Arabian–Nubian orogen, terranes in post-Archean accretionary orogens comprise < 10% of accreted oceanic arcs, whereas continental arcs compose 40–80% of these orogens. Nd and Hf isotopic data suggest that accretionary orogens include 40–65% juvenile crustal components, with most of these (> 50%) produced in continental arcs.Felsic igneous rocks in oceanic arcs are depleted in incompatible elements compared to average continental crust and to felsic igneous rocks from continental arcs. They have lower Th/Yb, Nb/Yb, Sr/Y and La/Yb ratios, reflecting shallow mantle sources in which garnet did not exist in the restite during melting. The bottom line of these geochemical differences is that post-Archean continental crust does not begin life in oceanic arcs. On the other hand, the remarkable similarity of incompatible element distributions in granitoids and felsic volcanics from continental arcs is consistent with continental crust being produced in continental arcs.During the Archean, however, oceanic arcs may have been thicker due to higher degrees of melting in the mantle, and oceanic lithosphere would be more buoyant. These arcs may have accreted to each other and to oceanic plateaus, a process that eventually led to the production of Archean continental crust. After the Archean, oceanic crust was thinner due to cooling of the mantle and less melt production at ocean ridges, hence, oceanic lithosphere is more subductable. Widespread propagation of plate tectonics in the late Archean may have led not only to rapid production of continental crust, but to a change in the primary site of production of continental crust, from accreted oceanic arcs and oceanic plateaus in the Archean to primarily continental arcs thereafter.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

Three recent larger earthquakes offshore Norway

Three earthquakes of magnitude around 5 occurred offshore western Norway on 5th February, 1986, on 8th August, 1988, and on 23rd January, 1989. These earthquakes, representing the highest seismic activity level in this area for at least 30 years, were all felt by people over most of southern and central Norway. Focal-mechanism solutions for these earthquakes indicate thrust faulting along N-S to NNE-SSW striking fault planes, in response to NW-SE compressional stress, most probably of plate tectonic origin.
A number of high-quality digital recordings of the ground motions at various distances from these and other recent earthquakes in Norway have shown that source spectral as well as wave attenuation characteristics in this area are reasonably consistent with what has been derived from other intraplate areas.     

Grundzüge der Geotektonischen Entwicklung Südafrikas

Zusammenfassung Der südafrikanische Subkontinent kann genetisch in drei Einheiten verschiedenen Alters und unterschiedlicher Entwicklung gegliedert werden. Der älteste Teil wurde etwa vor 3000×10⁶ Jahren stabiler Schelf. Die folgende Geosynklinalbildung — nicht so eindeutig umrissen wie die erste — erlebte ihre Hauptdeformation etwa eine Milliarde Jahre später. Der jüngste Deformationsgürtel erstreckt sich parallel zum Atlantischen Ozean und dürfte ans Ende des Präkambriums zu stellen sein.Präkambrische Geosynklinalen scheinen ausgedehnter und langsamer in ihrer Entwicklung gewesen zu sein als jüngere analoge Einheiten. Früharchaische, kaum deformierte und nur schwachmetamorphe Einheiten werden aus dem östlichen Südafrika beschrieben.

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According to the structural evolution of South Africa the subcontinent can be divided into three major units of different age and historical development. The oldest part became a stable shelf about 3000×10⁶ years ago. The following geosyncline, not as well defined as the first unit, was subjected to its major folding about 1000×10⁶ years later. The youngest belt, parallel to the Atlantic Ocean, is of late Pre-Cambrian age.Pre-Cambrian geosynclines apparently have not only been considerably larger, but also required much longer time for the completion of one geotectonic cycle than during younger, post-Cambrian periods of the earth's history. The existence of hardly folded and very slightly metamorphosed early Archean rocks is described of the eastern part of South Africa.

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Résumé Conformément à l'évolution structurale de l'Afrique du Sud, cette partie du continent peut être divisée en trois unités principales d'âges et de développement historique différents. La partie la plus ancienne devint un massif stable il y a quelque 3.000×10⁶ années. Le géosynclinal suivant, qui n'était pas aussi bien défini que le premier, a subi son plissement principal quelque 1000×10⁶ années plus tard. Le segment le plus jeune, parallèle à l'Océan atlantique, est d'âge précambrien récent.Les géosynclinaux précambriens non seulement semblent avoir été considérablement plus vastes, mais ont pris également pour accomplir un cycle géotectonique un temps plus long que lors des périodes plus récentes de l'histoire de la terre, postérieures au Cambrien. L'existence de roches archéennes anciennes à peine plissées et très faiblement métamorphosées est décrite dans la partie orientale de l'Afrique méridionale.

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Shallow seismicity at Montagne Pelée volcano,Martinique, Lesser Antilles

Continuous seismic monitoring at Martinique since the 1902 eruption of the Montagne Pelée volcano did not detect local earthquakes for the first 70 years. For the only eruption which occurred in this time span in 1929 the seismograph was 20 km away and of a standard type, not particularly suited for the detection of small-scale local seismicity. Improvement of the monitoring array over the last 15 years with the installation of sensors on the volcano itself allowed the detection of signals of local origin which were interpreted as being due to surface sources, such as rockfalls and landslides. Since December 1985 seismic sources in the volcano itself, i.e. small earthquakes at shallow depth, were identified and located with the aid of a temporary upgrading of the array close to these weak sources. Such an onset of local seismicity could not have been detected with previous seismic equipment; such episodes of seismicity in the volcano might have occurred in the past, apparently quiescent history of the volcano as the reinterpretation of seismograms of some events in 1976 would indicate, without evolving to more important volcanic phenomena. For seismographs on volcanoes the constant upgrading of observation capabilities is certainly perferred to a strict continuity of standard observations.