Properties and depositional environment of the Neogene Elhovo Lignite, Bulgaria

Several Mio-Pliocene aged lignite seams occur as part of a non-marine transgressive sequence in the Elhovo graben in south-eastern Bulgaria. The present study is focused on 45 samples collected from three boreholes in the eastern part of the basin. Petrographic data along with ash and sulphur contents were used in order to determine the lateral and vertical variations of the coal facies and depositional environment of the Elhovo lignite.The lignite seams accumulated in a rheotrophic, low-lying mire with high pH value and are characterized by high ash yields and sulphur contents. Despite of the neutral to weakly alkaline environment the bacterial activity was limited and the tissue preservation and gelification were mainly controlled by the redox conditions.Vegetation rich in decay resistant conifers dominated in the Elhovo basin together with mesophytic angiosperm species. The absence of algal remains and sapropelic coal indicated that open water areas were not present during peat accumulation. The latter processed in an environment, characterized by low subsidence rate, in which prior to the burial the woods were subjected to severe mechanical destruction. According to our interpretation, the enhanced impregnation of the tissues bacteria and fungi played only a secondary role in the process of humification. The lignite from borehole 122 and partly from BH 145 deposited in an environment characterized by relatively low (ground)water table, whereas to the south an area dominated by a flooded forest swamp (BH 104) formed. This is suggested by the better tissue preservation and gelification of the organic matter in BH 104. The vertical variation of the maceral composition in the studied lignite is interpreted as a consequence of vegetational changes, rather than to changes in the depositional environment. The low contents of inertinite macerals indicate that despite of the low water level the environment was relatively wet and the thermal and oxidative destruction of the tissues was limited.Peat accumulation was terminated by a major flooding event and a short term establishment of a lake. In contrast to the West Maritsa basin, no seam formed in the Elhovo basin during the filling stage of the lake.     

Built environment and agricultural value at risk from Hurricane Irma flooding in Florida (USA)

Natural Hazards - Flooding is the most costly type of natural disaster, as well as the most frequent. To provide risk-based flood insurance, providers must be able to accurately determine an...     

The Ca-Eskola component in eclogitic clinopyroxene as a function of pressure, temperature and bulk composition: an experimental study to 15 GPa with possible implications for the formation of oriented SiO2-inclusions in omphacite

Experiments have been conducted in the P-T range 2.5–15 GPa and 850–1,500°C using bulk compositions in the systems SiO₂–TiO₂–Al₂O₃–Fe₂O₃–FeO–MnO–MgO–CaO–Na₂O–K₂O–P₂O₅ and SiO₂–TiO₂–Al₂O₃–MgO–CaO–Na₂O to investigate the Ca-Eskola (CaEs Ca_0.5□_0.5AlSi₂O₆) content of clinopyroxene in eclogitic assemblages containing garnet + clinopyroxene + SiO₂ ± TiO₂ ± kyanite as a function of P, T, and bulk composition. The results show that CaEs_ss in clinopyroxene increases with increasing T and is strongly bulk composition dependent whereby high CaEs-contents are favoured by bulk compositions with high normative anorthite and low diopside contents. In this study, a maximum of 18 mol% CaEs_ss was found at 6 GPa and 1,350°C in a kyanite-eclogite assemblage garnet + clinopyroxene + kyanite + rutile + coesite. By comparison, no significant increase in CaEs_ss with increasing P could be observed. If the formation of oriented SiO₂-rods frequently observed in eclogititc clinopyroxenes is due to the retrogressive breakdown of a CaEs-component then these textures are a cooling rather than a decompression phenomenon and are most likely to be found in kyanite-bearing eclogites cooled from temperatures ≥750°C. The presence of clinopyroxene with approx. 4 mol% CaEs_ss in an experiment conducted at 2.5 GPa/850°C confirms earlier suggestions based on field data that vacancy-rich clinopyroxenes are not necessarily restricted to ultrahigh pressure metamorphic conditions. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Early Cambrian Mollusc Watsonella crosbyi: A Potential GSSP Index Fossil for the Base of the Cambrian Stage 2

The mollusc Watsonella crosbyi was studied on the basis of material from the lower Cambrian Dahai Member of the Zhujiaqing Formation in eastern Yunnan, China and the Pestrotsvet Formation of the Aldan River region in the Siberian Platform. This fossil had been excessively described under different names in the literature, such as Heraultia varensalensis Cobbold, 1935, H. sibirica Missarzhevsky, 1974, Heraultipegma yunnanensis He and Yang, 1982, H. yannanese He and Yang, 1982, Watsonella yunnanensis, W. crosbyi Grabau, 1900, etc. Taxonomic revision shows that other species are junior synonyms of W. crosbyi. Analysis of functional morphology implies that W. crosbyi may be rather a helcionelloid than a rostroconch since its univalved conch is untorted endogastric and lacks a rostrum and a true internal pegma. Replicas of the original microstructures preserved on the surfaces of phosphatic internal moulds confirm that the shell consists of two layers. The inner layer is lamello-fibrillar, and the outer layer is spherulitic prismatic. The widespread geographical occurrences in both siliciclastic and carbonate rocks of the late Terreneuvian indicate that W. crosbyi is an important index fossil for global correlations and subdivision of the Cambrian Series 1 (Terreneuvian). The first appearance datum (FAD) of W. crosbyi is suggested to be a potential GSSP (Global Boundary Stratotype Section and Point) candidate marker for defining the base of the Cambrian Stage 2.     

Volatile loss from melt inclusions in pyroclasts of differing sizes

We have investigated the loss of H₂O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H₂O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H₂O contents (loss of ~1 wt% H₂O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10^?9 to 10^?10 m²/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H₂O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H₂O concentrations in olivine-hosted MIs may reflect unrecognized H₂O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent.     

Selection of Momentum Variables for a Three-Dimensional Variational Analysis

Three choices of control variables for meteorological variational analysis (3DVAR or 4DVAR) are associated with horizontal wind: (1) streamfunction and velocity potential, (2) eastward and northward velocity, and (3) vorticity and divergence. This study shows theoretical and numerical differences of these variables in practical 3DVAR data assimilation through statistical analysis and numerical experiments. This paper demonstrates that (a) streamfunction and velocity potential could potentially introduce analysis errors; (b) A 3DVAR using velocity or vorticity and divergence provides a natural scale dependent influence radius in addition to the covariance; (c) for a regional analysis, streamfunction and velocity potential are retrieved from the background velocity field with Neumann boundary condition. Improper boundary conditions could result in further analysis errors; (d) a variational data assimilation or an inverse problem using derivatives as control variables yields smoother analyses, for example, a 3DVAR using vorticity and divergence as controls yields smoother wind analyses than those analyses obtained by a 3DVAR using either velocity or streamfunction/velocity potential as control variables; and (e) statistical errors of higher order derivatives of variables are more independent, e.g., the statistical correlation between U and V is smaller than the one between streamfunction and velocity potential, and thus the variables in higher derivatives are more appropriate for a variational system when a cross-correlation between variables is neglected for efficiency or other reasons. In summary, eastward and northward velocity, or vorticity and divergence are preferable control variables for variational systems and the former is more attractive because of its numerical efficiency. Numerical experiments are presented using analytic functions and real atmospheric observations.     

Lava penetrating water: the different behaviours of pāhoehoe and ‘a‘ā at the Nesjahraun, Tingvellir, Iceland

The Nesjahraun is a basaltic lava flow erupted from a subaerial fissure, extending NE along the Tingvellir graben from the Hengill central volcano that produced pāhoehoe lava followed by ‘a‘ā. The Nesjahraun entered Iceland’s largest lake, Tingvallavatn, along its southern shore during both phases of the eruption and exemplifies lava flowing into water in a lacustrine environment in the absence of powerful wave action. This study combines airborne light detection and ranging, sidescan sonar and Chirp seismic data with field observations to investigate the behaviour of the lava as it entered the water. Pāhoehoe sheet lava was formed during the early stages of the eruption. Along the shoreline, stacks of thin (5–20 cm thick), vesicular, flows rest upon and surround low (<5 m) piles of coarse, unconsolidated, variably oxidised spatter. Clefts within the lava run inland from the lake. These are 2–5 m wide, >2 m deep, ∼50 m long, spaced ∼50 m apart and have sub-horizontal striations on the walls. They likely represent channels or collapsed tubes along which lava was delivered into the water. A circular rootless cone, Eldborg, formed when water infiltrated a lava tube. Offshore from the pāhoehoe lavas, the gradient of the flow surface steepens, suggesting a change in flow regime and the development of a talus ramp. Later, the flow was focused into a channel of ‘a‘ā lava, ∼200–350 m wide. This split into individual flow lobes 20–50 m wide along the shore. ‘A‘ā clinker is exposed on the water’s edge, as well as glassy sand and gravel, which has been locally intruded by small (<1 m), irregularly shaped, lava bodies. The cores of the flow lobes contain coherent, but hackly fractured lava. Mounds consisting predominantly of scoria lapilli and the large paired half-cone of Grámelur were formed in phreatomagmatic explosions. The ‘a‘ā flow can be identified underwater over 1 km offshore, and the sidescan data suggest that the flow lobes remained coherent flowing down a gradient of <10°. The Nesjahraun demonstrates that, even in the absence of ocean waves, phreatomagmatic explosions are ubiquitous and that pāhoehoe flows are much more likely to break up on entering the water than ‘a‘ā flows, which, with a higher flux and shallow underlying surface gradient, can penetrate water and remain coherent over distances of at least 1 km.