Basement lithostratigraphy of the Adula nappe: implications for Palaeozoic evolution and Alpine kinematics

The Adula nappe belongs to the Lower Penninic domain of the Central Swiss Alps. It consists mostly of pre-Triassic basement lithologies occurring as strongly folded and sheared gneisses of various types with mafic boudins. We propose a new lithostratigraphy for the northern Adula nappe basement that is supported by detailed field investigations, U–Pb zircon geochronology, and whole-rock geochemistry. The following units have been identified: Cambrian clastic metasediments with abundant carbonate lenses and minor bimodal magmatism (Salahorn Formation); Ordovician metapelites associated with amphibolite boudins with abundant eclogite relicts representing oceanic metabasalts (Trescolmen Formation); Ordovician peraluminous metagranites of calc-alkaline affinity ascribed to subduction-related magmatism (Garenstock Augengneiss); Ordovician metamorphic volcanic–sedimentary deposits (Heinisch Stafel Formation); Early Permian post-collisional granites recording only Alpine orogenic events (Zervreila orthogneiss). All basement lithologies except the Permian granites record a Variscan + Alpine polyorogenic metamorphic history. They document a complex Paleozoic geotectonic evolution consistent with the broader picture given by the pre-Mesozoic basement framework in the Alps. The internal consistency of the Adula basement lithologies and the stratigraphic coherence of the overlying Triassic sediments suggest that most tectonic contacts within the Adula nappe are pre-Alpine in age. Consequently, mélange models for the Tertiary emplacement of the Adula nappe are not consistent and must be rejected. The present-day structural complexity of the Adula nappe is the result of the intense Alpine ductile deformation of a pre-structured entity.     

Mercury colonial footprint in Darién Gulf sediments,Colombia

The mercury (Hg) deposition history in the Darién Gulf is reconstructed from three sediment cores spanning up to 1,000 years. Knowledge on the contribution to global Hg budget from the Caribbean is limited. Patterns of water circulation, sediment deposition rates, cataclysmic atmospheric inputs, and post-depositional migration have been considered in Hg trapping in the seabed. The sediment delivery rates to the coastal zone over the Late Holocene have increased from 0.2 to 1 cm year^?1 owing to anthropogenic influence. This alteration took the form of geological effects, like coastal morphology change, that played a major role in Hg downcore signal preservation. Natural background Hg levels in Southern Caribbean sediments (77.0 μg kg^?1) are up to three times higher than preindustrial signals at other latitudes, because of volcanic contributions from the Pacific ring of fire. Enrichment factors rose from 0.9 to 1.5 (70.1–113.5 μg kg^?1) within profiles related to Hg usage since Spanish colonial times between the calendar years 1550 and 1811.     

Influence of artificial channels on the source and extent of saline water intrusion in the wind tide dominated wetlands of the southern Albemarle estuarine system (USA)

Saline water intrusion is degrading water quality in the channelized coastal wetlands of the southern Albemarle estuarine system (AES). The source, transport and fate of the saline water in the southern AES was determined by monitoring specific conductivity and water levels in small artificial channels, the Alligator River, the Alligator–Pungo Canal and the groundwater system for ~12 months. Results indicate that water levels are affected by wind tides which trigger the movement of saline water into the interior of the wetlands via the small canals. The wind tides are mostly driven by episodic southerly winds pushing saline water into the canal network and the groundwater regime proximal to the Alligator River. The saline waters persist in the canals as long as the wind tide events last. Specific conductivities from canals and groundwater are shown to be unexpectedly higher closer to the source of the Alligator River than toward the Albemarle Sound, suggesting that the large Alligator–Pungo Canal facilitates the northward migration of saline water from the Pamlico Sound to the Alligator River. Overwash and reversals in the flow directions between groundwater and surface water bodies suggest that saline water that is present during wind tide events may migrate into the groundwater system from surface water bodies. The results of this study reveal that whereas the large Alligator–Pungo Canal channels saline water to the AES, small artificial channels may also play significant roles in degrading water quality in the interior of channelized coastal wetlands.     

Hydraulic roughness over simple subaqueous dunes

Detailed studies of flow over subaqueous dunes in laboratory flumes were used to suggest a virtual near-bed layer of twice the dune height in which the mean velocity is accelerated towards the crest by contraction. The mean flow velocity in this layer above the crest, transformed into friction velocity by means of the surface skin roughness, is shown to give values consistent with measured values. The resulting dimensionless shear stress due to skin friction is depth-independent, in contrast to that derived by means of often cited traditional methods. As a result of the relationship between dune height and the thickness of the near-bed layer, an expression for the expansion loss behind dunes was formulated and used to relate form resistance directly to dune height.     

The interpretation of observations of ice and silicate ir features and polarization across it in the spectra of protostellar objects BN and AFGL 2591

The absorption features of ice at 3µm and of silicate at 10 and 20µm as well as the linear polarization across it have been calculated. The interpretations of data for protostellar objects BN and AFGL 2591 are made.The model of partially aligned spinning spheroidal grains with the Purcell's suprathermal alignment mechanism and the power law size distribution are considered. Core-mantle, porous and composite particles are investigated in the Rayleigh approximation. In the case of composite and porous grains the effective refractive indices are computed with the approximate Bruggeman rule.The influence of grain chemical composition, elongation and structure has been investigated. The distinctions in polarization between composite and core-mantle models are found. The mixing of grain materials smooths the individual spectral features of chemical components. The adding of graphite causes the shift of the 10µm peak position to shorter wavelengths. When the fraction of graphite increases, the peak at 20µm decreases and shifts to shorter wavelengths. The increase of elongation reduces the negative polarization at the 3µm feature, shifts the 10µm and 20µm peak positions to longer wavelengths, and raises the strength of the 20µm band. The porosity leads to similar effects.It was found that the studied grain models are in good agreement with observational data for BN and AFGL 2591 objects. The absence of polarization excess near 3µm for AFGL 2591 is attributable to a decrease in elongation of large grains as a result of coagulation. The attention is attracted to the problem of real distribution of the interstellar dust grains over the elongation parameter. The determination this distribution function and the study of its evolution in the processes of accretion and coagulation are necessary.     

Why does the Antarctic Peninsula Warm in climate simulations?

The Antarctic Peninsula has warmed significantly since the 1950s. This pronounced and isolated warming trend is collectively captured by 29 twentieth-century climate hindcasts participating in the version 3 Coupled Model Intercomparison Project. To understand the factors driving warming trends in the hindcasts, we examine trends in Peninsula region’s atmospheric heat budget in every simulation. We find that atmospheric latent heat release increases in nearly all hindcasts. These increases are generally anthropogenic in origin, and account for about 60% of the ensemble-mean warming trend in the Peninsula. They are driven primarily by well-understood features of the anthropogenic intensification of global hydrological cycle. As sea surface temperature increases, moisture contained in atmospheric flows increases. When such flows are forced to ascend the Peninsula’s topography, enhanced local latent heat release results. The mechanism driving the warming of the Antarctic Peninsula is therefore clear in the models. Evidence for a similar mechanism operating in the real world is seen in the increasing snow accumulation rates inferred from ice cores drilled in the Peninsula. However, the relative importance of this mechanism and other processes previously identified as potentially causing the observed warming, such as the recent sea ice retreat in the Bellingshausen Sea, is difficult to assess. Thus the relevance of the simulated warming mechanism to the observed warming is unclear, in spite of its robustness in the models.     

Equilibrium H/H fractionations in organic molecules: I. Experimental calibration of ab initio calculations

Carbon-bound hydrogen in sedimentary organic matter can undergo exchange over geologic timescales, altering its isotopic composition. Studies investigating the natural abundance distribution of ¹H and ²H in such molecules must account for this exchange, which in turn requires quantitative knowledge regarding the endpoint of exchange, i.e., the equilibrium isotopic fractionation factor (α_eq). To date, relevant data have been lacking for molecules larger than methane. Here we describe an experimental method to measure α_eq for C-bound H positions adjacent to carbonyl group (H_α) in ketones. H at these positions equilibrates on a timescale of days as a result of keto-enol tautomerism, allowing equilibrium ²H/¹H distributions to be indirectly measured. Molecular vibrations for the same ketone molecules are then computed using Density Functional Theory at the B3LYP/6-311G** level and used to calculate α_eq values for H_α. Comparison of experimental and computational results for six different straight and branched ketones yields a temperature-dependent linear calibration curve with slope = 1.081−0.00376T and intercept = 8.404−0.387T, where T is temperature in degrees Celsius. Since the dominant systematic error in the calculation (omission of anharmonicity) is of the same size for ketones and C-bound H in most other linear compounds, we propose that this calibration can be applied to analogous calculations for a wide variety of organic molecules with linear carbon skeletons for temperatures below 100 °C. In a companion paper (Wang et al., 2009) we use this new calibration dataset to calculate the temperature-dependent equilibrium isotopic fractionation factors for a range of linear hydrocarbons, alcohols, ethers, ketones, esters and acids.     

Raman spectroscopy and biomarker analysis reveal multiple carbon inputs to a Precambrian glacial sediment

Extractable biomarkers can help elucidate the environment and biota of ancient glaciations, although the method must be applied with care, as glacial sediments have a potential for incorporation of older detrital carbon. In Phanerozoic glacial sediments, the distinct elemental, molecular and isotopic compositions of the terrestrial and marine biomass allow discrimination between primary marine and redeposited terrestrial organic matter. However, as the Proterozoic biosphere was largely microbial and marine, biomarker and isotopic analyses are insufficient for distinguishing primary organic matter from secondary reworked organic matter. Here, we report the combined application of Raman spectroscopy and biomarker analysis to Precambrian glacial sediments, which, together, allows discrimination between mixed pools of organic carbon and provides a promising new approach for rapidly screening Precambrian sediments for immature organic matter amenable to biomarker analysis.     

Constructing economic geographies from corporate interviews: insights from a cross-country comparison of retailer–supplier relationships

In the light of the significant role played by corporate interviews in the construction of contemporary economic geographies, this paper suggests that the practices of corporate interviewing in the research process demand critical reflection. These practices are reflected upon in the context of a comparative study of retailer–manufacturer power relations in the UK and USA. In particular, attention is paid to the ways in which corporate interviews actively construct knowledge of contrasting own-brand supply relationships in these national economies. To do this, the paper addresses the following issues: (i) the embeddedness of corporate interviews in a transforming economic geography; (ii) the processes of identifying, and gaining access to, own-brand supply networks in the UK and USA; (iii) the use of materials resulting from corporate interviews to produce nuanced understandings of own-brand supply relationships; (iv) the adoption of an appropriate textual strategy for writing such interview-based material into economic geography.