New kind of type 3 chondrite with a graphite-magnetite matrix

We have discovered four clasts in three ordinary-chondrite regolith breccias which are a new kind of type 3 chondrite. Like ordinary and carbonaceous type 3 chondrites, they have distinct chondrules, some of which contain glass, highly heterogeneous olivines and pyroxenes, and predominantly monoclinic low-Ca pyroxenes. But instead of the usual fine-grained, Fe-rich silicate matrix, the clasts have a matrix composed largely of aggregates of micron- and submicron-sized graphite and magnetite. The bulk compositions of the clasts as well as the types of chondrules (largely porphyritic) are typical of type 3 ordinary chondrites, although chondrules in the clasts are somewhat smaller (0.1–0.5 mm). A close relationship with ordinary chondrites is also indicated by the presence of similar graphite-magnetite aggregates in seven type 3 ordinary chondrites. This new kind of chondrite is probably the source of the abundant graphite-magnetite inclusions in ordinary-chondrite regolith breccias, and may be more common than indicated by the absence of whole meteorites made of chondrules and graphite-magnetite.     

Electron microprobe correlation of tephra layers from Eastern Mediterranean abyssal sediments and the Island of Santorini

Five widespread tephra layers are found in late Quaternary sediments (0–130,000 yr B.P.) of the Eastern Mediterranean Sea. These layers have been correlated among abyssal cores and to their respective terrestrial sources by electron-probe microanalysis of glass and pumice shards. Major element variations are sufficient to discriminate unambiguously between the five major layers. Oxygen isotope stratigraphy in one of the cores studied was used to data four of the five layers. Two of the widespread layers are derived from explosive eruptions of the Santorini volcanic complex: the Minoan Ash (3370 yr B.P.) and the Acrotiri Ignimbrite (18,000 yr B.P.). An additional layer, found in one core only, is most likely correlated to the Middle Pumice Series of Santorini (approximately 100,000 yr B.P.). Two layers are correlated to deposits on the islands of Yali and Kos and date to 31,000 and 120,000 yr B.P., respectively. One layer originated from the Neapolitan area of Italy 38,000 yr B.P.     

Geochemistry and origin of volcanic rocks of the Andes (26°–28°S)

Mesozoic to Recent volcanic rocks from a transect of the Central Andes between latitudes 26 ° and 28 ° South in northern Chile and Argentina show chemical and temporal zonation with respect to the Peru-Chile trench. Jurassic to Eocene lavas occur closer to the trench and are comparable to calc-alkaline rocks of island arcs. Eastwards they are followed by Miocene to Quaternary sequences of typical continental margin calc-alkaline rocks which have higher contents of K, Rb, Sr, Ba, Zr, and REE and also higher K/Na and La/Yb ratios. The rocks occurring farthest from the trench have shoshonitic affinities. The distribution of major and trace elements is consistent with a model in which magmas were derived by anatexis of an upper mantle source already enriched in LILE and located above the descending oceanic slab. It is suggested that the chemical variations across the volcanic belt reflect systematic changes in the composition of the magmas due to a decreasing degree of partial melting with increasing depth, and probably also due to the heterogeneity of the source materials.     

Search for purines and pyrimidines in the Murchison meteorite

A 1 g interior sample of the Murchison CII meteorite was examined for the presence of purines and pyrimidines by dual-column, ion-exclusion chromatography and ultraviolet spectroscopy. Xanthine, not previously reported in meteorites, was found to be the major purine liberated by extraction with formic acid, with a concentration corresponding to 2.3 μg/g of meteorite. Guanine (0.1 ppm) and hypoxanthine (0.04 ppm) were also tentatively identified. The presence of adenine could not be confirmed. No pyrimidines were detected at concentrations higher than the background level (0.01 ppm) in water, formic acid or strong acid extracts. Silylation of the water extract, however, resulted in the appearance of 4-hydroxypyrimidine, 4-hydroxy-2-methylpyrimidine and 4-hydroxy-6-methylpyrimidine. These compounds are-though to be formed during the silylation procedure from contaminants present in the reagent.     

Oxygen isotopic compositions of Central Andean plutonic and volcanic rocks,latitudes 26°–29° south

Oxygen isotope data are reported for 27 igneous rocks of Mesozoic to Quaternary age from the Central Andes. 26–29°S. The plutonic rocks, and most of the volcanics, have δ¹⁸O values between 6.2 and 8.3‰.The whole-rock δ¹⁸O values show a weak correlation with initial⁸⁷Sr/⁸⁶Sr data. This O-Sr array differs from documented trends for calc-alkaline plutonic suites from California, Scotland and northern Italy, but overlaps with data for volcanic and plutonic rocks from Ecuador, northern Chile and southern Perú.The oxygen isotope results indicate that the magmas evolved without significant contamination from supracrustal rocks (e.g., rocks that experienced¹⁸O enrichment during surficial weathering). The available O, Sr and Pb isotopic data for these rocks are best explained by magma generation in the upper mantle or lower crust. From the Late Mesozoic on, the⁸⁷Sr/⁸⁶Sr values were modified at depth by isotopic exchange between the magma and a continually thickening crust of plutonic rocks of Late Precambrian to early Mesozoic age.     

On the standardization of measurements of the anisotropy of magnetic susceptibility

The magnetic anisotropy of several artificially constructed samples has been measured with different types of instruments in several laboratories. Susceptibility bridge determinations have given consistent results, but the magnitude of the anisotropy determined by the Digico anisotropy delineator is incorrect. For future measurements with this instrument it is necessary to make either a simple calibration change or to make a minor change in the associated computer program. A set of equations for correcting the old published data is given.     

Numerical modelling of stratified flow: a spectral approach

A numerical formulation is developed to solve the three-dimensional hydrodynamic equations which describe flow in a stratified sea.Arbitrary continuous physically realistic variations of density and eddy viscosity can be included in the model, which is sufficiently flexible to be applicable to sea areas of any horizontal extent and depth. A continuous current profile from sea surface to sea bed, is computed with the model. A method for expanding computed current profiles in terms of vertical modes is proposed and the contribution of these modes to the current profiles is considered.The time variation of the wind-induced circulation of a stratified lake in response to a suddenly imposed and maintained wind stress is examined. Calculations show that the wind-driven surface current is modulated by the internal seiche motion of the lake.     

A postglacial coleopterous assemblage from Lockport Gulf,New York

The Lockport Gulf site near Lockport, New York, is a 1.9-m sequence of organic-rich marls having a basal date of approximately 10,920 yr B.P. Six bulk samples with a combined weight of 48 kg produced over 780 individual fossil insects representing five orders, as well as molluscs and abundant plant macrofossils. Coleoptera were represented by 24 families. Several major beetle groups (Carabidae, ground beetles; Hydrophilidae, water scavenger beetles; Elmidae, riffle beetles; Staphylinidae, rove beetles; and Scolytidae, bark beetles) indicate a riffle-and-pool stream, surrounded by marsh, with open riparian habitats and nearby trees. Two zones were recognized based on the Coleoptera assemblages. The Zone 1 fauna (ca. 10,920–9800 yr B.P.) was dominated by boreal forest taxa with abundant bark beetles indicating the presence of spruce trees. In Zone 2 (ca. 9700-9100 yr B.P.) the combination of species with a restricted modern distribution in the Great Lakes-St. Lawrence Forest region and pine and deciduous tree inhabitants suggests a change in vegetation by 9700 yr B.P. Thermal estimates from a faunal analysis indicate that the climatic conditions were stable across the spruce-pine transition, with the mean July temperature in the range of 16° to 18°C.