On the influence of stratification and tidal forcing upon mixing in sill regions

A cross-sectional non-hydrostatic model with idealized topography was used to examine the processes influencing tidal mixing in the region of sills. Initial calculations with appropriate parameters for the sill at the entrance to Loch Etive showed that the model could reproduce the main features of the observed mixing in the region. In particular, the hydraulic jump in the sill region was reproduced, as was an intense mid-water jet that was observed to separate from the lee side of the sill. Shear instabilities associated with the jet appeared to be a source of mixing within the thermocline. In addition, internal lee waves were generated on the lee side of the sill, with the observed amplification because of trapping during the flood stage. Their magnitude and hence the mixing increased with increasing Froude number (F _r). In the case of vertically varying buoyancy frequency, its value near the sill top determined the F _r number, with its value below influencing internal waves magnitude at depth. At high F _r values particularly with strong currents, short waves and overturning occurred.     

http://www.sciencedirect.com/science/article/pii/S1674987114000437

The Pranhita-Godavari Basin in central eastern India is one of the Proterozoic "Purana" basins of cratonic India.New geochronology demonstrates that it has a vast depositional history of repeated basin reactivation from the Palaeoproterozoic to the Mesozoic.U-Pb laser ablation inductively coupled plasma mass spectrometry dating of detrital zircons from two samples of the Somanpalli Group—a member of the oldest sedimentary cycle in the valley-constrains its depositional age to ~1620 Ma and demonstrates a tripartite age provenance with peaks at ~3500 Ma,~2480 Ma and ~1620 Ma,with minor age peaks in the Eoarchaean(~3.8 Ga) and at ~2750 Ma.These ages are consistent with palaeocurrent data suggesting a southerly source from the Krishna Province and Enderby Land in East Antarctica.The similarity in the maximum depositional age with previously published authigenic glauconite ages suggest that the origin of the Pranhita-Godvari Graben originated as a rift that formed at a high angle to the coeval evolving late Meosproterozoic Krishna Province as Enderby Land collided with the Dharwar craton of India.In contrast,detrital zircons from the Cycle III Sullavai Group red sandstones yielded a maximum depositional age of 970±20 Ma and had age peaks of ~2550 Ma,~1600 Ma and then a number of Mesoproterozoic detrital zircons terminating in three analyses at ~970 Ma.The provenance of these is again consistent with a southerly source from the Eastern Ghats Orogen and Antarctica.Later cycles of deposition include the overlying Albaka/Usur Formations and finally the late Palaeozoic to Mesozoic Gondwana Supergroup.     

Chromite-plagioclase assemblages as a new shock indicator; implications for the shock and thermal histories of ordinary chondrites

Chromite in ordinary chondrites (OC) can be used as a shock indicator. A survey of 76 equilibrated H, L and LL chondrites shows that unshocked chromite grains occur in equant, subhedral and rounded morphologies surrounded by silicate or intergrown with metallic Fe-Ni and/or troilite. Some unmelted chromite grains are fractured or crushed during whole-rock brecciation. Others are transected by opaque veins; the veins form when impacts cause localized heating of metal-troilite intergrowths above the Fe-FeS eutectic (988°C), mobilization of metal-troilite melts, and penetration of the melt into fractures in chromite grains. Chromite-plagioclase assemblages occur in nearly every shock-stage S3-S6 OC; the assemblages range in size from 20-300 μm and consist of 0.2-20-μm-size euhedral, subhedral, anhedral and rounded chromite grains surrounded by plagioclase or glass of plagioclase composition. Plagioclase has a low impedance to shock compression. Heat from shock-melted plagioclase caused adjacent chromite grains to melt; chromite grains crystallized from this melt. Those chromite grains in the assemblages that are completely surrounded by plagioclase are generally richer in Al₂O₃ than unmelted, matrix chromite grains in the same meteorite. Chromite veinlets (typically 0.5-2 μm thick and 10-300 μm long) occur typically in the vicinity of chromite-plagioclase assemblages. The veinlets formed from chromite-plagioclase melts that were injected into fractures in neighboring silicate grains; chromite crystallized in the fractures and the residual plagioclase-rich melt continued to flow, eventually pooling to form plagioclase-rich melt pockets. Chromite-rich “chondrules” (consisting mainly of olivine, plagioclase-normative mesostasis, and 5-15 vol.% chromite) occur in many shocked OC and OC regolith breccias but they are absent from primitive type-3 OC. They may have formed by impact melting chromite, plagioclase and adjacent mafic silicates during higher-energy shock events. The melt was jetted from the impact site and formed droplets due to surface tension. Crystallization of these droplets may have commenced in flight, prior to landing on the parent-body surface.Chromite-plagioclase assemblages and chromite veinlets occur in 25 out of 25 shock-stage S1 OC of petrologic type 5 and 6 that I examined. Although these rocks contain unstrained olivine with sharp optical extinction, most possess other shock indicators such as extensive silicate darkening, numerous occurrences of metallic Cu, polycrystalline troilite, and opaque veins. It seems likely that these rocks were shocked to levels at least as high as shock-stage S3 and then annealed by heat generated during the shock event. During annealing, the olivine crystal lattices healed but other shock indicators survived. Published Ar-Ar age data for some S1 OC indicate that many shock and annealing events occurred very early in the history of the parent asteroids. The common occurrence of shocked and annealed OC is consistent with collisions being a major mechanism responsible for metamorphosing OC.     

Direct determination of organic carbon in modern reef sediments and calcareous organisms after dissolution of carbonate

An improved method for the direct determination of organic carbon in calcareous marine sediments, organisms and particulate matter is described. Samples are dissolved in phosphoric acid to remove carbonates, purged with oxygen to remove CO₂, and the resulting acidic solution is analysed for total (dissolved and particulate) organic carbon. The method is rapid, involves minimal sample manipulation, and is both accurate (better than ± 2%) and precise (better than ± 0.2 mg organic carbon/g sediment). The method is especially suitable for modern carbonate sediments which have low levels of predominantly acid-soluble organic carbon.     

CCD-photometry and pole coordinates for eight asteroids

The long time photometric observations were carried out for eight asteroids: (122) Gerda, (153) Hilda, (190) Ismene, (221) Eos, (411) Xanthe, (679) Pax, (700) Auravictrix, (787) Moskva. New rotation periods have been determined for the asteroids (153) Hilda (5.959 h) and (411) Xanthe (11.408 h), and known rotation periods for some of the others have been confirmed. Using our data and others data we have estimated new pole coordinates for the observed asteroids.     

Paragenesis and geochemistry of ore minerals in the epizonal gold deposits of the Yangshan gold belt,West Qinling,China

Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py₀) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py₁) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py₂) commonly overgrows Py₁ and is typically associated with main ore stage arsenopyrite (Apy₂). Late ore stage pyrite (Py₃), arsenopyrite (Apy₃), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py₄) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py₀ also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py₁ has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py₂ has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py₂ occurs in solid solution. Late ore stage Py₃, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy₂, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy₃ has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py₄ has relatively low concentrations of Fe and S, whereas As remains elevated (2.05～3.20 wt%), which could be interpreted by the substitution of As^? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.     

Significance of geomorphological and subsurface drainage controls on failures of peat‐covered hillslopes triggered by extreme rainfall

On 19 September 2003, 40 landslides of 140–18 000 m³ volume occurred within 2·5 km² on the slopes of Dooncarton Mountain (Republic of Ireland) during a storm that may have exceeded 90 mm within 90 minutes. The landslides were investigated to determine the reasons for such a high density of slope failures. All of the landslides were surveyed within four months, and nine of them were investigated in detail. The six largest landslides, all peat failures, accounted for 57% of the more than 100 000 m³ of material displaced during the event. A consistent sequence of superficial materials was found on the failed hillslopes, including an extensive iron pan at the base of a buried soil horizon 0·3 m below the base of the peat. Morphologically, almost all of the landslides occurred on steep planar slopes or around sharp convexities, with the latter failures developing retrogressively upslope. The only significant relationship found from analysis of 371 subsurface pipes and 142 seepage cracks (defined here as contiguous fissures conducting concentrated subsurface flow) across all the failures was that the thinner the peat cover, the deeper the pipes and seepage cracks occurred below the base of peat. It is concluded that most of the landslides were probably caused by a combination of excess water pressures in the buried soil horizon and the thinner overburden of peat or peaty soil associated with the steeper slope segments. Pipes and seepage cracks formed on the iron pan probably existed prior to the failure event and may have contributed to the high water pressures as rainwater inputs exceeded their discharge capacities. One large peat slide was probably triggered by excess water pressures developed within and between artificial tine cuts. The properties of the blanket peat were generally of little consequence in the occurrence of the landslides, but relict desiccation cracks and other structural weaknesses through the peat mass were probably highly significant. Although several aspects of the peat failures correspond to previously published examples, the context of these failures in terms of the topography and upland catena is distinctive. Copyright © 2007 John Wiley & Sons, Ltd.     

Origin of Halogens and Nitrogen in Enstatite Chondrites

The EH and EL enstatite chondrites are the most reduced chondrite groups, having formed in nebular regions where the gas may have had high C/O and/or pH₂/pH₂O ratios. Enstatite chondrites (particularly EH) have higher CI- and Mg-normalized abundances of halogens (especially F and Cl) and nitrogen than ordinary chondrites and most groups of carbonaceous chondrites. Even relative to CI chondrites, EH and EL chondrites are enriched in F. We have found that literature values for the halogen abundance ratios in EH and EL chondrites are strongly correlated with the electronegativities of the individual halogens. We suggest that the most reactive halogens were the most efficient at forming compounds (e.g., halides) that were incorporated into EH-chondrite precursor materials. It seems plausible that, under the more-oxidizing conditions pertaining to the other chondrite groups, a larger fraction of the halogens remained in the gas. Nitrogen may have been incorporated into the enstatite chondrites as simple nitrides that did not condense under the more-oxidizing conditions in the regions where other chondrite groups formed. Literature data show that unequilibrated enstatite chondrites have light bulk N (δ ¹⁵N ≈ −20‰) compared to most ordinary (−5 to +20‰) and carbonaceous (+20 to +190‰) chondrites; this may reflect the contribution in enstatite chondrites of nitride condensates with δ¹⁵ N values close to the proposed nebular mean (~−400‰). In contrast, N in carbonaceous chondrites is mainly contained within ¹⁵N-rich organic matter. The major carrier of N in ordinary chondrites is unknown.     

A three-dimensional finite-element model of wind effects upon higher harmonics of the internal tide

A non-linear three-dimensional unstructured grid model of the M₂ tide in the shelf edge area off the west coast of Scotland is used to examine the spatial distribution of the M₂ internal tide and its higher harmonics in the region. In addition, the spatial variability of the tidally induced turbulent kinetic energy and associated mixing in the area are considered. Initial calculations involve only tidal forcing, although subsequent calculations are performed with up-welling and down-welling favourable winds to examine how these influence the tidal distribution (particularly the higher harmonics) and mixing in the region. Both short- and long-duration winds are used in these calculations. Tidal calculations show that there is significant small-scale spatial variability particularly in the higher harmonics of the internal tide in the region. In addition, turbulence energy and mixing exhibit appreciable spatial variability in regions of rapidly changing topography, with increased mixing occurring above seamounts. Wind effects significantly change the distribution of the M₂ internal tide and its higher harmonics, with appreciable differences found between up- and down-welling winds and long- and short-duration winds because of differences in mixing and the presence of wind-induced flows. The implications for model validation, particularly in terms of energy transfer to higher harmonics, and mixing are briefly discussed.