The middle Pleistocene transition: characteristics, mechanisms, and implications for long-term changes in atmospheric pCO2

The emergence of low-frequency, high-amplitude, quasi-periodic (100-kyr) glacial variability during the middle Pleistocene in the absence of any significant change in orbital forcing indicates a fundamental change internal to the climate system. This middle Pleistocene transition (MPT) began 1250 ka and was complete by 700 ka. Its onset was accompanied by decreases in sea surface temperatures (SSTs) in the North Atlantic and tropical-ocean upwelling regions and by an increase in African and Asian aridity and monsoonal intensity. During the MPT, long-term average ice volume gradually increased by 50 m sea-level equivalent, whereas low-frequency ice-volume variability experienced a 100-kyr lull centered on 1000 ka followed by its reappearance 900 ka, although as a broad band of power rather than a narrow, persistent 100-kyr cycle. Additional changes at 900 ka indicate this to be an important time during the MPT, beginning with an 80-kyr event of extreme SST cooling followed by the partial recovery and subsequent stabilization of long-term North Atlantic and tropical ocean SSTs, increasing Southern Ocean SST variability primarily associated with warmer interglacials, the loss of permanent subpolar sea-ice cover, and the emergence of low-frequency variability in Pacific SSTs and global deep-ocean circulation. Since 900 ka, ice sheets have been the only component of the climate system to exhibit consistent low-frequency variability. With the exception of a near-universal organization of low-frequency power associated with marine isotope stages 11 and 12, all other components show an inconsistent distribution of power in frequency-time space, suggesting a highly nonlinear system response to orbital and ice-sheet forcing.Most hypotheses for the origin of the MPT invoke a response to a long-term cooling, possibly induced by decreasing atmospheric pCO₂. None of these hypotheses, however, accounts for the geological constraint that the earliest Northern Hemisphere ice sheets covered a similar or larger area than those that followed the MPT. Given that the MPT was associated with an increase in ice volume, this constraint requires that post-MPT ice sheets were substantially thicker than pre-MPT ice sheets, indicating a change in subglacial conditions that influence ice dynamics. We review evidence in support of the hypothesis that such an increase in ice thickness occurred as crystalline Precambrian Shield bedrock became exposed by glacial erosion of a thick mantle of regolith. This exposure of a high-friction substrate caused thicker ice sheets, with an attendant change in their response to the orbital forcing. Marine carbon isotope data indicate a rapid transfer of organic carbon to inorganic carbon in the ocean system during the MPT. If this carbon came from terrigenous sources, an increase in atmospheric pCO₂ would be likely, which is inconsistent with evidence for widespread cooling, Apparently rapid carbon transfer from terrestrial sources is difficult to reconcile with gradual erosion of regolith. A more likely source of organic carbon and nutrients (which would mitigate pCO₂ rise) is from shelf and upper slope marine sediments, which were fully exposed for the first time in millions of years in response to thickening ice sheets and falling sealevels during the MPT. Modeling indicates that regolith erosion and resulting exposure of crystalline bedrock would cause an increase in long-term silicate weathering rates, in good agreement with marine Sr and Os isotopic records. We use a carbon cycle model to show that a post-MPT increase in silicate weathering rates would lower atmospheric pCO₂ by 7–12 ppm, suggesting that the attendant cooling may have been an important feedback in causing the MPT.     

Preparing for climate change in Washington State

Climate change is expected to bring potentially significant changes to Washington State’s natural, institutional, cultural, and economic landscape. Addressing climate change impacts will require a sustained commitment to integrating climate information into the day-to-day governance and management of infrastructure, programs, and services that may be affected by climate change. This paper discusses fundamental concepts for planning for climate change and identifies options for adapting to the climate impacts evaluated in the Washington Climate Change Impacts Assessment. Additionally, the paper highlights potential avenues for increasing flexibility in the policies and regulations used to govern human and natural systems in Washington.     

Tracer Flux Balance at an Urban Canyon Intersection

Despite their importance for pollutant dispersion in urban areas, the special features of dispersion at street intersections are rarely taken into account by operational air quality models. Several previous studies have demonstrated the complex flow patterns that occur at street intersections, even with simple geometry. This study presents results from wind-tunnel experiments on a reduced scale model of a complex but realistic urban intersection, located in central London. Tracer concentration measurements were used to derive three-dimensional maps of the concentration field within the intersection. In combination with a previous study (Carpentieri et al., Boundary-Layer Meteorol 133:277–296, 2009) where the velocity field was measured in the same model, a methodology for the calculation of the mean tracer flux balance at the intersection was developed and applied. The calculation highlighted several limitations of current state-of-the-art canyon dispersion models, arising mainly from the complex geometry of the intersection. Despite its limitations, the proposed methodology could be further developed in order to derive, assess and implement street intersection dispersion models for complex urban areas.     

Ejecta exchange and satellite color evolution in the Pluto system, with implications for KBOs and asteroids with satellites

In this Note, I present first-order scaling calculations to examine the efficacy of impacts by Kuiper Belt debris in causing regolith exchange between objects in the Pluto system. It is found that ejecta can escape Nix and Hydra with sufficient velocity to reach one another, as well as Charon, and even Pluto. The degree of ejecta exchanged between Nix and Hydra is sufficient to cover these bodies with much more material than is required for photometrically change. In specific, Nix and Hydra may have exchanged as up to 10s of meters of regolith, and may have covered Charon to depths up to 14 cm with their ejecta. Pluto is likely unaffected by most Nix and Hydra ejecta by virtue of a combination of dynamical shielding from Charon and Pluto's own annual atmospheric frost deposition cycle. As a result of ejecta exchange between Nix, Hydra, and Charon, these bodies are expected to evolve their colors, albedos, and other photometric properties to be self similar. These are testable predictions of this model, as is the prediction that Nix and Hydra will have diameters near 50 km, owing to having a Charon-like albedo induced by ejecta exchange. As I discuss, this ejecta exchange process can also be effective in many KBOs and asteroids with satellites, and may be the reason that very many KBO and asteroid satellite systems have like colors.     

A survey of Karin cluster asteroids with the Spitzer Space Telescope

The Karin cluster is one of the youngest known families of main-belt asteroids, dating back to a collisional event only 5.8±0.2 Myr ago. Using the Spitzer Space Telescope we have photometrically sampled the thermal continua (3.5-22 μm) of 17 Karin cluster asteroids of different sizes, down to the smallest members discovered so far, in order to make the first direct measurements of their sizes and albedos and study the physical properties of their surfaces. Our targets are also amongst the smallest main-belt asteroids observed to date in the mid-infrared. The derived diameters range from 17.3 km for 832 Karin to 1.5 km for 75176, with typical uncertainties of 10%. The mean albedo is pv=0.215±0.015, compared to 0.20±0.07 for 832 Karin itself (for H=11.2±0.3), consistent with the view that the Karin asteroids are closely related physically as well as dynamically. The albedo distribution (0.12?pv?0.32) is consistent with the range associated with S-type asteroids but the variation from one object to another appears to be significant. Contrary to the case for near-Earth asteroids, our data show no evidence of an albedo dependence on size. However, the mean albedo is lower than expected for young, fresh “S-type” surfaces, suggesting that space weathering can darken main-belt asteroid surfaces on very short timescales. Our data are also suggestive of a connection between surface roughness and albedo, which may reflect rejuvenation of weathered surfaces by impact gardening. While the available data allow only estimates of lower limits for thermal inertia, we find no evidence for the relatively high values of thermal inertia reported for some similarly sized near-Earth asteroids. Our results constitute the first observational confirmation of the legitimacy of assumptions made in recent modeling of the formation of the Karin cluster via a single catastrophic collision 5.8±0.2 Myr ago.     

Spectral properties and composition of potentially hazardous Asteroid (99942) Apophis

The known close approach of Asteroid (99942) Apophis in April 2029 provides the opportunity for the case study of a potentially hazardous asteroid in advance of its encounter. The visible to near-infrared (0.55 to 2.45 μm) reflectance spectrum of Apophis is compared and modeled with respect to the spectral and mineralogical characteristics of likely meteorite analogs. Apophis is found to be an Sq-class asteroid that most closely resembles LL ordinary chondrite meteorites in terms of spectral characteristics and interpreted olivine and pyroxene abundances, although we cannot rule out some degree of partial melting. A meteorite analog allows some estimates and conjectures of Apophis' possible range of physical properties such as the grain density and micro-porosity of its constituent material. Composition and size similarities of Apophis with (25143) Itokawa suggest a total porosity of 40% as a “current best guess” for Apophis. Applying these parameters to Apophis yields a mass estimate of 2×¹⁰¹⁰ kg with a corresponding energy estimate of 375 Mt for its potential hazard. Substantial unknowns, most notably the total porosity, allow uncertainties in these mass and energy estimates to be as large as factors of two or three.     

CCD-photometry and pole coordinates for eight asteroids

The long time photometric observations were carried out for eight asteroids: (122) Gerda, (153) Hilda, (190) Ismene, (221) Eos, (411) Xanthe, (679) Pax, (700) Auravictrix, (787) Moskva. New rotation periods have been determined for the asteroids (153) Hilda (5.959 h) and (411) Xanthe (11.408 h), and known rotation periods for some of the others have been confirmed. Using our data and others data we have estimated new pole coordinates for the observed asteroids.     

TNOs are Cool: A Survey of the Transneptunian Region

Over one thousand objects have so far been discovered orbiting beyond Neptune. These trans-Neptunian objects (TNOs) represent the primitive remnants of the planetesimal disk from which the planets formed and are perhaps analogous to the unseen dust parent-bodies in debris disks observed around other main-sequence stars. The dynamical and physical properties of these bodies provide unique and important constraints on formation and evolution models of the Solar System. While the dynamical architecture in this region (also known as the Kuiper Belt) is becoming relatively clear, the physical properties of the objects are still largely unexplored. In particular, fundamental parameters such as size, albedo, density and thermal properties are difficult to measure. Measurements of thermal emission, which peaks at far-IR wavelengths, offer the best means available to determine the physical properties. While Spitzer has provided some results, notably revealing a large albedo diversity in this population, the increased sensitivity of Herschel and its superior wavelength coverage should permit profound advances in the field. Within our accepted project we propose to perform radiometric measurements of 139 objects, including 25 known multiple systems. When combined with measurements of the dust population beyond Neptune (e.g. from the New Horizons mission to Pluto), our results will provide a benchmark for understanding the Solar debris disk, and extra-solar ones as well.     

Origin of Halogens and Nitrogen in Enstatite Chondrites

The EH and EL enstatite chondrites are the most reduced chondrite groups, having formed in nebular regions where the gas may have had high C/O and/or pH₂/pH₂O ratios. Enstatite chondrites (particularly EH) have higher CI- and Mg-normalized abundances of halogens (especially F and Cl) and nitrogen than ordinary chondrites and most groups of carbonaceous chondrites. Even relative to CI chondrites, EH and EL chondrites are enriched in F. We have found that literature values for the halogen abundance ratios in EH and EL chondrites are strongly correlated with the electronegativities of the individual halogens. We suggest that the most reactive halogens were the most efficient at forming compounds (e.g., halides) that were incorporated into EH-chondrite precursor materials. It seems plausible that, under the more-oxidizing conditions pertaining to the other chondrite groups, a larger fraction of the halogens remained in the gas. Nitrogen may have been incorporated into the enstatite chondrites as simple nitrides that did not condense under the more-oxidizing conditions in the regions where other chondrite groups formed. Literature data show that unequilibrated enstatite chondrites have light bulk N (δ ¹⁵N ≈ −20‰) compared to most ordinary (−5 to +20‰) and carbonaceous (+20 to +190‰) chondrites; this may reflect the contribution in enstatite chondrites of nitride condensates with δ¹⁵ N values close to the proposed nebular mean (~−400‰). In contrast, N in carbonaceous chondrites is mainly contained within ¹⁵N-rich organic matter. The major carrier of N in ordinary chondrites is unknown.     

Clastic matrix in EH3 chondrites

Abstract— Patches of clastic matrix (15 to 730 μm in size) constitute 4.9 vol% of EH3 Yamato (Y‐) 691 and 11.7 vol% of EH3 Allan Hills (ALH) 81189. Individual patches in Y‐691 consist of 1) ?25 vol% relatively coarse opaque grain fragments and polycrystalline assemblages of kamacite, schreibersite, perryite, troilite (some grains with daubréelite exsolution lamellae), niningerite, oldhamite, and caswellsilverite; 2) ?30 vol% relatively coarse silicate grains including enstatite, albitic plagioclase, silica and diopside; and 3) an inferred fine nebular component (?45 vol%) comprised of submicrometer‐size grains. Clastic matrix patches in ALH 81189 contain relatively coarse grains of opaques (?20 vol%; kamacite, schreibersite, perryite and troilite) and silicates (?30 vol%; enstatite, silica and forsterite) as well as an inferred fine nebular component (?50 vol%). The O‐isotopic composition of clastic matrix in Y‐691 is indistinguishable from that of olivine and pyroxene grains in adjacent chondrules; both sets of objects lie on the terrestrial mass‐fractionation line on the standard three‐isotope graph. Some patches of fine‐grained matrix in Y‐691 have distinguishable bulk concentrations of Na and K, inferred to be inherited from the solar nebula. Some patches in ALH 81189 differ in their bulk concentrations of Ca, Cr, Mn, and Ni. The average compositions of matrix material in Y‐691 and ALH 81189 are similar but not identical‐matrix in ALH 81189 is much richer in Mn (0.23 ± 0.05 versus 0.07 ± 0.02 wt%) and appreciably richer in Ni (0.36 ± 0.10 versus 0.18 ± 0.05 wt%) than matrix in Y‐691. Each of the two whole‐rocks exhibits a petrofabric, probably produced by shock processes on their parent asteroid.