Ambient well-bore mixing, aquifer cross-contamination, pumping stress, and water quality from long-screened wells: What is sampled and what is not?

Water quality tests were performed on two long-screened alluvial aquifer wells (15–30 m of screen) that had been completed in a heterogeneous aquifer that exhibits extreme temporal water quality variability. When stressed, the total dissolved solids (TDS) in one well decreased from 10,600 to 3,500 mg/L and in another well the TDS increased from 136 to 2,255 mg/L. Nested short-screened monitoring wells were constructed in chemically distinct horizons affecting each well. Water level measurements and solute and isotopic samples were obtained from the production wells and the monitoring wells during a water quality test. Results of a time drawdown tests demonstrate transmissivity differences between horizons. Ambient water quality in the production wells and aquifer cross-contamination are controlled by well-bore mixing due to head differences of as little as 0.01 m between chemically distinct horizons which are linked by the production well screen. During non-stress periods, the ambient well-bore chemistry is controlled by the horizon with the greatest hydraulic head, whereas during stressed conditions, horizon transmissivity controls the well-bore chemistry. In one well, aquifer cross-contamination, driven by an ambient head differential of 1.2 m, persisted until about 1,600 well-bore volumes were purged.     

Patterns and Scales of Phytoplankton Variability in Estuarine–Coastal Ecosystems

Phytoplankton variability is a primary driver of chemical and biological dynamics in the coastal zone because it directly affects water quality, biogeochemical cycling of reactive elements, and food supply to consumer organisms. Much has been learned about patterns of phytoplankton variability within individual ecosystems, but patterns have not been compared across the diversity of ecosystem types where marine waters are influenced by connectivity to land. We extracted patterns from chlorophyll-a series measured at 84 estuarine–coastal sites, using a model that decomposes time series into an annual effect, mean seasonal pattern, and residual “events.” Comparisons across sites revealed a large range of variability patterns, with some dominated by a recurrent seasonal pattern, others dominated by annual (i.e., year-to-year) variability as trends or regime shifts and others dominated by the residual component, which includes exceptional bloom events such as red tides. Why is the partitioning of phytoplankton variability at these three scales so diverse? We propose a hypothesis to guide next steps of comparative analysis: large year-to-year variability is a response to disturbance from human activities or shifts in the climate system; strong seasonal patterns develop where the governing processes are linked to the annual climate cycle; and large event-scale variability occurs at sites highly enriched with nutrients. Patterns of phytoplankton variability are therefore shaped by the site-specific relative importance of disturbance, annual climatology, and nutrient enrichment.     

A Boundary-Layer Scaling for Turbulent Katabatic Flow

Scaling relationships are proposed for the turbulent katabatic flow of a stably stratified fluid down a homogeneously cooled planar slope—the turbulent analogue of a Prandtl-type slope flow. The \(\Pi \) Theorem predicts that such flows are controlled by three non-dimensional parameters: the slope angle, the Prandtl number, and a Reynolds number defined in terms of the surface thermal forcing (surface buoyancy or surface buoyancy flux), Brunt-Väisälä frequency, slope angle, and molecular viscosity and diffusivity coefficients. However, by exploiting the structure of the governing differential equations in a boundary-layer form, scaled equations are deduced that involve only two non-dimensional parameters: the Prandtl number and a modified Reynolds number. In the proposed scaling framework, the slope angle does not appear as an independent governing parameter, but merely acts as a stretching factor in the scales for the dependent and independent variables, and appears in the Reynolds number. Based on the boundary-layer analysis, we hypothesize that the full katabatic-flow problem is largely controlled by two rather than three parameters. Preliminary tests of the scaling hypothesis using data from direct numerical simulations provide encouraging results.     

Environmental Correlates of Growth and Stable Isotopes in Intertidal Species Along an Estuarine Fjord

Production and resource use by intertidal taxa were studied in the estuarine fjord of Puget Sound, Washington, USA. Along nearly 100 km, salinity is similar, and intertidal habitat and immersion time were kept consistent, thus allowing a focus on other environmental variables such as temperature and resource availability that could influence growth. Primary producers (ulvoid and fucoid macroalgae) and suspension feeders (oysters and barnacles) were transplanted on three beaches in each of three regions and assessed for individual-level growth, carbon and nitrogen ratios, and stable isotopes. In most transplants, δ¹³C and C/N showed no regional variation but δ¹⁵N was enriched up-estuary. Among environmental variables, chlorophyll a, total suspended solids, and particulate organic matter had small and/or inconsistent regional variation, but temperature was higher up-estuary. For the most intensively studied species (Pacific oyster, Crassostrea gigas) transplanted four times over 2 years, seasonal and regional variation in growth were best predicted by temperature rather than resource availability. Growth rates continued to increase into Totten Inlet, a shallow finger inlet at the head of Puget Sound. As indicators of environmental conditions, the growth and tissue chemistry of intertidal study taxa affirm that sources and amounts of resources show no strong gradients along this estuarine fjord, and they also support temperature as a key factor for performance, with species-specific responses. Higher temperatures may also have community-level impacts, given prior evidence linking beach temperatures to reduced intertidal diversity and biomass into Puget Sound.     

Paragenesis and geochemistry of ore minerals in the epizonal gold deposits of the Yangshan gold belt,West Qinling,China

Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py₀) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py₁) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py₂) commonly overgrows Py₁ and is typically associated with main ore stage arsenopyrite (Apy₂). Late ore stage pyrite (Py₃), arsenopyrite (Apy₃), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py₄) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py₀ also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py₁ has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py₂ has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py₂ occurs in solid solution. Late ore stage Py₃, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy₂, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy₃ has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py₄ has relatively low concentrations of Fe and S, whereas As remains elevated (2.05～3.20 wt%), which could be interpreted by the substitution of As^? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.     

Coastal flooding in Scotland: towards national-level hazard assessment

This study investigated contributory factors to flood hazard around Scotland. There is a need to develop preliminary assessments of areas potentially vulnerable to flooding for compliance with the European Union Directive on the Assessment and Management of Flood Risks (2007/60/EC). Historical accounts of coastal flood events in Scotland, notably in a storm in January 2005, had shown that estimates of risk based on still water levels required further information to identify sites at which waves and surges could combine. Additionally, it was important to add the effect of future sea-level rise and other drivers from published sources. Analysis of multiple years’ tidal data at seven sites, including estuaries, compared recorded water levels at high-return periods to those derived from a spatially interpolated numerical model contained within a publicly available flood risk map. For gauges with the longest records, increases were seen over time that reflected rises in mean sea level. Exposure to wave energy was computed from prevailing wind strength and direction at 36 stations, related to wave fetch and incident wind direction. Although the highest wave exposure was at open coast locations exposed to the long Atlantic fetch, GIS analysis of coastal rasters identified other areas in or close to estuaries that also had high exposure. Projected sea-level change, when added to the surge and wave analyses, gives a spatially extensive structured variable flood risk assessment for future coastal flood hazard to complement the public flood risk map. Such tools can help fulfil the requirements of the EC Directive and may be a useful approach in other regions with high spatial variability in coastal flood risk related to exposure to waves and wind.     

The Pleistocene evolution of the East Antarctic Ice Sheet in the Prydz bay region: stable isotopic evidence from ODP Site 1167

Ocean Drilling Program Leg 188, Prydz Bay, East Antarctica is part of a larger initiative to explore the Cenozoic history of the Antarctic Ice Sheet through direct drilling and sampling of the continental margins. In this paper, we present stable isotopic results from Ocean Drilling Program (ODP) Site 1167 located on the Prydz Channel Trough Mouth Fan (TMF), the first Antarctic TMF to be drilled. The foraminifer-based δ¹⁸O record is interpreted along with sedimentary and downhole logging evidence to reconstruct the Quaternary glacial history of Prydz Bay and the adjacent Lambert Glacier Amery Ice Shelf System (LGAISS). We report an electron spin resonance age date of 36.9±3.3 ka at 0.45 m below sea floor and correlate suspected glacial–interglacial cycles with the global isotopic stratigraphy to improve the chronology for Site 1167. The δ¹⁸O record based on planktonic (Neogloboquadrina pachyderma (s.)) and limited benthic results (Globocassidulina crassa), indicates a trend of ice sheet expansion that was interrupted by a period of reduced ice volume and possibly warmer conditions during the early–mid-Pleistocene (0.9–1.38 Ma). An increase in δ¹⁸O values after 900 ka appears to coincide with the mid-Pleistocene climate transition and the expansion of the northern hemisphere ice sheet. The δ¹⁸O record in the upper 50 m of the stratigraphic section indicates as few as three glacial–interglacial cycles, tentatively assigned as marine isotopic stages (MIS) 16–21, are preserved since the Brunhes/Matuyama paleomagnetic reversal (780 ka). This suggests that there is a large unconformity near the top of the section and/or that there may have been few extreme advances of the ice sheet since the mid-Pleistocene climate transition resulting in lowered sedimentation rates on the Prydz Channel TMF. The stable isotopic record from Site 1167 is one of the few available from the area south of the Antarctic Polar Front that has been linked with the global isotopic stratigraphy. Our results suggest the potential for the recovery of useful stable isotopic records in other TMFs.     

Metallic copper in ordinary chondrites

Abstract— Metallic Cu of moderately high purity (～985 mg/g Cu, ～15 mg/g Ni) occurs in at least 66% of ordinary chondrites (OC) as heterogeneously distributed, small (typically ≤20 μm) rounded to irregular grains. The mean modal abundance of metallic Cu in H, L and LL chondrites is low: 1.0 to 1.4 × 10^?4 vol%, corresponding to only 4–5% of the total Cu in OC whole rocks. In more than 75% of the metallic-Cu-bearing OC, at least some metallic Cu occurs at metallic-Fe-Ni-troilite grain boundaries. In some cases it also occurs within troilite, within metallic Fe-Ni, or at the boundaries these phases form with silicates or chromite. Ordinary chondrites that contain a relatively large number of occurrences of metallic Cu/mm² have a tendency to have experienced moderately high degrees of shock. Shock processes can cause local melting and transportation of metallic Fe-Ni and troilite; because metallic Cu is mainly associated with these phases, it also gets redistributed during shock events. In the most common petrographic assemblage containing metallic Cu, the Cu is adjacent to small irregular troilite grains surrounded by taenite plus tetrataenite; this assemblage resembles fizzed troilite and may have formed by localized shock melting or remelting of a metal-troilite assemblage.     

Mineralogy of meteorite groups

Abstract— Approximately 275 mineral species have been identified in meteorites, reflecting diverse redox environments, and, in some cases, unusual nebular formation conditions. Anhydrous ordinary, carbonaceous and R chondrites contain major olivine, pyroxene and plagioclase; major opaque phases include metallic Fe-Ni, troilite and chromite. Primitive achondrites are mineralogically similar. The highly reduced enstatite chondrites and achondrites contain major enstatite, plagioclase, free silica and kamacite as well as nitrides, a silicide and Ca-, Mg-, Mn-, Na-, Cr-, K- and Ti-rich sulfides. Aqueously altered carbonaceous chondrites contain major amounts of hydrous phyllosilicates, complex organic compounds, magnetite, various sulfates and sulfides, and carbonates. In addition to kamacite and taenite, iron meteorites contain carbides, elemental C, nitrides, phosphates, phosphides, chromite and sulfides. Silicate inclusions in IAB/IIICD and IIE iron meteorites consist of mafic silicates, plagioclase and various sulfides, oxides and phosphates. Eucrites, howardites and diogenites have basaltic to orthopyroxenitic compositions and consist of major pyroxene and calcic plagioclase and several accessory oxides. Ureilites are made up mainly of calcic, chromian olivine and low-Ca clinopyroxene embedded in a carbonaceous matrix; accessory phases include the C polymorphs graphite, diamond, lonsdaleite and chaoite as well as metallic Fe-Ni, troilite and halides. Angrites are achondrites rich in fassaitic pyroxene (i.e., Al-Ti diopside); minor olivine with included magnesian kirschsteinite is also present. Martian meteorites comprise basalts, lherzolites, a dunite and an orthopyroxenite. Major phases include various pyroxenes and olivine; minor to accessory phases include various sulfides, magnetite, chromite and Ca-phosphates. Lunar meteorites comprise mare basalts with major augite and calcic plagioclase and anorthositic breccias with major calcic plagioclase. Several meteoritic phases were formed by shock metamorphism. Martensite (α₂-Fe,Ni) has a distorted body-centered-cubic structure and formed by a shear transformation from taenite during shock reheating and rapid cooling. The C polymorphs diamond, lonsdaleite and chaoite formed by shock from graphite. Suessite formed in the North Haig ureilite by reduction of Fe and Si (possibly from olivine) via reaction with carbonaceous matrix material. Ringwoodite, the spinel form of (Mg,Fe)₂SiO₄, and majorite, a polymorph of (Mg,Fe)SiO₃ with the garnet structure, formed inside shock veins in highly shocked ordinary chondrites. Secondary minerals in meteorite finds that formed during terrestrial weathering include oxides and hydroxides formed directly from metallic Fe-Ni by oxidation, phosphates formed by the alteration of schreibersite, and sulfates formed by alteration of troilite.