Multi-method radiometric dating of volcano-sedimentary layers from northern Italy: Age and duration of the Priabonian stage

A comparison between conventional KAr (biotite) ages and fission track (zircon and apatite) and UPb (zircon) ages obtained from stratigraphically well-constrained Priabonian (Late Eocene) volcano-sedimentary deposits of northern Italy is presented. Two sections at Priabona (one level) and Possagno (two levels) were dated. The application of fission track dating appears fruitful for obtaining reasonably precise (±4 to 5% 2σ errors) ages useful for time-scale calibration. The concordancy of apatite and zircon fission track ages, and the reproducibility of results provide the time of volcanic eruption and deposition. The UPb analysis of the zircons has not been unsuccessful, but discordancy does not permit accurate dating. Significant dates obtained from Possagno are: KAr method, 35.0 ± 0.5 Ma (duplicate analysis on K-rich biotite from the same level); fission track dating method, 35.8 ± 1.4 Ma (weighted mean age on 2 apatite and 3 zircon separates from the same level); UPb method, 36.7 ± 1.0 Ma (maximum age of discordant zircons from the same level). The comparison between the present results and recent multi-method and multi-laboratory results obtained from time equivalent Priabonian (Late Eocene) biotite-rich layers from the Apennines shows perfect agreement and supports the location of a Priabonian stage between about 37.5 Ma and about 33.7 (±0.5) Ma; the alternative ages preferred by the Decade of North American Geology convention should be abandoned and a large portion of this scale revised accordingly.     

Impact of suboxia on sinking particulate organic carbon: Enhanced carbon flux and preferential degradation of amino acids via denitrification

Fluxes of particulate organic carbon (POC) through the oxygen deficient waters in the eastern tropical North Pacific were found to be relatively less attenuated with depth than elsewhere in the eastern North Pacific. The attenuation coefficient (b) for the flux was found to be 0.40 versus the composite value of 0.86 determined by Martin et al. (1987). To examine this further, sinking POC was collected using sediment traps and allowed to degrade in oxic and suboxic experiments. Using a kinetic model, it was found that degradation proceeded at similar rates (roughly 0.8 day⁻¹) under oxic and suboxic conditions, but a greater fraction of bulk POC was resistant to degradation in the suboxic experiments (61% vs. 23%). Amino acids accounted for 37% of POC collected at 75m, but following degradation the value dropped to 17% and 16% in the oxic and suboxic experiments respectively. POC collected from 500m was 10% amino acids. The non-AA component of POC collected at 75m was not degraded under suboxic conditions, while under oxic conditions it was. These results suggest that microbes degrading OC under suboxic conditions via denitrification preferentially utilize nitrogen-rich amino acids. This preferential degradation of amino acids suggests that 9% more nitrogen may be lost via water column denitrification than is accounted for when a more “Redfieldian” stoichiometry for POC is assumed.     

Numerical Solution of Lock-Release Gravity Current with Viscous Self-Similar Regime

Lock-release gravity currents with a viscous self-similar regime are simulated by use of the renormalization group(RNG) k - ε model for Reynolds-stress closure. Besides the turbulent regime with initially a slumping phase of a conslant current front speed and later an inviseid self-similar phase of front speed decreasing as t^-1/3(where t is the time measured from release), the viseous self-similar regime is satisfactorily reproduced with front speed decreasing as t^-4/5,consistent with well known experimental observations.     

When hazard avoidance is not an option: lessons learned from monitoring the postdisaster Oso landslide,USA

On 22 March 2014, a massive, catastrophic landslide occurred near Oso, Washington, USA, sweeping more than 1 km across the adjacent valley flats and killing 43 people. For the following 5 weeks, hundreds of workers engaged in an exhaustive search, rescue, and recovery effort directly in the landslide runout path. These workers could not avoid the risks posed by additional large-scale slope collapses. In an effort to ensure worker safety, multiple agencies cooperated to swiftly deploy a monitoring and alerting system consisting of sensors, automated data processing and web-based display, along with defined communication protocols and clear calls to action for emergency management and search personnel. Guided by the principle that an accelerating landslide poses a greater threat than a steadily moving or stationary mass, the system was designed to detect ground motion and vibration using complementary monitoring techniques. Near real-time information was provided by continuous GPS, seismometers/geophones, and extensometers. This information was augmented by repeat-assessment techniques such as terrestrial and aerial laser scanning and time-lapse photography. Fortunately, no major additional landsliding occurred. However, we did detect small headscarp failures as well as slow movement of the remaining landslide mass with the monitoring system. This was an exceptional response situation and the lessons learned are applicable to other landslide disaster crises. They underscore the need for cogent landslide expertise and ready-to-deploy monitoring equipment, the value of using redundant monitoring techniques with distinct goals, the benefit of clearly defined communication protocols, and the importance of continued research into forecasting landslide behavior to allow timely warning.

     

A subsidiary fast-diffusing substitution mechanism of Al in forsterite investigated using diffusion experiments under controlled thermodynamic conditions

Diffusion of Al in synthetic forsterite was studied at atmospheric pressure from 1100 to 1500 °C in air along [100] with activities of SiO₂, MgO and Al₂O₃ (a_SiO2, a_MgO and a_Al2O3) buffered. At low a_SiO2, the buffer was forsterite + spinel + periclase (fo + sp + per) at all temperatures, while at high a_SiO2 and subsolidus conditions a variety of three-phase assemblages containing forsterite and two other phases from spinel, cordierite, protoenstatite or sapphirine were used at 1100–1350 °C. Experiments at high a_SiO2 and 1400 °C used forsterite + protoenstatite + melt (fo + en + melt), and at 1500 °C, fo + melt. The resulting diffusion profiles were analysed by LA–ICP–MS in scanning mode. Diffusion profiles in the high a_SiO2 experiments were generally several hundred microns in length, but diffusion at low a_SiO2 was three orders of magnitude slower than in high a_SiO2 experiments carried out at the same temperature, producing short profiles only a few microns in length and close to the spatial resolution of the analytical method. Interface concentrations of Al in the forsterite, obtained by extrapolating the diffusion profiles to the crystal/buffer interface, were only a fraction of those expected at equilibrium, and varied among the differing buffer assemblages according to (a_Al2O3)^1/2 and (a_SiO2)^3/4, pointing to the substitution of Al in forsterite by an octahedral-site, vacancy-coupled (OSVC) component with the stoichiometry Al _4/3 ³⁺ vac_2/3SiO₄, whereas the main substitution expected from previous equilibrium studies would be the coupled substitution of 2 Al for Mg + Si, giving the stoichiometry MgAl₂O₄. It is proposed that this latter substitution is not seen on the length scales of the present experiments because it requires replacement of Si by Al on tetrahedral sites, and is accordingly rate-limited by the slow diffusivity of Si. Instead, diffusion of Al by the OSVC mechanism is relatively fast, and at high a_SiO2, even faster than Fe–Mg interdiffusion.     

Palaeomagnetism and magnetostratigraphy of the Permian–Triassic northwest central Siberian Trap Basalts

A detailed palaeomagnetic and magnetostratigraphic study of the Permian–Triassic Siberian Trap Basalts (STB) in the Noril'sk and Abagalakh regions in northwest Central Siberia is presented. Thermal (TH) and alternating field (AF) demagnetisation techniques have been used and yielded characteristic magnetisation directions. The natural remanent magnetisation of both surface and subsurface samples is characterised by a single component in most cases. Occasionally, a viscous overprint can be identified which is easily removed by TH or AF demagnetisation.The resulting average mean direction after tectonic correction for the 95 flows sampled in outcrops is D=93.7°, I=74.7° with k=19 and α₉₅=3.3°. The corresponding pole position is 56.2°N, 146.0°E.Unoriented samples from four boreholes cores in the same regions have also been studied. They confirm the reversed–normal succession found in outcrops. The fact that only one reversal of the Earth's magnetic field has been recorded in the traps can be taken as evidence for a rather short time span for the major eruptive episode in this region. However, there is evidence elsewhere that the whole volcanic activity associated with the emplacement of the STB was much longer and lasted several million years.