Benthic-pelagic coupling and export of organic carbon from a tropical Atlantic continental shelf—Sierra Leone

An approximate carbon budget for the Sierra Leone River Estuary and adjacent inner continental shelf indicates that phytoplankton production is balanced by grazers only in the wet season estuary; on the continental shelf, and in the dry season estuary, phytoplankton production exceeds demand of consumer populations by 70–90%. Regional production is dominated by the dry season estuary where diatom blooms support large population of the phytophagous clupeid fish Ethmalosa fimbriata. It is suggested that as well as what is used in bacterial respiration, not quantified in the study, important amounts of inshore organic carbon production are available for export, or burial, or both, either in inshore mudbanks or at the shelf edge by slumping. This carbon budget for a tropical continental shelf having neither coral-reefs nor coastal upwelling appears to correspond with what is emerging as a generic distinction between shelves and open ocean ecosystems: surplus production on shelves, balance between producers and consumers in the open ocean.     

The 1.7- to 4.2-μm spectrum of asteroid 1 Ceres: Evidence for structural water in clay minerals

A high-resolution Fourier spectrum (1.7–3.5 μm) and medium-resolution spectrophotometry (2.7–4.2 μm) were obtained for Asteroid 1 Ceres. The presence of the 3-μm absorption feature due to water of hydration was confirmed. The 3-μm feature is compared with the 3-μm bands due to water of hydration in clays and salts. It is concluded that the spectrum of Ceres shows a strong absorption at 2.7–2.8 μm due to structural OH groups in clay minerals. The dominant minerals on the surface of Ceres are therefore hydrated clay minerals structurally similar to terrestrial montmorillonites. There is also a narrow absorption feature at 3.1 μm which is attributable to a very small amount of water ice on Ceres. This is the first evidence for ice on the surface of an asteroid.     

The initiation of Waulsortian buildups in Western Ireland

The contact zone at the base of the Waulsortian (Upper Tournaisian) carbonate mud‐bank complex in western Ireland has been investigated at four localities spaced over a distance of 120 km. At all localities, a transition facies up to 3 m thick, characterized by several types of grumous (clotted and/or peloidal) carbonate muds, immediately underlies the Waulsortian facies. These muds show a developmental sequence provisionally interpreted as a necessary precursor to the formation of Waulsortian polymuds. Such pre‐bank precursors produced thin (a few decimetres) units of transition facies. The same mud types also persisted as an aureole around growing banks (mud‐mounds). Migration of the aureole during bank progradation produced thicker units of transition facies. The distribution of skeletal grain types in the Waulsortian banks, the transition facies and the ‘background’ argillaceous bioclastic limestones show two trends: one regional and one local. The regional trend is expressed by progressive north–south attenuation and, in some cases (for example, plurilocular foraminifera), the disappearance of organism groups. It parallels changes in Waulsortian Phases (defined by skeletal grain‐type assemblages) and is thought to indicate a southerly increase in water depth. The local trend, which occurs only in the two southern localities (deeper water), expresses differences between the skeletal grain content of the various lithofacies. These differences result partly from increased sensitivity to substrate texture by organism groups suffering southward attenuation (notably gastropods, hyalosteliid sponges, aoujgaliids, Earlandia and kirkbyacean ostracods) and partly from selective colonization, particularly of the transition facies, by tabulate corals and stick/ramose bryozoans. However, the developmental sequence of precursor carbonate muds is the same at all localities, indicating that the mud‐making process (probably microbial) was independent of water depth.     

Petrology and sulfur and chlorine emissions of the 1963 eruption of Gunung Agung,Bali, Indonesia

 The 1963 eruption of Gunung Agung produced 0.95 km³ dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield basaltic andesite with a temperature of 1040–1100  °C at an assumed pressure of 2 kb, f O₂>NNO, and an average melt volatile content (H₂O±CO₂) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic method to products of the 1963 eruption for estimating volatile release yields of 2.5×10¹²g (Mt) of SO₂ and 3.4 Mt of Cl released from the 0.65 km³ of juvenile tephra which contributed to stratospheric injection of H₂SO₄ aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of SO₂ release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO₂ was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent high-S-release eruptions of more evolved and oxidized magmas (El Chichón, Pinatubo), the petrologic method gives values two orders of magnitude less than independent estimates of SO₂ emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions of more mafic magmas, suggest that SO₂ emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those from more-evolved magma eruptions. Received: 29 June 1994 / Accepted: 25 April 1996     

Very high strains recorded in mylonites along the Alpine Fault, New Zealand: implications for the deep structure of plate boundary faults

Oblique displacement on the Alpine Fault, which forms the principal structure along the Australian–Pacific plate boundary in South Island, New Zealand, has resulted in exhumation of a kilometre-wide mylonite zone in the hanging wall adjacent to the current brittle fault trace. The mylonites formed under amphibolite facies conditions at depths of ca. 25 km and have been uplifted during the past 5 Ma. A suite of 65–70 Ma pegmatite veins in the hanging wall Alpine schists has been progressively deformed within the mylonite zone and sheared out over a strike length of ca. 100 km. Measurements of the thickness distribution of the pegmatite veins within the non-mylonitised schists and at three localities within the progressively strained mylonites have been used to estimate strain values within the mylonites. The thicknesses approximate a log-normal distribution, with a mean value that is progressively reduced through the protomylonites, mylonites and ultramylonites. By assuming that the thickness distribution currently observed in the schists was the same for the pegmatites within the mylonites before strain, a model of deformation incorporating simple shear and simultaneous pure shear is used to strain the undeformed veins until a fit is obtained with the strained distributions. Shear strains calculated range from 12 to 22 for the protomylonites, 120 to 200 for the mylonites and 180 to 300 for the ultramylonites, corresponding to pure shear values of 1–3 in each case. These values are compatible with the strains predicted if most of the surface displacement on the fault over the past 5 Ma were accommodated within a 1–2-km-wide mylonite zone through the middle and lower crusts. The results suggest that processes such as erosional focussing of deformation and thermal weakening may cause intense strain localisation within the lower crust, with plate boundary deformation restricted to narrow zones rather than becoming increasingly distributed over a widening shear zone with depth.     

Formation of metal and silicate globules in Gujba: a new Bencubbin-like meteorite fall

Gujba is a coarse-grained meteorite fall composed of 41 vol% large kamacite globules, 20 vol% large light-colored silicate globules with cryptocrystalline, barred pyroxene and barred olivine textures, 39 vol% dark-colored, silicate-rich matrix, and rare refractory inclusions. Gujba resembles Bencubbin and Weatherford in texture, oxygen-isotopic composition and in having high bulk δ¹⁵N values (∼+685‰). The ³He cosmic-ray exposure age of Gujba (26 ± 7 Ma) is essentially identical to that of Bencubbin, suggesting that they were both reduced to meter-size fragments in the same parent-body collision. The Gujba metal globules exhibit metal-troilite quench textures and vary in their abundances of troilite and volatile siderophile elements. We suggest that the metal globules formed as liquid droplets either via condensation in an impact-generated vapor plume or by evaporation of preexisting metal particles in a plume. The lower the abundance of volatile elements in the metal globules, the higher the globule quench temperature. We infer that the large silicate globules also formed from completely molten droplets; their low volatile-element abundances indicate that they also formed at high temperatures, probably by processes analogous to those that formed the metal globules. The coarse-grained Bencubbin-Weatherford-Gujba meteorites may represent a depositional component from the vapor cloud enriched in coarse and dense particles. A second class of Bencubbin-like meteorites (represented by Hammadah al Hamra 237 and QUE 94411) may be a finer fraction derived from the same vapor cloud.     

U.S. Foreign Direct Investment in the London Legal Market: An Empirical Analysis

This article examines the nature and timing of U.S. foreign direct investment (FDI) in the London legal market. Evidence from a survey of thirty–eight U.S. subsidiaries suggests that FDI has taken place primarily to serve U.S. clients located within the United Kingdom. The evidence also suggests that early investors (pre–1990) belong to a core group of multinational companies with headquarters located in first–tier U.S. cities (New York, Chicago, Los Angeles). Later investors more typically hail from smaller cities. The evidence reveals a number of important differences between early versus late investors. Specifically, subsidiaries that were established prior to 1990 are more likely to enjoy local decision–making autonomy than are their counterparts that entered the London market more recently. The article concludes with a brief discussion of the implications of the survey findings for future research on FDI in professional services.     

Prediction of future short-term stream chemistry — a modelling approach

The problem of predicting future short-term chemical behaviour in acidic and acid-sensitive streams is addressed. A relatively simple method is presented which combines a chemical technique for splitting the hydrograph into ground water and soil water components, based on the conservative component acid neutralization capacity, with the long-term hydrochemical model (MAGIC) in a ‘two-box’ mode. This method, coupled with a chemical speciation program (ALCHEMI), is used to assess short-term variations in stream chemistry with change in atmospheric deposition chemistry. The method is applied for a semi-natural moorland catchment in mid-Wales (Afon Gwy). For both hydrogen ion and inorganic aluminium, the modelled stream mixing relationships are non-linear, particularly at low hydrogen ion concentrations. The results also show that the relationship between hydrogen ion and inorganic aluminium concentrations varies with time in the stream. This result has important implications as it implies that aluminium concentrations will not recover, with reduced anthropogenic sulphur deposition, as rapidly as has previously been thought. Two methods, for use with critical load evaluation of ecological stress, are presented for describing the changes occurring: the hydrogen ion and inorganic aluminium concentration duration curve; the hydrogen ion and inorganic aluminium incident frequenty diagram.     

Oxygen isotope fractionation in decarbonation metamorphism: the Mottled Zone event

Calculated univariant equilibria and oxygen isotope compositions of silicates and carbonates support the proposal that the “Mottled Zone Event” is a low-pressure (1–25 atm), high-temperature (200° < T < 1300°C) metamorphism of calcareous siliceous sediments in which the thermal energy is provided by combustion of organic matter. δ¹⁸O of silicates decreases systematically with increasing metamorphic grade from averages of 18.1‰ in protolith shales, to 16.6‰ in grossular-diopside-zeolite rocks, 15.6‰ in wollastonite and anorthite-diopside-gehlenite-grossular fels, 14.1‰ in spurrite-brownmillerite marbles and 11.7‰ in the highest-grade larnite-gehlenite-brownmillerite assemblages. Decarbonation is the principal mechanism influencing the oxygen isotope compositions. The progressive decrease of δ¹⁸O in silicates can be modelled as a Rayleigh distillation of CO₂ approximately 16‰ enriched in ¹⁸O relative to whole rock assemblages i.e., of initial isotopic composition 8.5‰ heavier than the parent carbonates. The mineral assemblage of one sample with an unusual granoblastic texture is in apparent isotopic equilibrium at a temperature of 540°C.