Provincialism and correlations between some properties of vitrinites

Optical and chemical properties for hand-picked samples of vitrinite from a number of British coalfields are correlated and the correlations compared with previously published data. The form of the relationship found for the properties of British vitrinites is generally similar to that exhibited by a number of other sets of analyses, but some significant differences also exist in several of the correlations. For maximum reflectance as a function of carbon content, the present data indicate that at medium and low ranks, maximum reflectance is lower than the level suggested by most previous studies. The relationships of volatile-matter yield to reflectance and carbon content suggest that at low ranks, volatile-matter yield is strongly dependent upon the nature of the coalification history of the vitrinite. Furthermore, these correlations are likely to show provincialism, in that correlations which hold for one coalfield may not be representative of the relationship in other coalfields. Similarly, major differences in relationships involving bireflectance are associated with the tectonic setting at the time of effective coalification. The data presented here indicate that for low-rank coals at least, correlations between properties of vitrinites must take account of provincialism if they are to be sufficiently reliable to be useful. The measurement of a number of rank-sensitive variables can yield additional information about rank, as compared with the use of a single rank-sensitive variable.     

Genetic significance of fluid inclusions in the CSA Cu–Pb–Zn deposit, Cobar, Australia

CSA mine exploits a ‘Cobar-type’ Cu–Pb–Zn±Au±Ag deposit within a cleaved and metamorphosed portion of the Cobar Supergroup, central New South Wales. The deposit comprises systems of ‘lenses’ that encompass veins, disseminations and semi-massive to massive Cu–Pb–Zn ores. The systems and contained lenses truncate bedding, are approximately coplanar with regional cleavage and similarly oriented shear zones and plunge parallel to the elongation lineation. Systems have extreme vertical continuity (>1000 m), short strike length (400 m) and narrow width (100 m), exhibit vertical and lateral ore-type variation and have alteration haloes. Models of ore formation include classical hydrothermalism, structurally controlled remobilisation and polymodal concepts; syntectonic emplacement now holds sway.Fluid inclusions were examined from quartz±sulphide veins adjacent to now-extracted ore, from coexisting quartz–sulphide within ore, and from vughs in barren quartz veins. Lack of early primary inclusions precluded direct determination of fluids associated with D₂–D₃ ore and vein emplacement. Similarly, decrepitation (by near-isobaric heating) of the two oldest secondary populations precluded direct determination of fluid phases immediately following D₂–D₃ ore and vein emplacement. Post-decrepitation outflow (late D₃ to early post-D₃) is recorded by monophase CH₄ inclusions. Entrained outflow of deeply circulated meteoric fluid modified the CH₄ system; modification is recorded by H₂O+CH₄ and H₂O+(trace CH₄) secondary populations and by an H₂O+(trace CH₄) primary population. The contractional tectonics (D₂–D₃) of ore emplacement was superseded by relaxational tectonics (D_4P) that facilitated meteoric water penetration and return flow.Under D₂ prograde metamorphism, entrapment temperatures (Tt) and pressures (Pt) for pre-decrepitation secondary inclusions are estimated as Tt300–330 °C and Pt1.5–2 kbar≈Plith (the lithostatic pressure). Decrepitation accompanied peak metamorphism (T350–380 °C) in mid- to late-D₃, while in late-D₃ to early post-D₃, essentially monophase CH₄ secondary inclusions were entrapped at Tt350 °C and Pt=1.5–2 kbar≈Plith. Subsequently, abundant CH₄ and entrained meteoric water were entrapped as H₂O+CH₄ secondaries under slowly decreasing temperature (Tt330–350 °C) and constant pressure (Pt1.5–2 kbar). Finally, with increasingly dominant meteoric outflow, H₂O+(trace CH₄) populations record decreasing temperatures (Tt>300 to <350 down to 275–300 °C) at pressures of Phydrostatic<Pt (1 kbar) <Plith (1.5 kbar).The populations of inclusions provide insight into fluid types, flow regimes and P–T conditions during parts of the deposit's evolution. They indirectly support the role of basin-derived CH₄ fluids in ore formation, but provide no insight into a basement-sourced ore-forming fluid. They fully support post-ore involvement of meteoric water. The poorly constrained entrapment history is believed to span 10 Ma from 395 to 385 Ma.     

Nd isotopic evidence for the position of southernmost Indian terranes within East Gondwana

Sm-Nd model ages of orthopyroxene-bearing massif charnockites from the Cardamom Hills Massif and adjoining supracrustal rocks from the Kerala Khondalite Belt in southernmost India are used to infer some of the relationships within these rocks and between them and neighboring areas. Most of these rocks have model ages of 2.1–2.8 Ga with most charnockites in the range 2.2–2.6 Ga. Thus, 3.0–3.4 Ga Archean rocks to their north did not contribute material to either suite and the two suites may have been juxtaposed after formation of the supracrustal rocks. The similarity of Sm-Nd isotope systems in the two units studied here supports an argument that the massif charnockites were the primary sole source of the detritus incorporated into the supracrustal rocks. A cordierite gneiss, representative of a relatively minor lithology in the supracrustal belt, has a model age of 1.3 Ga. The protolith of this gneiss not only formed from much younger material than the rest of the belt but also formed significantly after the other metasedimentary rocks. The source material of the gneiss protolith may have been located in the Wanni and Vijayan Complexes of Sri Lanka. The overlap of the model ages of rocks in this area and those in the Highland Complex of Sri Lanka supports the notion that these two sets of rocks were joined to each other in Gondwana. They belong to a belt that ran from Antarctica through Sri Lanka and India into Madagascar. This belt was involved in Pan-African tectono-metamorphism, as reflected in the 550 Ma age of the last, granulite-forming, event throughout the belt.     

The role of tides in redistributing macrodetrital aggregates within the Swartvlei estuary

The Swartvlei estuary possesses a prolific growth of both intertidal and subtidal eelgrass,Zostera capensis. During 1984 less than 12% of the eelgrass beds were located in the upper half of the estuary, yet deposition ofZostera/macroalgal wrack in this region, when the estuary was linked to the sea (open phase), was similar to that in the lower half. Over a period of 20 semidiurnal tidal cycles there was a net gain of 2.5 tonnes dry mass of plant material into the upper reaches. Export of aquatic macrophytes and filamentous algae from the lower reaches toward the sea over 20 tidal cycles amounted to 1.6 tonnes dry mass. The amount of plant material transported during spring tides was 2 to 3 times greater than that carried during neap tides. Shallowing of the estuary mouth due to sand deposition resulted in a decline in the tidal prism and a decrease in macrodetrital flux. Total export ofZostera and associated algae amounted to 0.87 g ash-free dry mass m^?2d^?1 and represented a monthly export of 18% ofZostera bed biomass. Deposition of plant wrack during the 1984–1985 closed phase amounted to 63 g dry mass per meter of shore per day at the lower reaches site but only 10 g m^?1d^?1 was recorded at the upper reaches site. The relatively low latter value was attributed to the absence of tidal action which transports macrodetritus from the lower and middle reaches into the upper part of the system. During the 1984 open phase 70 g m^?1d^?1 was deposited at the lower reaches site and 68 g m^?1d^?1 at the upper reaches site. The role of tides in the redistribution of aquatic macrophyte primary production in the Swartvlei estuary was therefore clearly underscored.     

Three varieties of alpine-type ultramafic rocks in the Norwegian Caledonides and basal gnesis complex

Three varieties of alpine-type ultramafic rocks are distinguish in the Norwegian Caledonides associated Basal Gneiss Complex. Type one rocks have primary (magmatic) olivine, clinopyroxene, orthopyroxene and chromite, and are partly or completely serpentinised. They are found exclusively in rocks of Cambro-Silurian age. Type two are polymetamorphic metaperidotites or sagvandites consisting of olivine, enstatite and carbonate minerals, with talc and amphibole commonly being present. They are found in medium- to high-grade metamorphic rocks. Type three also show a metamorphic mineral association of olivine, orthopyroxene and minor chromite, while clinopyroxene, amphibole and chrome-bearing chlorite may also be present in some samples. Garnet may or may not occur and, where present, is often surrounded by reaction rims of spinel and amphibole. The type three ultramafic bodies are serpentinised to varying degrees and occur in high-grade metamorphic gneisses which may also contain eclogites and anorthosites. Distinction of these three varieties of ultramafic body may be useful for correlation purposes and for more detailed studies on the nature of their metamorphism.     

Import of coastally-derived chlorophylla to South Slough, Oregon

Material transfer between estuaries and the nearshore zone has long been of interest, but information on the processes affecting Pacific Northwest estuaries has lagged behind other areas. The west coast of the U.S. is a region of seasonally variable upwelling that results in enhanced phytoplankton production in the nearshore zone. We examined estuarine-nearshore links over time by measuring physical oceanographic variables and chlorophylla concentration from an anchor station in South Slough, Oregon. Data was collected during 24-h cruises conducted at approximately weekly intervals during summer 1996 and spring 1997. The results demonstrate that the physical oceanography of this estuarine site was strongly influenced by the coastal ocean. Marine water reached the estuarine site on every sampled tide, and chlorophylla was clearly advected into the estuary with this ocean water. In contrast, phytoplankton concentrations were comparatively reduced in the estuarine water. There were, however, large fluctuations in the import of chlorophyll over the course of the summer. These variations likely reflect upwelling-generated phytoplankton production in the coastal ocean and subsequent cross-shelf transport to the estuary. Suspension feeding organisms in South Slough likely depend on the advection of this coastally-derived phytoplankton. The large allochthonous chlorophyll input measured for this system appears dissimilar from most estuaries studied to date. Previous investigations have focused on the outwelling and inwelling of materials in estuaries. We must now consider the influence of coastal upwelling and downwelling processes on estuarine material exchange.     

A middle–late Ediacaran volcano‐sedimentary record from the eastern Arabian‐Nubian shield

The Ediacaran Jibalah Group comprises volcano‐sedimentary successions that filled small fault‐bound basins along the NW–SE‐trending Najd fault system in the eastern Arabian‐Nubian Shield. Like several other Jibalah basins, the Antaq basin contains exquisitely preserved sedimentary structures and felsic tuffs, and hence is an excellent candidate for calibrating late Ediacaran Earth history. Shallow‐marine strata from the upper Jibalah Group (Muraykhah Formation) contain a diversity of load structures and intimately related textured organic (microbial) surfaces, along with a fragment of a structure closely resembling an Ediacaran frond fossil and a possible specimen of Aspidella. Interspersed carbonate beds through the Muraykhah Formation record a positive δ¹³C shift from ?6 to 0‰. U‐Pb zircon geochronology indicates a maximum depositional age of ~570 Ma for the upper Jibalah Group, consistent with previous age estimates. Although this age overlaps with that of the upper Huqf Supergroup in nearby Oman, these sequences were deposited in contrasting tectonic settings on opposite sides of the final suture of the East African Orogen.     

In search of a hidden long-term isolated sub-chondritic Nd/Nd reservoir in the deep mantle: Implications for the Nd isotope systematics of the Earth

Here we search for evidence of the existence of a sub-chondritic ¹⁴²Nd/¹⁴⁴Nd reservoir that balances the Nd isotope chemistry of the Earth relative to chondrites. If present, it may reside in the source region of deeply sourced mantle plume material. We suggest that lavas from Hawai’i with coupled elevations in ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os, from Iceland that represent mixing of upper mantle and lower mantle components, and from Gough with sub-chondritic ¹⁴³Nd/¹⁴⁴Nd and high ²⁰⁷Pb/²⁰⁶Pb, are favorable samples that could reflect mantle sources that have interacted with an Early-Enriched Reservoir (EER) with sub-chondritic ¹⁴²Nd/¹⁴⁴Nd.High-precision Nd isotope analyses of basalts from Hawai’i, Iceland and Gough demonstrate no discernable ¹⁴²Nd/¹⁴⁴Nd deviation from terrestrial standards. These data are consistent with previous high-precision Nd isotope analysis of recent mantle-derived samples and demonstrate that no mantle-derived material to date provides evidence for the existence of an EER in the mantle.We then evaluate mass balance in the Earth with respect to both ¹⁴²Nd/¹⁴⁴Nd and ¹⁴³Nd/¹⁴⁴Nd. The Nd isotope systematics of EERs are modeled for different sizes and timing of formation relative to ε¹⁴³Nd estimates of the reservoirs in the μ¹⁴²Nd = 0 Earth, where μ¹⁴²Nd is ((measured ¹⁴²Nd/¹⁴⁴Nd/terrestrial standard ¹⁴²Nd/¹⁴⁴Nd)−1 * 10⁻⁶) and the μ¹⁴²Nd = 0 Earth is the proportion of the silicate Earth with ¹⁴²Nd/¹⁴⁴Nd indistinguishable from the terrestrial standard. The models indicate that it is not possible to balance the Earth with respect to both ¹⁴²Nd/¹⁴⁴Nd and ¹⁴³Nd/¹⁴⁴Nd unless the μ¹⁴²Nd = 0 Earth has a ε¹⁴³Nd within error of the present-day Depleted Mid-ocean ridge basalt Mantle source (DMM). The 4567 Myr age ¹⁴²Nd-¹⁴³Nd isochron for the Earth intersects μ¹⁴²Nd = 0 at ε¹⁴³Nd of +8 ± 2 providing a minimum ε¹⁴³Nd for the μ¹⁴²Nd = 0 Earth. The high ε¹⁴³Nd of the μ¹⁴²Nd = 0 Earth is confirmed by the Nd isotope systematics of Archean mantle-derived rocks that consistently have positive ε¹⁴³Nd.If the EER formed early after solar system formation (0-70 Ma) continental crust and DMM can be complementary reservoirs with respect to Nd isotopes, with no requirement for significant additional reservoirs. If the EER formed after 70 Ma then the μ¹⁴²Nd = 0 Earth must have a bulk ε¹⁴³Nd more radiogenic than DMM and additional high ε¹⁴³Nd material is required to balance the Nd isotope systematics of the Earth.     

Response of the uppermost mantle to Indo-Eurasian collisional tectonics

The rheological law for the power law creep field of peridotite suggested by Chopra and Paterson (1981, 1984) is combined with theoretically modelled thermal and stress perturbations for continent-continent collisions (Bird et al., 1975; Bird, 1978a) to determine the effect of such collisions on the uppermost mantle below the zone of convergence. The model predicts a change from continental to oceanic geotherms during the oceanic subduction phase, followed by a rapid rise in differential stress during the collisional phase.These perturbations, when combined, cause a cyclical change in the steady state flow of the uppermost mantle ending with a re-equilibration of thermal and stress regimes. The thermal re-equilibration proceeds at a much slower rate, with a suggested total re-equilibration period of about 100 m.y. after collision has ceased. The combination of the flow law with the model predicts that the perturbations in the mantle are limited in depth with no changes in mantle behavior below about 100 km.