Relationship between surface morphology and chemical composition of spheroidal carbonaceous particles within sediment core samples recovered from Osaka Bay,Japan

Spheroidal carbonaceous particles (SCPs) are produced by the high-temperature combustion of fossil fuels and are emitted to the atmosphere. Previous studies are divided regarding whether SCPs derived from the combustion of various fossil fuels can be identified based on their surface morphologies and chemical compositions. In this study, we examined the surface morphology and chemical composition of SCPs in sediment core samples collected from Osaka Bay, Japan, with the aim of evaluating the usefulness of SCPs morphology in identifying their origin. Scanning electron microscope (SEM) observations reveal three distinct surface morphologies: (1) smooth, (2) rough and irregular, and (3) convoluted and layered. According to a morphological classification scheme proposed previously, the former two morphologies correspond to coal-derived carbon particles, whereas the latter corresponds to oil-derived carbon particles. In terms of the chemical compositions of the particles with different morphologies, as analyzed by energy-dispersive spectroscopy, linear discriminant analysis reveals that the two fuel types can be distinguished. An overall success rate of >90% of reference of morphologically classified material correctly assigned to two groups that are chemically different each other, indicating a relationship between surface morphology and chemical composition. This result suggests that morphological characterization based on conventional SEM observations is useful in identifying the source fuel of SCPs.     

Laboratory Study of the Bidirectional Reflectance of Powdered Surfaces: On the Asymmetry Parameter of Asteroid Photometric Data

We performed laboratory experiments on the bidirectional reflectance of powdered surfaces of dunite, graphite, and Allende (CV3) and Gao (H5) meteorites. The particle size of each sample varied from tens to hundreds of micrometers. The absolute bidirectional reflectance was determined for two ranges of phase angle: from 2° to 80° at 0° angle of incidence and from 2° to 155° at 75° angle of incidence. The phase angle was incremented every 1° in between 2° and 5° and every 10° between 10° and 150°. We determined the Hapke parameters and found that the values of the asymmetry parameter retrieved for most of the samples were positive when the coverage of the phase angle was wide, 2° to 155°, although the values derived from remote sensing instruments on asteroid flyby missions have been negative or nearly zero. Among our sample surfaces, only those of graphite, Allende, and Gao with particle sizes of hundreds micrometers show negative or nearly zero values. The single-scattering albedos determined for the Gao samples are comparable to the values of S-class asteroids, while those for the Allende samples are much larger than those of C-class asteroids.     

Seismic damage accumulation in multiple mainshock–aftershock sequences

Earthquakes are generally clustered, both in time and space. Conventionally, each cluster is made of foreshocks, the mainshock, and aftershocks. Seismic damage can possibly accumulate because of the effects of multiple earthquakes in one cluster and/or because the structure is unrepaired between different clusters. Typically, the performance-based earthquake engineering (PBEE) framework neglects seismic damage accumulation. This is because (i) probabilistic seismic hazard analysis (PSHA) only refers to mainshocks and (ii) classical fragility curves represent the failure probability in one event, of given intensity, only. However, for life cycle assessment, it can be necessary to account for the build-up of seismic losses because of damage in multiple events. It has been already demonstrated that a Markovian model (i.e., a Markov chain), accounting for damage accumulation in multiple mainshocks, can be calibrated by maintaining PSHA from the classical PBEE framework and replacing structural fragility with a set of state-dependent fragility curves. In fact, the Markov chain also works when damage accumulates in multiple aftershocks from a single mainshock of known magnitude and location, if aftershock PSHA replaces classical PSHA. Herein, this model is extended further, developing a Markovian model that accounts, at the same time, for damage accumulation: (i) within any mainshock–aftershock seismic sequence and (ii) among multiple sequences. The model is illustrated through applications to a series of six-story reinforced concrete moment-resisting frame buildings designed for three sites with different seismic hazard levels in Italy. The time-variant reliability assessment results are compared with the classical PBEE approach and the accumulation model that only considers mainshocks, so as to address the relevance of aftershocks for life cycle assessment.     

Distribution of fault rocks in the fracture zone of the Nojima Fault at a depth of 1140 m: Observations from the Hirabayashi NIED drill core

Abstract Characteristics of deformation and alteration of the 1140 m deep fracture zone of the Nojima Fault are described based on mesoscopic (to the naked eye) and microscopic (by both optical and scanning electron microscopes) observations of the Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drill core. Three types of fault rocks; that is, fault breccia, fault gouge and cataclasite, appear in the central part of the fault zone and two types of weakly deformed and/or altered rocks; that is, weakly deformed and altered granodiorite and altered granodiorite, are located in the outside of the central part of the fault zone (damaged zone). Cataclasite appears occasionally in the damaged zone. Six distinct, thin foliated fault gouge zones, which dip to the south-east, appear clearly in the very central part of the fracture zone. Slickenlines plunging to the north-east are observed on the surface of the newest gouge. Based on the observations of XZ thin sections, these slickenlines and the newest gouge have the same kinematics as the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake), which was dextral-reverse slip. Scanning electron microscopy observations of the freeze-dried fault gouge show that a large amount of void space is maintained locally, which might play an important role as a path for fluid migration and the existence of either heterogeneity of pore fluid pressure or strain localization.     

Crustal thermal regime inferred from magnetic anomaly data and its relationship to seismogenic layer thickness: The Japanese islands case study

The seismogenic layer thickness correlates with surface heat flow beneath the Japanese islands. However, this correlation is shown at restricted area, where seismic activity is high. In order to overcome this spatial limitation, we used another approach to estimate the regional thermal structure in the crust beneath the Japanese islands with more uniform coverage. The bottom depths of the magnetized crust determined from the spectral analysis of residual magnetic anomalies is generally interpreted as the level of the Curie point isotherm. We applied this method to estimate the crustal thermal structure in square windows of 2.125° × 2.125°. The obtained depths ranging from 11 to 30 km with average value of 18 km, correlate with the seismogenic layer thickness. It suggests that the Curie point depth is a useful indicator of the crustal thermal structure in these regions.     

Geochemical assessment of arsenic contamination in well water and sediments from several communities in the Nawalparasi District of Nepal

Arsenic contamination of well water is a serious issue in the Nawalparasi District of the Terai region in Nepal. A local investigation was carried out on 137 tube wells in 24 communities of the district in December 2011. The investigation revealed that the average arsenic concentration in the tube wells was 350 μg/L, and that nearly 98 % of the wells exceeded the WHO guideline arsenic level limit of 10 μg/L. Highly contaminated well water, with more than 400 μg/L of arsenic, was found within the limited depth ranges of 18–22 and 50–80 m. High arsenic levels exceeding 500 μg/L were detected in shallower wells at Patkhauli, Mahuawa, Thulokunwar, and Goini located between 27.517° and 27.543°N and between 83.648° and 83.748°E. Boring sampling at five communities of Kashiya, Goini, Sanokunwar, Thulokunwar, and Mahuawa revealed two aquifers located at the two depths around 14–22 and 41–50 m in each community. Dark gray or black-colored peaty clay layers rich in organic matter were distributed at depths of 18–21 m beside the upper aquifers with high arsenic concentration in each community. Positive correlations were shown between iron and arsenic in the sediments from the five communities. It can be inferred that these results were caused by dissolution of iron-oxyhydroxide molecules with arsenic from solid phases. Microbial metabolisms have a great potential to induce the dissolution and release arsenic attached on the solid phases into aqueous phases depending on the level of redox potential and pH.     

The spatial and temporal distributions of spheroidal carbonaceous particles from sediment core samples from industrial cities in Japan and China

Spheroidal carbonaceous particles (SCPs) are produced by the high-temperature combustion of fossil fuels and emitted in to the atmosphere. The distribution and concentration of SCPs in sediments have been used as a proxy for the distribution of pollutants emitted to the atmosphere. However, the effect on the distribution of SCPs due to industrial activity at nearby industrial cities is yet to be quantified. To clarify the origin of SCPs of ~20 μm in size that are preserved in sediments, we evaluated the abundance, surface morphology, and chemical composition of SCPs in sediment core samples recovered from industrial cities in Japan (Tokyo, Osaka, and Nagasaki) and China (Beijing), with the cities being located at least ~500 km away from each other. Vertical profiles of SCP concentration in sediment cores from the Japanese cities and Beijing are different, reflecting the contrasting industrial histories of the two countries. The SCPs from different cities show contrasting morphological and chemical characteristics, suggesting that ~20 μm SCPs in sediments from the industrial cities could represent the local combustion history in detail, as the influx of local SCPs is dominant at such sites.     

Large-scale landslides in Toyama Prefecture,central Japan,and their probable relationship with earthquakes

Large-scale landslides along the Kubusu and Besso rivers in Toyama Prefecture are developed in the Miocene Iwaine Formation, which is composed of andesitic lava, tuff, and tuff breccia. In the middle member of this formation, the tuff is easily altered to montmorillonite-bearing rock, and subsequently plays an important role in the development of landslides events, which tend to be large-scale events, as the massive lava of the upper member forms a cap rock over the tuff. The Kiritani and Koinami basins, which are flat intermontane basins located along the Kubusu and Besso rivers, respectively, are interpreted as landslide-dammed lakes, later filled with sediment. Accelerator mass spectrometry ¹⁴C ages show that the landslides forming each dam occurred simultaneously, at approximately 2500 BP. These ages were measured from wood fragments embedded in the landslide material of Kiritani, and from an in situ stump drowned during the impoundment of Koinami. If the trigger of these landslides was an earthquake, it is most likely to have been the penultimate event along the Atotsugawa fault zone.     

Residual structural capacity evaluation of steel moment‐resisting frames with dynamic‐strain‐based model updating method

This paper presents a method for evaluating the residual structural capacity of earthquake‐affected steel structures. The method first quantifies the damage severity of a beam by computing the dynamic‐strain‐based damage index. Next, the model used to analyze the structure is updated based on the damage index, to reflect the observed damage conditions. The residual structural capacity is then estimated in terms of changes in stiffness and strength, which can be applied by structural engineers, via a nonlinear static analysis of the updated model. The main contributions of this paper are in performance evaluation of the dynamic‐strain‐based damage index for seismically induced damage using a newly developed substructure testing environment, consideration of various damage patterns in composite beams, and extension of a local damage evaluation technique to a residual capacity estimation procedure by incorporating the model‐updating technique. In laboratory testing, the specimens were damaged quasi‐statically, and vibration tests were conducted as the damage proceeded. First, a bare steel beam–column connection was tested, and then a similar one with a floor slab was used for a more realistic case. The estimated residual structural capacities for these specimens were compared with the static test results. The results verified that the proposed method can provide fine estimates of the stiffness and strength deteriorations within 10% for the specimen without the floor slab and within 30% for that with the floor slab. Copyright © 2017 John Wiley & Sons, Ltd.