The fossil H chondrite Brunflo, found in a slab of Ordovician limestone from central Sweden, is pervasively altered to an assemblage dominated by calcite and barite. The meteorite is surrounded by a 15–20 cm wide zone of lighter colors than the unaffected limestone due to dissolution of hematite. Here we present detailed geochemical analyses of two meteorite samples, 14 limestone samples at distances from 0 to 29 cm along two profiles from the meteorite, and a reference sample of Brunflo limestone. Element concentrations in Brunflo and surrounding bleached limestone have been strongly disturbed during two stages of alteration (early oxygenated and deep burial). In the meteorite, the Ni/Co ratio has changed from an initial value of 20 to 0.8 and redox sensitive elements like V, As, Mo, Re and U are strongly enriched. The sulfur isotope composition of barite from Brunflo (δ34S=+35‰) indicates initial loss of meteoritic sulfide, followed by later accumulation of sea water sulfate as barite. During deep burial under more reducing conditions, reduction processes supported by an externally derived reductant possibly derived from alum shale underlying the limestone, were largely responsible for the observed redox phenomena. In spite of massive redistribution of many elements, concentrations of Pt, Ir and Au remain at chondritic levels. The geochemistry and mineralogy of alteration determined for Brunflo are similar to those in “reduction spots” in red beds, where accumulation of a similar suite of elements (except Mo, Re) occurred as a result of isolated reduction activity. 相似文献
Farming is the major source of income for the villagers of North-central Sri Lanka. However, chronic kidney disease of unknown etiology is a major health hazard in the area and it is assumed that agricultural contaminants are the major causative agents. This study focuses on the geochemistry of soils in the area to determine possible natural and anthropogenic impacts of the problem. X-ray fluorescence analysis was used to determine the abundance of selected major and trace elements. Results show that geo-enrichment for many elements indicates slight to significant variations between agricultural and non-agricultural soils. Geoaccumulation index (Igeo) shows higher pollution levels of Pb and V (2 < Igeo < 3) and very lower pollution levels of As, Zn, Cu, Fe and Mn (1 < Igeo < 2) in agricultural soils. However, Igeo for non-agricultural soils implies lack of contaminations (Igeo < 1). Positive correlations of As with Pb and Zn and negative correlations with Cu, Ni and Cr suggest that they may have derived from different sources such as sulfide minerals of basement rocks, fertilizers and agrochemicals. The results of this study suggest that there is no significant threat from As and other trace elements to soils. The accumulation of these elements in agricultural fields may have been effectively controlled by seasonal farming practices. However, there is a potential environmental risk from elements such as Pb and V due to their significant enrichment in soils. 相似文献
Spatial and temporal variations in summer and winter extreme temperature indices are studied by using daily maximum and minimum temperatures data from 227 surface meteorological stations well distributed over India for the period 1969–2012. For this purpose, time series for six extreme temperature indices namely, hot days (HD), very hot days (VHD), extremely hot days (EHD), cold nights (CN), very cold nights (VCN), and extremely cold nights (ECN) are calculated for all the stations. In addition, time series for mean extreme temperature indices of summer and winter seasons are also analyzed. Study reveals high variability in spatial distribution of threshold temperatures of extreme temperature indices over the country. In general, increasing trends are observed in summer hot days indices and decreasing trends in winter cold night indices over most parts of the country. The results obtained in this study indicate warming in summer maximum and winter minimum temperatures over India. Averaged over India, trends in summer hot days indices HD, VHD, and EHD are significantly increasing (+1.0, +0.64, and +0.32 days/decade, respectively) and winter cold night indices CN, VCN, and ECN are significantly decreasing (−0.93, −0.47, and −0.15 days/decade, respectively). Also, it is observed that the impact of extreme temperature is higher along the west coast for summer and east coast for winter.
The paper discusses the conditions corresponding to the largest and smallest North Atlantic Oscillations (NAOs). It is shown
that in winter, when NAOs are at a minimum, the number of cyclones over the Black Sea increases. At the same time, cloudiness
in the Atlantic-European section becomes heavier, compared with the largest NAO. Heavy cloudiness over the Balkan and Karpaty
mountains, with NAO at a minimum, may imply the greater likelihood of Balkan cyclones’ penetration into the Black Sea region.
The mechanism responsible for the generation of maximum (minimum) cloudiness in the Atlantic-European section is discussed.
Translated by Vladimir A. Puchkin. 相似文献
Doklady Earth Sciences - The results of studies of the trace-element contents in olivine and plagioclase of chondrules from equilibrated ordinary chondrite Orlovka (H5) are reported. Olivine is... 相似文献
Summary Following a recent hypothesis on the role of activated sodium chloride particles as potential nuclei of atmospheric precipitation, further analysis is made of average annual data due toC. Junge on the chemical composition of rainwater salts, and correlation of some parameters with the total amount of rainfall is attempted. It is found that the results obtained are in agreement with the proposed role of activated sodium chloride as a nucleus of a substantial part of the atmospheric precipitation. 相似文献
Natural gas can have two distinct origins, biogenic and thermogenic sources. This paper investigates the types and maturities of natural gas present in the SE Columbus basin, offshore Trinidad. The chemical composition and the isotope ratios of C and H were determined for approximately 100 samples of natural gas from eight areas within the SE Columbus basin. These compositions and isotopic data are interpreted to identify the origins of gas (biogenic, thermogenic) and maturity. The data showed that the gases in the SE Columbus basin are of both biogenic and thermogenic origin with a trend of mainly thermogenic to mixed to biogenic when moving from SW to NE across the basin. This trend suggests differential burial of the source rock. The presence of mixed gas indicates there was migration of gas in the basin resulting in deeper thermogenic gas mixing with shallow biogenic gas. 相似文献
In the Southern Gas Basin (SGB) of the North Sea there are many mature gas fields where time‐lapse monitoring could be very beneficial in extending production life. However, the conditions are not immediately attractive for time‐lapse seismic assessment. This is primarily because the main production effect to be assessed is a pore pressure reduction and frame stiffening because of gas production in tight sandstone reservoirs that also have no real seismic direct hydrocarbon indicators. Modelling, based on laboratory measurements, has shown that such an effect would be small and difficult to detect in seismic data. This paper makes two main contributions. Firstly, this is, to our knowledge, the first time‐lapse study in the SGB and involves a real‐data assessment of the viability for detecting production in such an environment. Secondly, the feasibility of using markedly different legacies of data in such a study is addressed, including an assessment of the factors influencing the crossmatching. From the latter, it is found that significant, spatially varying time shifts need to be, and are successfully, resolved through 3‐D warping. After the warping, the primary factors limiting the crossmatching appear to be residual local phase variations, possibly induced by the differing migration strategies, structure, reverberations and different coherencies of the volumes, caused by differences in acquisition‐structure azimuth and acquisition fold. Despite these differences, a time‐lapse amplitude signature is observed that is attributable to production. The character of the 4‐D amplitude anomalies may also indicate variations in stress sensitivity, e.g. because of zones of fracturing. Additionally, warping‐derived time attributes have been highlighted as a potential additional avenue for detection of pressure depletion in such reservoirs. Although the effects are subtle, they may indicate changes in stress/pressure in and around the reservoir because of production. However, to fully resolve the subtle time‐lapse effects in such a reservoir, the data differences need to be better addressed, which may be possible by full re‐processing and pre‐stack analysis, but more likely dedicated 4‐D acquisition would be required. 相似文献
Flyrock is a rock thrown to greater distance than desired and is a dangerous and unwanted phenomenon in surface mines, particularly, when blasting is proceeding close to human occupation and dwellings. The prediction of flyrock distance is critical in defining the statutory danger zone of blasting and has evaded blasters for quite some time. Control of flyrock with its distance prediction involves identification of key variables and understanding their influence. Theoretical models though provide a good understanding of the phenomenon, the confidence that can be assigned to such models is still very less. This study presents novel method to identify, merge and consolidate independent variables into a simplified equation for flyrock distance prediction without compromising on the actual field applications. Field investigations were carried out in several mines and relevant data were generated relating to flyrock. The key parameters, namely, explosive, blast design and rock mass nature were characterized and analysed. An empirical model involving the key contributors for flyrock generation and distance prediction were assimilated and a new equation was developed based on actual data collected by employing surface response analysis. The developed model was found to be statistically significant and validated. Sensitivity analysis was conducted to ascertain the role of independent factors on flyrock distance. 相似文献