The lunar geochemistry of chromium and vanadium

Crystal/liquid partition coefficients for Cr, V, Mn, and Fe have been determined experimentally between olivine, orthopyroxene, clinopyroxene and silicate melt possesing the composition of a primitive lunar green glass, at oxygen fugacities appropriate to the lunar interior. These species all behave essentially as compatible elements and possess crystal/liquid partition coefficients mostly between 0.3 and 0.9. Partition coefficients for Cr, V, and Mn are generally similar to those of Fe. This implies that crystal/liquid fractionation processes in the lunar interior which do not involve the participation of spinels would not have been effective in fractionating MnO, CrO, and VO from FeO. The well-known constancy of FeO/MnO ratios in nearly all lunar rocks is a reflection of this behaviour. It is shown that comparably strong correlations between CrO-;FeO and VO-;FeO exist for lunar highland breccias and soils from all sites and that these correlations extend to primitive lunar volcanic glasses associated with mare volcanism, strongly suggesting that the CrO/FeO and VO/FeO ratios so derived are of global importance. The observed ratios characterizing differentiated regions of the Moon can be combined with the corresponding ratios for residual refractory portions of the Moon, using measured partition coefficients for Fe, Mg, Cr, V, and Mn between olivine, orthopyroxene and liquid. Bulk Moon abundances for Cr and V have been calculated for a range of reasonable assumptions concerning the petrogenetic relationships between differentiated portions of the Moon and complementary refractory residua consisting of olivine and orthopyroxene mineralogies. Because of the small differences in crystal liquid partition coefficients between FeO, CrO, and VO, these estimates are insensitive to large variations in the models. The bulk Moon is accordingly estimated to contain 2190–2463 ppm Cr and 79–95 ppm V. These values are very similar to the Cr and V contents of the Earth's mantle, estimated as 3010 ppm Cr and 81 ppm V by Sun (1982). The geochemical implications of these similarities are discussed.     

Bidimensional spectroscopy of network bright points

We develop an automatic, computer controlled procedure to select and to analyze the Network Bright Points (NBPs) on solar images. These have been obtained at the Sac Peak Vacuum Tower Telescope by means of the Universal Birefringent Filter and Zeiss H filters, tuned, respectively, along the profiles of the H, Mg-b1, Na-D2, and H lines.A structure is identified as an NBP if at the wavelength H- 1.5 A its maximum intensity is greater than I + 3 and its area is greater than 1.5 arc sec² at I + 1.5, where I is the mean value and the standard deviation of the intensity distribution on the image. Each detected NBP is then searched and confirmed in all the remaining 31 images at different wavelengths.For each NBP several parameters are measured (position, area, mean and maximum contrast, Dopplergram velocity, compactness, and so on) and some identification constraints are applied.The statistical analysis of the various parameter distributions, for NBPs present within an active region and its surroundings, shows that two types of NBPs can be identified according to the value of their mean contrast C _min the H- 1.5 Å image (C _m 0.1 type I, C _m> 0.1 type II). The type I NBPs (all occurring on the boundaries of the supergranular network) appear to be much more frequent (180/26) than the type II ones.The size A of type I NBPs is less than 1.0 arc sec for H/H wings but of the order of 1.2 arc sec for Na-D2 and Mg-bl. The mean contrast C _m is around the value of 10% along the Na-D2 and Mg-bl profiles and of 20% along the H/H wings.The C _m - A scatter diagrams show, for the photospheric radiation (h < 100 km), a narrow range of variability for C _min correspondence with a wide range for A. For radiation orginated at higher levels (h > 200 km), the C _m- A scatter diagrams seem to indicate, even if with a large variance, that the highest C _m's tend to correspond to the highest A values.The mean Doppler shift is close to zero for Na-D2 and Mg-bl lines but negative (downward motion) for H and H lines.The type II NBPs tends to be preferentially located in the neighbourhood of small, compact sunspots and their detectability is almost constant through all the 4 studied line profiles. No conclusions can be derived on the mean size, contrast and Doppler shift values because their distributions are too dispersed. The only positive information is that its C _m- A scatter diagram, in H and H wings, indicates a wide range of variability for C _m in correspondence with very narrow range of variability for A.     

Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.     

Heterodyne spectroscopy of the 158 micron C II line in M42

We have obtained velocity-resolved spectra of the 12C II 157.8 microns 2P3/2-2P1/2 fine structure line in the M42 region of Orion. Observations at 0.8 km s-1 resolution with a laser heterodyne spectrometer show multiple velocity components in some locations, with typical linewidths of 3-5 km s-1. Spectra of theta 1C and BN-KL also show weak emission from the F = 2-1 hyperfine component of the equivalent 13C II line. From the observed 12C II/13C II line intensity ratios, we deduce that the 12C II emission is optically thick with tau approximately 5 at both positions. Excitation temperatures of 128 K and 90 K, together with column densities of approximately 1 x 10(19) cm-2 and approximately 4 x 10(18) cm-2, are derived for theta 1C and BN-KL, respectively.     

The possible formation of a hydrogen coma around comets at large heliocentric distances

An observational test--the detection of a hydrogen coma around comets at large heliocentric distances--is proposed for determining whether comets were formed by the agglomeration of unaltered, ice-coated, interstellar grains. Laboratory experiments showed that amorphous water ice traps H2, D2, and Ne below 20 K and does not release them completely until the ice is heated to 150 K. Gas/ice ratios as high as 0.63 are obtainable. Thus, if the ice-coated interstellar grains were not heated above approximately 110 K, prior to their agglomeration into cometary nuclei, the inward propagating heat waves should release from the comets a continuous flux of molecular hydrogen. This flux would exceed that of water molecules at approximately 3 AU preperihelion and approximately 4 AU postperihelion.     

A new approach to the librational solution in the Ideal Resonance Problem

The librational motion of the Ideal Resonance Problem (Garfinkel, 1966, Jupp, 1969) is treated through an initialnon-canonical transformation which, however, leaves the equations of motion in a quasi-canonical form, with Hamiltonian expressed in standard trigonometric functions amenable to traditional averaging techniques. The perturbed solutions, similarly expressed intrigonometric near-identity transformations, and their frequencies can be found to arbitrary order, with the elliptic integrals expected of the system introduced only in a final explicit quadrature for a Kepler-type equation in the angular variable. The specific transformations and resulting equations of motion are introduced, and explicit solutions for the original variables are found to second order, with mean motion accurate to fifth. Limitation of the present solution to the librational region, the extension of that solution to higher order, and observations on the form of the associated Hamiltonian are also discussed.     

Union republic migration trends in the USSR during the 1980s

"This article examines union republic migration trends in the USSR between 1979 and 1987 and prospects for indigenous out-migration from rural areas in Central Asia. The study is based on migration data derived by the residual technique and migration data from the 1985 microcensus. Results indicate that a south-to-north and probably Russian-dominated migration trend emerged in the 1980s, one which marks an almost complete reversal from earlier periods, especially 1959-70. Although Central Asia continues to have low levels of indigenous out-migration, labor surpluses and relatively waning capital investment in Central Asia may change this situation."     

Tepev Mons on Venus: Morphology and elastic bending models

Tepev Mons is a large volcanic structure of about 250 km in diameter with an elevation of 5 km above the surroundings, located at the southwestern edge of Bell Regio. It is surrounded by a moat with a depth of about 0.5 km. If this moat is considered to be caused by bending of the lithosphere due to the load of the volcano, then elastic bending models give limits for the effective flexural rigidity FR and the effective elastic thickness of the lithosphere L: 2 x 10²³ Nm FR 3 x 10²⁴ Nm and 30 km L 100 km. High flexural rigidities are associated with small depressions and large thicknesses of the lithosphere and vice versa.Contribution No 345, Institut für Geophysik der Universität Kiel, F.R.G.     

A new approach to the possibilities of Σ(D)-dependence and distances of the supernova remnants

A new way of choosing of the calibrators for constructing (D)-dependence of supernova remnants (SNR) is suggested. A knowledge of the distance of an SNR is not sufficient to consider it as a calibrator. It is shown that neither more accurate determination of distance to calibrators, nor an increase in their number, nor an increase in the precision of the remnant angular size and radio flux determination can lead to a considerable improvement of simple (D)-dependence which is suggested in the given work.For remnants with small surface brightnesses there is no (D)-dependence at all. The most accurate remnant distances currently known, are given: these are liable to change only after a large amount of additional observational data accurately compiled.     

Effects of mass transfer on an oscillating free-convection flow in the Stokes's problem past an infinite porous vertical limiting surface with heat sources and variable suction

An analysis of the effects of the mass transfer on the unsteady free-convection flow of a viscous incompressible fluid, past an impulsively started infinite porous vertical limiting surface with heat sources is presented, when the free-stream velocity and the suction velocity, are oscillating in the time about constant mean values. Approximate solutions for the coupled nonlinear equations are derived for the mean velocity, the mean temperature, the mean skin-friction, and the mean rate of heat transfer. All the above quantities are shown graphically followed, by a discussion.