Discovery of Pyrrhotite-Chalcopyrite-Bearing Amphibole Megacrysts in Tongling Area, Anhui Province

Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts, belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts.amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well.     

含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。     

稀土元素问题

稀有元素中有一族化学特性相近的金属,一共有十五种,它们称为稀土元素。这十五种金属是烂、铈、镨、钕、钷、钐、铕、钆、铽、镝、钬、铒、铥、镱和镏。此外还有两种性质相近的金属也可以归并进去,这就是抗和钇。数十年来,稀士元素的利用范围一直比较小,并且由于它们通常仅呈混合状态产于天然矿物原料之中,所以也只能混合利用。但是近五、六年来,在稀土元素的利用方面有了根本性的进展。现在发现稀土元素在工业上有新的更重要的用途,而且已经明确地规定了新的方向--单独利用本族的各种金属。     

Geochemical Characteristics and Genesis of Late Cretaceous to Paleogene Basalts in the Tuyon Basin, South Tianshan Mountains

1. Introduction The Tianshan Mountains is a typical intercontinental orogenic belt in the world. From late Carboniferous to Permian, the old Tianshan formed during the tectonic amalgamation of the Tarim block, Tianshan block and Siberia craton (Carroll et al, 1990). Mid-Cenozoic basalts are widely distributed in both the Tuyon basin of southwest Tianshan and its western part of Tianshan in Jierjisi in late Cretaceous-Paleogene period, which indicates the activation of the old Tianshan.…     

关于黄土及其沉陷性质的一本有价值的书

“黄土与黄土状亚粘土的建筑性质”一书的作者,将关于这种广泛分布并对建筑师极为重要的岩石的沉陷性问题的全部论述建立在十分正确的基础——黄土成因的特征上。他有力地指出,黄土类岩石的沉陷性是与它们的未达压密性、高的孔隙度、粉土成分,以及易为水破坏的胶结性碳酸盐和硫酸盐薄膜的存在有关的。胶结性的碳酸盐和硫酸盐薄膜胶结着粉土颗粒,主要是胶结石英,长石及其它稳定矿物(其中有很多矿物易于风化),而较少胶结粘土颗粒。所有这些决定黄土具有不良建筑性能的特征及性质,完全是由于它的形成条件及形成时的自然地理环     

中国西部元古代蓝片岩带——世界上保存最好的前寒武纪蓝片岩

阿克苏附近所发现的元古界阿克苏群为一完整的蓝片岩-绿片岩系列,我们通过野外调查肯定了这一认识,并认为它是高压-温相的变质块体,长40km,宽约2.5km.该变质岩由强烈片理化的绿泥石-黑硬绿泥石石墨片岩、黑硬绿泥石-多硅白云母片岩、绿片岩、蓝片岩及少量石英岩、变铁质岩组成.原岩包活泥质岩、砂岩、基性玻屑凝灰岩、块状熔岩、枕状熔岩及少量深海沉积物.蓝片岩的矿物组合:青铝闪石-绿帘石-绿泥石-钠长石-石英-阳起石.阿克苏群为世界上真正的前震旦纪蓝片岩之一,其变质年龄至少有800Ma.     

探地雷达(GPR)在海南岛东北部海岸带调查中的应用 *

对海南岛东北部海岸带调查采用了探地雷达(GPR)研究海岸带沙体的结构、展布和沉积序列,取得了很好的效果。文章通过和有限的露头资料对比以及对反射波形态、结构的研究,确定了海滩脊、海岸沙丘的反射特征以及潜水面的位置。雷达图像显示五龙港古海滩脊由亚水平、不连续、高振幅和透镜状反射波组成;木兰头海岸沙丘已受到人类活动的扰动,短的、陡倾斜反射可能代表未受扰动的海岸风成沙的前积层。研究表明探地雷达是一种可靠、快速和经济的地球物理方法,在砂砾质海岸可产生高质量、高分辨率和连续的反射剖面,值得加以推广。     

AGE OF THE ALTYN TAGH STRIKE—SLIP FAULT

AGE OF THE ALTYN TAGH STRIKE—SLIP FAULT     

汉诺坝玄武岩及大同火山群的岩石学和同位素地球化学

利用主元素、造岩矿物、REE及Sr、Nd、Pb同位素资料,对汉诺坝玄武岩和大同火山群的岩石学、地球化学、地幔源区特征、岩浆的分异和演化、玄武岩岩浆活动的构造条件进行了讨论。     

The Voisey’s Bay Ni-Cu-Co Sulfide Deposit, Labrador, Canada: Emplacement of Silicate and Sulfide-Laden Magmas into Spaces Created within a Structural Corridor

The Voisey’s Bay Ni-Cu-Co sulfide deposit is hosted in a 1.34 Ga mafic intrusion that is part of the Nain Plutonic Suite in Labrador, Canada.The Ni-Cu-Co sulfide mineralization is associated with magmatic breccias that are typically contained in weakly mineralized olivine gabbros, troctolites and ferrogabbros, but also occur as veins in adjacent paragneiss.The mineralization is associated with a dyke-like body which is termed the feeder dyke.This dyke connects the shallow differentiated Eastern Deeps chamber in the east to a deeper intrusion in the west termed the Western Deeps Intrusion.Where the conduit is connected to the Eastern Deeps Intrusion, the Eastern Deeps Deposit is developed at the entry line of the dyke along the steep north wall of the Eastern Deeps Intrusion.The Eastern Deeps Deposit is surrounded by a halo of moderately to weakly mineralized Variable-Textured Troctolite (VTT) that reaches a maximum thickness above the ENE-WSW axis of the Eastern Deeps Deposit. At depth to the west, the conduit is adjacent to the south side of the Western Deeps Intrusion, where the dyke and intrusion contain disseminated magmatic sulfide mineralization.The Reid Brook Zone plunges to the east within the dyke, and both the dyke and adjacent paragneiss are mineralized.The Ovoid Deposit comprises a bowl-shaped body of massive sulfide where the dyke widens near to the present-day surface.It is not clear whether this deposit was developed as a widened-zone within the conduit or at the entry point into a chamber that is now lost to erosion. The massive sulfides and breccia sulfides of the Eastern Deeps are petrologically and chemically different when compared to the disseminated sulfides in the VTT; there is a marked break in Ni tenor (Ni content in 100% sulfide, abbreviated to [Ni]100) and Ni/Co of sulfide between the two.The boundary of the sulfide types is often marked by strong sub-horizontal alignment of heavily digested and metamorphosed paragneiss fragments, development of barren olivine gabbro, and by a change from typically massive sulfides and breccias sulfides into more typical variable-textured troctolites with heavy to weak disseminated sulfide.Sulfides hosted in the feeder dyke tend to have low metal tenors ([Ni]100=2.5%-3.5%); sulfides in Eastern Deeps massive and breccia ores have intermediate Ni tenors ([Ni]100=3.5%-4%) and disseminated sulfides in overlying rocks have high Ni tenors ([Ni] 100=4%-8%) . Conduit-hosted mineralization and mineral zones in the paragneiss adjacent to the Reid Brook Deposit tend to have lower Ni tenor than the Ovoid and Eastern Deeps Deposits.The tenor of mineral hosted in the country rock gneisses tends to be the same as that developed in the conduit ; the injection of the sulfide into the country rocks likely occurred before formation of monosulfide solid solution.The Ovoid Deposit is characterized by coarse-grained loop-textured ores consisting of 10cm-2msized pyrrhotite crystals separated by chalcopyrite and pentlandite.A small lens of massive cubanite surrounded by more magnetite-rich sulfide assemblages represents what appears to be the product of in-situ sulfide fractionation. Detailed exploration in the area between the Reid Brook Zone and the Eastern Deeps has shown that these intrusions and ore deposits are connected by a branched dyke and chamber system in a major westeast fault zone.The Eastern Deeps chamber may be controlled by graben-like fault structures , and the marginal structures appear to have controlled dykes which connect the chambers at different levels in the crust.The geological relationships in the intrusion are consistent with emplacement of the silicate and sulfide laden magma from a deeper sub-chamber (possibly a deep eastward extension of the Western Deeps Intrusion where S-saturation was initially achieved) .The silicate and sulfide magmas were likely emplaced through this conduit into the Eastern Deeps intrusion as a number of different fragment laden pulses of sulfide-silicate melt that evolved with different R factors and in response to some variation in the degree of evolution of the parental magma.S isotope and S/Se data coupled with geological evidence point to a crustal source for the sulfur , and the site of equilibration of mafic magma and crustal S is placed at depth in a sulfidic Tasiuyak Gneiss. The structural control on emplacement of small intrusions with transported sulfide is a feature found in different nickel sulfide deposits around the world.Champagne glass-shaped openings in sub-vertical chonoliths are a common morphology for this deposit type (e.g.the Jinchuan , Huangshan , Huangshandong , Jingbulake , Limahe , Hong Qi Ling deposits in China , the Eagle deposits in the United States , and the Double Eagle deposit in Canada) .Some of the structures of the Midcontinent Rift of North America also host Ni-Cu-(PGE) deposits of this type (e.g.the Current Lake Complex in the Quetico Fault Zone in Ontario , Canada and the Tamarac mineralisation in the Great Lakes Structural Zone of the United States) .Other major nickel deposits associated with flat structures adjacent to major mantle-penetrating structures include the Noril’sk , Noril’sk II , Kharaelakh , NW Talnakh , and NE Talnakh Intrusions of the Noril’sk Region of Russia , the Kalatongke deposit in NW China , and Babel-Nebo in Western Australia.These deposits are all formed in mantle-penetrating structural conduits that link into the roots of large igneous provinces near the edges of old cratons.