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31.
Tourmalinization associated with peraluminous granitic intrusions in metapelitic host-rocks has been widely recorded in the Iberian Peninsula, given the importance of tourmaline as a tracer of granite magma evolution and potential indicator of Sn-W mineralizations. In the Penamacor-Monsanto granite pluton (Central Eastern Portugal, Central Iberian Zone), tourmaline occurs: (1) as accessory phase in two-mica granitic rocks, muscovite-granites and aplites, (2) in quartz (±mica)-tourmaline rocks (tourmalinites) in several exocontact locations, and (3) as a rare detrital phase in contact zone hornfels and metapelitic host-rocks. Electron microprobe and stable isotope (δ18O, δD, δ11B) data provide clear distinctions between tourmaline populations from these different settings: (a) schorl–oxyschorl tourmalines from granitic rocks have variable foititic component (X□ = 17–57 %) and Mg/(Mg + Fe) ratios (0.19–0.50 in two-mica granitic rocks, and 0.05–0.19 in the more differentiated muscovite-granite and aplites); granitic tourmalines have constant δ18O values (12.1 ± 0.1 ‰), with wider-ranging δD (?78.2 ± 4.7 ‰) and δ11B (?10.7 to ?9.0 ‰) values; (b) vein/breccia oxyschorl [Mg/(Mg + Fe) = 0.31–0.44] results from late, B- and Fe-enriched magma-derived fluids and is characterized by δ18O = 12.4 ‰, δD = ?29.5 ‰, and δ11B = ?9.3 ‰, while replacement tourmalines have more dravitic compositions [Mg/(Mg + Fe) = 0.26–0.64], close to that of detrital tourmaline in the surrounding metapelitic rocks, and yield relatively constant δ18O values (13.1–13.3 ‰), though wider-ranging δD (?58.5 to ?36.5 ‰) and δ11B (?10.2 to ?8.8 ‰) values; and (c) detrital tourmaline in contact rocks and regional host metasediments is mainly dravite [Mg/(Mg + Fe) = 0.35–0.78] and oxydravite [Mg/(Mg + Fe) = 0.51–0.58], respectively. Boron contents of the granitic rocks are low (<650 ppm) compared to the minimum B contents normally required for tourmaline saturation in granitic melts, implying loss of B and other volatiles to the surrounding host-rocks during the late-magmatic stages. This process was responsible for tourmalinization at the exocontact of the Penamacor-Monsanto pluton, either as direct tourmaline precipitation in cavities and fractures crossing the pluton margin (vein/breccia tourmalinites), or as replacement of mafic minerals (chlorite or biotite) in the host-rocks (replacement tourmalinites) along the exocontact of the granite. Thermometry based on 18O equilibrium fractionation between tourmaline and fluid indicates that a late, B-enriched magmatic aqueous fluid (av. δ18O ~12.1 ‰, at ~600 °C) precipitated the vein/breccia tourmaline (δ18O ~12.4 ‰) at ~500–550 °C, and later interacted with the cooler surrounding host-rocks to produce tourmaline at lower temperatures (400–450 °C), and an average δ18O ~13.2 ‰, closer to the values for the host-rock. Although B-metasomatism associated with some granitic plutons in the Iberian Peninsula seems to be relatively confined in space, extending integrated studies such as this to a larger number of granitic plutons may afford us a better understanding of Variscan magmatism and related mineralizations.  相似文献   
32.
Boundary-Layer Meteorology - Space–time correlations are fundamental to statistical theories and turbulence modelling. However, experimental studies of space–time correlations are often...  相似文献   
33.
In the paper, a numerical study of the size of a representative volume element (RVE) for both the heat flow as well as the linear elasticity problems is presented. A particular two-phase random microstructure is studied and the method is applied to the digital image of reconstructed 2D realization of random media. The minimum size of RVE is determined by the investigation of the convergence of apparent properties as the size of RVE is increasing. Then, two estimates of the minimum RVE size are proposed and it is shown that the estimates are in a good agreement with the results determined by the investigation of the convergence of apparent properties. The minimum size of RVE can be successfully predicted based only on the microstructure morphology. The statistical measures used in this work are: the two-point probability and the linealpath functions.  相似文献   
34.
The paper describes results of microgravity measurements made on the surface over an underground geo reactor where experimental coal gasification was performed in a shallow seam of coal. The aim of the research was to determine whether, and to what extent, the microgravity method can be used to detect and image a coal gasification zone, especially caverns where the coal was burnt out. In theory, the effects of coal gasification process create caverns and cracks, e.g., zones of altered bulk density. Before the measurements, theoretical density models of completely and partially gasified coal were analysed. Results of the calculations of gravity field response showed that in both cases on the surface over the gasification zone there should be local gravimetric anomalies. Over the geo reactor, two series of gravimetric measurements prior to and after gasification were conducted. Comparison of the results of two measurement series revealed the presence of gravimetric anomalies that could be related to the cavern formation process. Data from these measurements were used to verify theoretical models. After the experiment, a small cavern was detected at the depth of the coal seam by the test borehole drilled in one of the anomalous areas.  相似文献   
35.
On 19 March 2013, a tremor shook the surface of Polkowice town where the Rudna Mine is located. This event, of ML = 4.2, was the third most powerful seismic event recorded in the Legnica G?ogów Copper District (LGCD). Inhabitants of the area reported that the felt tremor was bigger and lasted longer than any other ones felt in the last couple of years. Analysis of spectral parameters of the records from in-mine seismic system and surface LUMINEOS network along with broadband station KSP record were carried out. The location of the event was close to the Rudna G?ówna Fault zone; the nodal planes orientations determined with two different approaches were almost parallel to the strike of the fault. The mechanism solutions were also obtained as Full Moment Tensor from P-wave amplitude pulses of underground records and waveform inversion of surface network seismograms. The results from the seismic analysis along with macroseismic survey and observed effects from the destroyed part of the mining panel indicate that the mechanism of the event was complex rupture initiated as thrust faulting on an inactive tectonic normal fault zone. The results confirm that the fault zones are the areas of higher risk, even in case of carefully taken mining operations.  相似文献   
36.
Volcanic ash can disperse thousands of kilometres from the source volcano and provide valuable chronostratigraphic markers for palaeoclimate studies. We present new cryptotephra findings of historical and modern Icelandic eruptions in annually laminated lacustrine sediment records from several sites within a 570 km SW–NE transect across northern Poland. Sediments from the two lakes Wąsoskie and Szurpiły contain glass shards originating from the Plinian Askja ad 1875 eruption and showing bimodal, rhyolitic and dacitic affinities. A further cryptotephra finding in Lake Lubińskie suggests a potential origin from the Hekla ad 1845 eruption. These new findings extend the tephra dispersal map towards the south-east and provide valuable isochrons for the synchronisation of palaeoclimate proxy data at the termination of the Little Ice Age in central eastern Europe. Very low glass concentrations of modern cryptotephra in Lake Wąsoskie were potentially correlated with the Eyjafjallajökull ad 2010 eruption. Further findings in the uppermost sediments of lakes Szurpiły and Żabińskie in north-eastern Poland tentatively suggest other sources from either the Hekla and/or Kamchatkan volcanoes.  相似文献   
37.
The aluminium (Al) cycle in glacierised basins has not received a great deal of attention in studies of biogeochemical cycles. As Al may be toxic for biota, it is important to investigate the processes leading to its release into the environment. It has not yet been ascertained whether filterable Al (passing through a pore size of 0.45 μm) is incorporated into biogeochemical cycles in glacierised basins. Our study aims to determine the relationship between the processes bringing filterable Al and glacier‐derived filterable nutrients (particularly Fe and Si) into glacierised basins. We investigated the Werenskiöldbreen basin (44.1 km2, 60% glacierised) situated in SW Spitsbergen, Svalbard. In 2011, we collected meltwater from a subglacial portal at the glacier front and at a downstream hydrometric station throughout the ablation season. The Al concentration, unchanged between the subglacial system and proglacial zone, reveals that aluminosilicate weathering is a dominant source of filterable Al under subglacial conditions. By examining the Al:Fe ratio compared with pH and the sulphate mass fraction index, we found that the proton source for subglacial aluminosilicate weathering is mainly associated with sulphide oxidation and, to a lesser degree, with hydrolysis and carbonation. In subglacial outflows and in the glacial river, Al and Fe are primarily in the forms of Al(OH)4 and Fe(OH)3. The annual filterable Al yield (2.7 mmol m‐2) was of a magnitude similar to that of nutrients such as filterable Fe (3.0 mmol m‐2) and lower than that of dissolved Si (18.5 mmol m‐2). Our results show that filterable Al concentrations in meltwater are significantly correlated to filterable and dissolved glacier‐derived nutrients (Fe and Si, respectively) concentrations in glaciers worldwide. We conclude that a potential bioavailable Al pool derived from glacierised basins may be incorporated in biogeochemical cycles, as it is strongly related to the concentrations and yields of glacier‐derived nutrients.  相似文献   
38.
Extensive research and increasing number of potential industrial applications made ionic liquids (ILs) important materials in design of new, cleaner technologies. Together with the technological applicability, the environmental fate of these chemicals is considered and significant efforts are being made in designing strategies to mitigate their potential negative impacts. Many ILs are proven to be poorly biodegradable and relatively toxic. Bioaugmentation is known as one of the ways of enhancing the microbial capacity to degrade xenobiotics by addition of specialized strains. The aim of current work was to select microbial species that could be used for bioaugmentation in order to enhance biodegradation of ILs in the environment. We subjected activated sewage sludge to the selective pressure of 1-methyl-3-octylimidazolium chloride ([OMIM][Cl]) and isolated nine strains of bacteria which were able to prevail in these conditions. Subsequently, we utilized axenic cultures (pure cultures) of these bacteria as well as mixed consortium to degrade this IL. In addition, we performed growth inhibition tests and found that bacteria were able to grow in 2 mM, but not in 20 mM solutions of [OMIM][Cl]. The biodegradation conducted by the isolated consortium was higher than conducted by the activated sewage sludge when normalized by the cell density, which indicates that the isolated strains seem specifically suited to degrade the IL.  相似文献   
39.
MichaŁek  G.  Ostrowski  M. 《Solar physics》2001,200(1-2):177-187
The spatial transport of charged particles in the presence of pure slab Alfvén waves, pure isotropic magnetosonic waves and their mixture is considered using Monte Carlo particle simulations. We show that the mean free path of solar cosmic ray protons strongly depends on the assumed spectrum and amplitude of MHD turbulence but much less on the type of the considered waves. It is demonstrated that, for realistic solar wind parameters, the presented wide range wave spectrum models can reproduce the observed mean free path in a particular SEP event but not in a wide range of rigidity characterized by the Palmer's `consensus'.  相似文献   
40.
We used two different methods of statistical analysis—cluster analysis and principal component analysis—to analyze the concentrations of principal chemical components (Si, Mg, Ca, Fe, Ni) and Co in ordinary chondrites. The analysis is based predominantly on published data (metadata). In total, chemical composition data from 646 ordinary chondrites were used in the statistical analysis. The aim of this analysis was to establish whether it would be possible or not to distinguish H, L, and LL chondrites based on the concentrations of major elements and Co in their bulk chemical compositions. It was also important to determine what conclusions such an analysis could enable to draw about matter differentiation in the formation environments of primordial parent bodies of particular ordinary chondrite groups (H, L, and LL). Another aim of the statistical analysis was to determine whether the distribution of Fe and Ni (with Co admixtures) is independent of petrographic types within particular groups of chondrites. This is of crucial importance for determining the distribution of FeNi(Co) ore occurrences in potential extraterrestrial deposits on modern asteroids—the sources of ordinary chondrites. The obtained results of statistical analyses confirmed that a clear-cut distinction between particular groups of ordinary chondrites is only possible for group H, while distinguishing L chondrites from LL chondrites is not always obvious. The results of the statistical analyses relating to the question of the possible existence of several primordial parent bodies (formation environments) of each group of ordinary chondrites are consistent with the results of contemporary astronomical spectroscopy research. What is particularly interesting is obtaining indications of the existence of common formation environments of the matter of L and LL chondrites, possibly on a few primordial parent bodies. The statistical analyses indicate that there is no correlation between the concentration of principal chemical components and the petrographic type of ordinary chondrites. This proves homogenous distributions of these elements within the parent bodies of each group of ordinary chondrites. Hence, the distribution of these elements in individual present-day asteroids is also homogenous.  相似文献   
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