The Fe-C system at 5 GPa and implications for Earth’s core

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.     

Kinematics of throughgoing fractures in jointed rocks

Throughgoing fractures play a major role in subsurface fluid flow yet the kinematics of their formation, which directly impact rock flow properties, are often difficult to establish. We investigate throughgoing fractures in the Monterey Formation of California that developed by the coalescence of pre-existing joints. At Lompoc Landing, throughgoing fractures fall into three main groups: linked, linked with aperture, and breccia zones. The segmented nature of their walls provides numerous piercing points to firmly establish the sense of displacement. Analysis of displacement vectors derived from piercing points demonstrates that the NW–SE trending throughgoing fractures, often interpreted as strike–slip faults, are in fact extensional structures in origin. We suggest that this method may be applied to throughgoing fractures that form by the same mechanism in other geologic settings. Establishing kinematics of throughgoing fractures will lead to a better understanding of their contribution to subsurface fluid flow.     

Late cenozoic bimodal magmatism in the northern basin and range province of southeastern Oregon

Compositional features of 93 samples of primitive Pliocene to recent basalts erupted along the Brothers Fault Zone in the northernmost Basin and Range indicate that they were derived from a shallow mantle source and underwent only minor shallow-level fractionation. Simple mass-balance modelling can derive these basaltic bulk compositions by removal of small amounts of observed crystalline phases from glass compositions produced in peridotite melting experiments. Additional support comes from phase equilibria data on other magnesian basalts having similar bulk compositions. The eruption of these lavas without substantial subcrustal fractionation was probably promoted by progressive extension along the Brothers Fault Zone. This origin is in sharp contrast to that generally proposed for mid-Miocene Columbia River and Steens Mountain basalts, which show clear evidence in their evolved compositions (e.g. Mg # ~ 40) of having stagnated at shallow depth where they differentiated to nearly basaltic andesite compositions. Bulk compositions of northern Basin and Range silicic rocks, together with physical and thermal considerations, suggest that they, like their counterparts in the Snake River Plain, were products of crustal anatexis driven by the injection of mafic magmas, but with meta-volcaniclastic protoliths rather than Archaean basement rocks, as in the case of the Snake River Plain rhyolites. These petrologic features suggest that the arrival of the mantle plume presently beneath Yellowstone produced or strongly influenced most late Cenozoic magmatism in the Oregon northern Basin and Range. This model accounts for many features of the northern Basin and Range in Oregon: (1) the change in basaltic character about 10 to 8 Ma ago from voluminous, evolved Columbia River/Steens lavas to smaller-volume primitive lavas and the lack of younger lavas atop the Columbia River Basalts; (2) the lack of an obvious track of the Yellowstone hot spot west of the Oregon-Idaho-Nevada tri-state area; (3) the “mirror-image” age relationship of silicic rocks in the northern Basin and Range and Snake River Plain; (4) the formation of silicic rocks by crustal anatexis and the general decrease in their volumes with time in Oregon but not along the Snake River Plain; (5) the high elevation of the region; and (6) the high surface heat flow in the Oregon northern Basin and Range. The proposed model obviates the controversy surrounding the pre-Miocene history of the Yellowstone plume by proposing that the plume initiated about 18 Ma ago.     

SPATIAL PATTERNS OF SUPPORT FOR A NUCLEAR WEAPONS FREEZE*

Support for a Freeze on nuclear weapons is greatest in the East with pockets of support in the Middle West and Pacific Coast States. Factors influencing the spatial pattern are Walker's innovativeness rankings, the number of peace/Freeze activist groups and the pattern of defense employment.     

Environmental and political implications of Vietnam's water vulnerabilities: A multiscale assessment

Vietnam's low‐lying areas of the Lower Mekong Basin are prone to floods, salt water inundation, and riparian competition with upstream neighbours. Vietnam's opening to the global economy, accompanied by industrialization and a rapidly growing population, impose multiscale (global, regional, local) stresses on urban and rural water systems resulting in water contamination and groundwater overdraft. Water vulnerability is a function of both natural and social hazards and depends on the scope of capital investment, political and ideological institutions, managerial capacity and governance. Water distribution and riparian ecosystem health are also hydropolitical issues related to dam‐building activity by Vietnam and its transboundary neighbours, Laos, Cambodia and particularly China, whose territory contains the source of the Mekong River. A multiscale assessment of Vietnam's interlinked water vulnerabilities indicates that the resilience of the country's social‐ecological water system rests on peaceful resolution of regional transboundary conflicts based on shared economic interests and on improved managerial practices of local authorities.     

Connecting Satellite Observations with Water Cycle Variables Through Land Data Assimilation: Examples Using the NASA GEOS-5 LDAS

A land data assimilation system (LDAS) can merge satellite observations (or retrievals) of land surface hydrological conditions, including soil moisture, snow, and terrestrial water storage (TWS), into a numerical model of land surface processes. In theory, the output from such a system is superior to estimates based on the observations or the model alone, thereby enhancing our ability to understand, monitor, and predict key elements of the terrestrial water cycle. In practice, however, satellite observations do not correspond directly to the water cycle variables of interest. The present paper addresses various aspects of this seeming mismatch using examples drawn from recent research with the ensemble-based NASA GEOS-5 LDAS. These aspects include (1) the assimilation of coarse-scale observations into higher-resolution land surface models, (2) the partitioning of satellite observations (such as TWS retrievals) into their constituent water cycle components, (3) the forward modeling of microwave brightness temperatures over land for radiance-based soil moisture and snow assimilation, and (4) the selection of the most relevant types of observations for the analysis of a specific water cycle variable that is not observed (such as root zone soil moisture). The solution to these challenges involves the careful construction of an observation operator that maps from the land surface model variables of interest to the space of the assimilated observations.     

Political ecology in the key of policy: From chains of explanation to webs of relation

Political ecology (PE) is rooted in a combination of critical perspectives and the hard won insights distilled from field work. The theoretical base of political ecology was joined, by Piers Blaikie and others, to an unflinching commitment to empirical observation of biophysical and socio-economic phenomena in place. To this already ambitious mix was added a practical intent to contribute to material as well as social change: a practical political ecology of alternative development ran beneath the surface of much of this work. For many this led to serious encounters with policy and the machinery of policy research institutions. While seemingly contradictory with the critical tenets of political ecology, Blaikie’s pursuit of this pathway led beyond the ivory tower to Political Ecology in the Key of Policy, initially to inform national and international policy and eventually expanding - through the work of second-generation PE - to address internal policy in social movements and alternative development networks. Among recent variations on political ecology that have built partly on the work of Blaikie, Feminist Political Ecology (FPE) expands PE to address women as a group, and gender as a category. FPE and post-structural PE are based on multiple actors with complex and overlapping identities, affinities and interests. An emergent wave of political ecology joins FPE, post-structural theory, and complexity science, to address theory, policy and practice in alternatives to sustainable development. It combines a radical empiricism and situated science, with feminist post-structural theories of multiple identity and “location”, and alternative development paradigms. This approach honors the legacy of Piers Blaikie and other PE founders yet incorporates the insights and political projects of feminism, post-structural critique and autonomous or alternative development movements.     

Grain size as an indication of shear strain in brittle fault zones

Shear strain γ in brittle fault zones is related to final and initial grain size parameters, d_f and d_i, respectively, by an expression of the form: where μ_k the coefficient of kinetic friction of crushed rock and σ_n the normal stress across the zone at the time of faulting.Technological literature suggests that ƒ(d_f, d_i) may be given by 10 , where W_i is a material constant. The resulting relationship between shear strain and grain size seems to be compatible with existing experimental data.     

Linking phytoplankton community composition with juvenile-phase growth in the Northern QuahogMercenaria mercenaria (L.)

This study examined whetherMercenaria mercenaria (L.) (quahog) growth is influenced by variability in phytoplantkon community composition in the waters of Long Island, New York. Field studies conducted during 1999 and 2000 compared juvenile quahog growth and phytoplankton assemblages between West Sayville (WS), an embayment in Great South Bay along Long Island’s south shore where quahog landings have recently declined, and Oyster Bay (OB), an embayment on Long Island’s north shore where quahog landings are still high. Quahogs grew better at OB than WS during both study years. Centric diatoms were typically the dominant phytoplankton species at OB, and pennate diatoms and dinoflagellates characterized WS. At WS, the phytoplankton community consisted of heterotrophic dinoflagellates during a brown tide in 2000 and pennate diatoms afterward. Nanoflagellates were abundant (10⁵–10⁶ cells ml^?1) at WS throughout the summer of 2000. Multiple regression analysis revealed a significant effect of site and temperature on individual clam biomass during both years, but brown tide was only significant during 2000. Biomass comparisons of dominant phytoplantkon taxa with laboratory physiology studies showed that 0B, with its abundance of centric diatoms, likely represented a more nutritional diet for quahogs than pennate diatoms, which were abundant at WS. Small flagellates, which were common at WS, may also have been important for sustaining growth during some months. Variability in plankton assemblages between OB and WS likely represented two distinct, diets that were critical influences on clam growth.