Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

Coronal environment of quiescent prominences

With thespectro-coronagraph and themultichannel subtractive double pass spectrograph (MSDP) at the Pic du Midi Observatory two quiescent prominences were observed simultaneously. From the spectro-coronagraph observations 2D maps of Hei 10830 , Fexiii 10798 and 10747 line intensities were obtained. In addition, we obtained 2D maps of the ratioR of the two iron lines. This ratio is used as a diagnostic for determining the density of the hot coronal plasma surrounding prominences. We found that the electron density is higher at the location of the prominences than in the corona, whereas small regions (40) of lower electron density are unevenly distributed around the prominences indicating that the surrounding corona is highly inhomogeneous. The density of the cavity is reduced by a factor 1.5 compared to the density of the prominence environment (5 × 10⁸ cm^–3). We discuss the existence of cavities around these prominences according to the orientation of their axes relative to the line of sight and according to the velocity field inside the prominences. Constraints on models for prominence formation are derived.     

Variabilité isotopique des précipitations sahéliennes à différentes échelles de temps à Niamey (Niger) entre 1992 et 1999 : implication climatiqueIsotopic variability of Sahelian rainfall at different time steps in Niamey (Niger, 1992–1999): climatic implications

The isotopic content of rainfall was measured in Niamey (Niger) over a period of eight years (1992–1999). Seasonal distribution of rainy events depends on the monsoon movement over the region. At the beginning and at the end of the rainy season, low rainfall, high temperatures and low relative humidity favour isotopic enrichment. In the middle of the rainy season, heavy rainfall, low temperatures and relative humidity close to saturation lead to isotopically depleted contents because of the mass effect; moreover, in the case of low rainfall, marked vertical convective development favours high altitude condensation. How far the Intertropical Front moves north, determines the quality of the rainy season and influences the isotopic contents. Thus the isotopic contents of rainfall are good climatic indicators. To cite this article: J.-D. Taupin et al., C. R. Geoscience 334 (2002) 43–50     

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.     

Magnetic activity inside the auroral zones and field-aligned currents

Big perturbations of the magnetic field (amplitudes larger than 250 nT) are simply detected by subtracting the values of a model from the measurements of CHAMP satellite. Taking a full year of CHAMP data and organizing them in four subsets of three months length (spring, summer, autumn, winter), it is found that: (a) the two domains where such big perturbations mainly exist are limited, in both hemispheres, by a parallel of high latitude of the corrected geomagnetic coordinates system; (b) a conspicuous seasonal (annual) variation affects the density of the perturbations and is opposite in the two hemispheres. We hold that these perturbations are linked to the midday magnetic activity within the auroral zone, long ago described by one of us (Mayaud, 1956). The source of the perturbations observed at the satellite altitude would be field-aligned currents resulting from the penetration of the solar wind into the magnetospheric cusps. To cite this article: J.-L. Le Mouël et al., C. R. Geoscience 335 (2003).     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

青藏高原东北侧干旱的数值试验

用谱方法（Ｔ４２）求解半球球面无辐散正压涡度方程,采用实际的干旱环流资料,分别在有地形和无地形的情况下,求出其对应的干旱环流型的强迫场,模拟了在强迫场的作用下干旱环流的形成、维持情况及在强迫场消失后干旱环流型的崩溃情况。结果表明：（１）强迫场在干旱环流型的形成、维持及崩溃过程中起重要作用;（２）青藏高原的存在使其东北侧干旱形成和崩溃均加快。     

Scaling of the Vertical Spreading of a Plume of a Passive Tracer in a Rough-Wall Neutral Boundary Layer

The influence of surface roughness on the dispersion of a passive scalar in a rough wall turbulent boundary layer has been studied using wind-tunnel experiments. The surface roughness was varied using different sizes of roughness elements, and different spacings between the elements. Vertical profiles of average concentration were measured at different distances downwind of the source, and the vertical spread of the plume was computed by fitting a double Gaussian profile to the data. An estimate of the integral length scale is derived from the turbulence characteristics of the boundary layer and is then used to scale the measured values of plume spread. This scaling reduces the variability in the data, confirming the validity of the model for the Lagrangian integral time scale, but does not remove it entirely. The scaled plume spreading shows significant differences from predictions of theoretical models both in the near and in the far field. In the region immediately downwind of the source this is due to the influence of the wake of the injector for which we have developed a simple model. In the far field we explain that the differences are mainly due to the absence of large-scale motions. Finally, further downwind of the source the scaled values of plume spread fall into two distinct groups. It is suggested that the difference between the two groups may be related to the lack of dynamical similarity between the boundary-layer flows for varying surface roughness or to biased estimates of the plume spread.     

Numerical simulation of percussive drilling

This paper presents a novel dynamical model to analyze the long‐term response of a percussive drilling system. This departs from existing approaches that usually consider a single activation and bit/rock interaction cycle for the analysis of the process performance. The proposed model integrates the axial dynamics of an elastic piston and an elastic drill bit, a motion‐dependent pressure law to drive the piston, and a generalized bit/rock interaction law representative of the dynamic indentation taking place at the bit/rock interface. It applies to down‐the‐hole percussive drilling as well as top‐hole, with minor modifications. The model does not account for the angular motion or the hole cleaning, however. The model is first formulated mathematically; then, a finite‐dimensional approximation is proposed for computations. Numerical analyses of the model response, for a low‐size down‐the‐hole percussive system, follow. The period‐1 stationary response for the reference configuration is studied in detail, and parametric analyses assessing the influence on the rate of penetration of the bit/rock interaction parameters, the feed force, and the percussive activation parameters are conducted. These analyses reveal that the multiscale nature of the process is well captured by the model and recover expected trends for the influence of the parameters. They also suggest that a significant increase of the penetration rate can be achieved by increasing the percussive frequency. Copyright © 2015 John Wiley & Sons, Ltd.