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The partitioning of Fe and Mg between olivine and carbonate and the stability of carbonate under mantle conditions 总被引:4,自引:1,他引:4
We have investigated the effect of Fe on the stabilities of carbonate (carb) in lherzolite assemblages by determining the partitioning of Fe and Mg between silicate (olivine; ol) and carbonates (magnesite, dolomite, magnesian calcite) at high pressures and temperatures. Fe enters olivine preferentially relative to magnesite and ordered dolomite, but Fe and Mg partition almost equally between disordered calcic carbonate and olivine. Measurement of K
d
(X
Fe
carb
X
Mg
ol
/X
Fe
ol
X
Mg
carb
) as a function of Fe/ Mg ratio indicates that Fe–Mg carbonates deviate only slightly from ideality. Using the regular solution parameter for olivine W
FeMg
ol
of 3.7±0.8 kJ/mol (Wiser and Wood 1991) we obtain for (FeMg)CO3 a W
FeMg
carb
of 3.05±1.50 kJ/mol. The effect of Ca–Mg–Fe disordering is to raise K
d
substantially enabling us to calculate W
CaMg
carb
-W
CaFe
carb
of 5.3±2.2 kJ/mol. The activity-composition relationships and partitioning data have been used to calculate the effect of Fe/Mg ratio on mantle decarbonation and exchange reactions. We find that carbonate (dolomite and magnesian calcite) is stable to slightly lower pressures (by 1 kbar) in mantle lherzolitic assemblages than in the CaO–MgO–SiO2(CMS)–CO2 system. The high pressure breakdown of dolomite + orthopyroxene to magnesite + clinopyroxene is displaced to higher pressures (by 2 kbar) in natural compositions relative to CMS. CO2. We also find a stability field of magnesian calcite in lherzolite at 15–25 kbar and 750–1000°C. 相似文献
4.
Pranab K. Roy Chowdhury Jeanette E. Weaver Eric M. Weber Dalton Lunga St. Thomas M. LeDoux Amy N. Rose 《International Journal of Digital Earth》2020,13(1):119-135
ABSTRACTUrban areas presently consume around 75% of global primary energy supply, which is expected to significantly increase in the future due to urban growth. Having sustainable, universal energy access is a pressing challenge for most parts of the globe. Understanding urban energy consumption patterns may help to address the challenges to urban sustainability and energy security. However, urban energy analyses are severely limited by the lack of urban energy data. Such datasets are virtually non-existent for the developing countries. As per current projections, most of the new urban growth is bound to occur in these data-starved regions. Hence, there is an urgent need of research methods for monitoring and quantifying urban energy utilization patterns. Here, we apply a data-driven approach to characterize urban settlements based on their formality, which is then used to assess intra-urban urban energy consumption in Johannesburg, South Africa; Sana’a, Yemen; and Ndola, Zambia. Electricity is the fastest growing energy fuel. By analyzing the relationship between the settlement types and the corresponding nighttime light emission, a proxy of electricity consumption, we assess the differential electricity consumption patterns. Our study presents a simple and scalable solution to fill the present data void to understand intra-city electricity consumption patterns. 相似文献
5.
Dale P. Cruikshank Allan W. Meyer Roger N. Clark Katrin Stephan Scott A. Sandford Gianrico Filacchione Philip D. Nicholson Thomas B. McCord J. Brad Dalton Dennis L. Matson 《Icarus》2010,206(2):561-572
Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO2) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm−1), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO2 absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO2, CO2 clathrates, ternary mixtures of CO2 with other volatiles, implanted and adsorbed CO2 in non-volatile materials, and ab initio theoretical calculations of CO2 * nH2O. At the wavelength resolution of VIMS, the CO2 on Phoebe is indistinguishable from pure CO2 ice (each molecule’s nearby neighbors are also CO2) or type II clathrate of CO2 in H2O. In contrast, the CO2 band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm−1)) and broadened. These wavelengths are characteristic of complexes of CO2 with different near-neighbor molecules that are encountered in other volatile mixtures such as with H2O and CH3OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO2 is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO2 on the other three satellites results at least in part from particle or UV irradiation of native H2O plus a source of C, implantation or accretion from external sources, or redistribution of native CO2 from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO2 gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO2 absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO2 absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO2, as discussed in this paper. 相似文献
6.
Manuela Magliocchetti Steve J. Maddox Ed Hawkins John A. Peacock Joss Bland-Hawthorn Terry Bridges Russell Cannon Shaun Cole Matthew Colless Chris Collins Warrick Couch Gavin Dalton Roberto de Propris Simon P. Driver George Efstathiou Richard S. Ellis Carlos S. Frenk Karl Glazebrook Carole A. Jackson Bryn Jones Ofer Lahav Ian Lewis Stuart Lumsden Peder Norberg Bruce A. Peterson Will Sutherland Keith Taylor 《Monthly notices of the Royal Astronomical Society》2004,350(4):1485-1494
7.
The 2dF Galaxy Redshift Survey: the bJ -band galaxy luminosity function and survey selection function
Peder Norberg Shaun Cole Carlton M. Baugh Carlos S. Frenk Ivan Baldry Joss Bland-Hawthorn Terry Bridges Russell Cannon Matthew Colless Chris Collins Warrick Couch Nicholas J. G. Cross Gavin Dalton Roberto De Propris Simon P. Driver George Efstathiou Richard S. Ellis Karl Glazebrook Carole Jackson Ofer Lahav Ian Lewis Stuart Lumsden Steve Maddox Darren Madgwick John A. Peacock Bruce A. Peterson Will Sutherland Keith Taylor 《Monthly notices of the Royal Astronomical Society》2002,336(3):907-931
8.
Peder Norberg Carlton M. Baugh Ed Hawkins Steve Maddox John A. Peacock Shaun Cole Carlos S. Frenk Joss Bland-Hawthorn Terry Bridges Russell Cannon Matthew Colless Chris Collins Warrick Couch Gavin Dalton Roberto De Propris Simon P. Driver George Efstathiou Richard S. Ellis Karl Glazebrook Carole Jackson Ofer Lahav Ian Lewis Stuart Lumsden Darren Madgwick Bruce A. Peterson Will Sutherland Keith Taylor 《Monthly notices of the Royal Astronomical Society》2001,328(1):64-70
We investigate the dependence of the strength of galaxy clustering on intrinsic luminosity using the Anglo-Australian two degree field galaxy redshift survey (2dFGRS). The 2dFGRS is over an order of magnitude larger than previous redshift surveys used to address this issue. We measure the projected two-point correlation function of galaxies in a series of volume-limited samples. The projected correlation function is free from any distortion of the clustering pattern induced by peculiar motions and is well described by a power law in pair separation over the range . The clustering of galaxies in real space is well-fitted by a correlation length and power-law slope . The clustering amplitude increases slowly with absolute magnitude for galaxies fainter than M *, but rises more strongly at higher luminosities. At low luminosities, our results agree with measurements from the Southern Sky Redshift Survey 2 by Benoist et al. However, we find a weaker dependence of clustering strength on luminosity at the highest luminosities. The correlation function amplitude increases by a factor of 4.0 between and −22.5, and the most luminous galaxies are 3.0 times more strongly clustered than L * galaxies. The power-law slope of the correlation function shows remarkably little variation for samples spanning a factor of 20 in luminosity. Our measurements are in very good agreement with the predictions of the hierarchical galaxy formation models of Benson et al. 相似文献
9.
Donald S. Mussel White Heather A. Dalton Walter S. Kiefer Allan H. Treiman 《Meteoritics & planetary science》2006,41(9):1271-1290
Abstract— The Martian meteorite Yamato (Y‐) 980459 is an olivine‐phyric shergottite. It has a very primitive character and may be a primary melt of the Martian mantle. We have conducted crystallization experiments on a synthetic Y‐980459 composition at Martian upper mantle conditions in order to test the primary mantle melt hypothesis. Results of these experiments indicate that the cores of the olivine megacrysts in Y‐980459 are in equilibrium with a melt of bulk rock composition, suggesting that these megacrysts are in fact phenocrysts that grew from a magma of the bulk rock composition. Multiple saturation of the melt with olivine and a low‐calcium pyroxene occurs at approximately 12 ± 0.5 kbar and 1540 ± 10°C, suggesting that the meteorite represents a primary melt that separated from its mantle source at a depth of ?100 km. Several lines of evidence suggest that the Y‐980459 source underwent extensive melting prior to and/or during the magmatic event that produced the Y‐980459 parent magma. When factored into convective models of the Martian interior, the high temperature indicated for the upper Martian mantle and possibly high melt fraction for the Y‐980459 magmatic event suggests a significantly higher temperature at the core‐mantle boundary than previously estimated. 相似文献
10.
Ian Lewis Michael Balogh Roberto De Propris Warrick Couch Richard Bower Alison Offer Joss Bland-Hawthorn Ivan K. Baldry Carlton Baugh Terry Bridges Russell Cannon Shaun Cole Matthew Colless Chris Collins Nicholas Cross Gavin Dalton Simon P. Driver George Efstathiou Richard S. Ellis Carlos S. Frenk Karl Glazebrook Edward Hawkins Carole Jackson Ofer Lahav Stuart Lumsden Steve Maddox Darren Madgwick Peder Norberg John A. Peacock Will Percival Bruce A. Peterson Will Sutherland Keith Taylor 《Monthly notices of the Royal Astronomical Society》2002,334(3):673-683