Numerical simulation of comet nuclei I. Water-ice comets

A one-dimensional simulation of pure water-ice cometary nuclei is presented, and the effect of the nucleus as a heat reservoir is considered. The phase transition from amorphous to crystalline ice is studied for two cases: (1) where the released latent heat goes entirely into heating adjacent layers and (2) where the released latent heat goes entirely into sublimation. For a Halley-like orbit it was found that for case 1 the phase boundary penetrates about 15 m on the first orbit and does not advance until sublimation brings the surface to some 10 m from the phase boundary. For case 2 the phase boundary penetrates about 1 m below the surface and remains at this depth as the surface sublimates. For an orbit like that of Schwassmann-Wachmann 1 the phase boundary penetrates about 50 m initially for case 1 and about 1 m for case 2. There is no further transformation until the entire comet is heated slowly to near the transition temperature, after which the entire nucleus is converted to crystalline ice. For an Encke-type orbit case 1 gives a nearly continuous transition of the entire nucleus to crystalline ice, while for case 2 the initial penetration is about 8 m and remains at this depth relative to the surface as sublimation decreases the cometary radius. Thus the entire comet is converted to crystalline ice just before it is completely dissipated.     

Numerical simulations of comet nuclei: II. The effect of the dust mantle

The insulating effect of an evolving dust mantle is examined. The role of this mantle in determining the surface temperature of the ice core is studied as a function of the mass fraction of the dust in the ice-dust mixture and the thermal conductivity of the nucleus. Using the so-called “looselattice” model of D.A. Mendis and G.D. Brin (1977, Moon17, 359–372) (which was also extended to include cracks and pores in the mantle), it was found that both high dust to ice ratios and high core conductivities inhibit mantle blowoff. Indeed, it is often possible to build an essentially permanent dust mantle around an ice nucleus, so that the nucleus will take on an asteroidal appearance.     

Transient biouptake flux and accumulation by microorganisms: The case of two types of sites with Langmuir adsorption

The uptake of a chemical species by an aquatic microorganism is modelled considering two kinds of sites where Langmuirian adsorption is followed by first order internalisation kinetics. Simpler models, such as only one internalisation route (while most of the adsorption takes place on non-internalising sites) or a linear isotherm for adsorption on one or both sites, become limiting cases of this double-Langmuirian model. The model considers the sites located on the spherical (or semi-spherical) surface of the organism, and takes diffusion from the medium into explicit account. The numerical solution for the internalisation flux shows a maximum. We provide an estimate for the time needed to reach a certain proximity to steady state. The transient solution confirms that the analytical expressions for the steady-state flux are usually valid and that the accumulated amounts reflect the impact of the short-time uptake. The Instantaneous Steady-State Approximation (ISSA), where an intercept of the linear regression of accumulated amount as a function of time is interpreted as an adsorbed amount, can be critically assessed with the transient numerical code for two cases: (i) when the total burden of metal on the cell is the input data and (ii) when an extraction procedure provides further information on the adsorbed and internalised amount.     

From in-situ coal to fly ash: a study of coal mines and power plants from Indiana

This paper presents data on the properties of coal and fly ash from two coal mines and two power plants that burn single-source coal from two mines in Indiana. One mine is in the low-sulfur (<1%) Danville Coal Member of the Dugger Formation (Pennsylvanian) and the other mines the high-sulfur (>5%) Springfield Coal Member of the Petersburg Formation (Pennsylvanian). Both seams have comparable ash contents (11%). Coals sampled at the mines (both raw and washed fractions) were analyzed for proximate/ultimate/sulfur forms/heating value, major oxides, trace elements and petrographic composition. The properties of fly ash from these coals reflect the properties of the feed coal, as well as local combustion and post-combustion conditions. Sulfur and spinel content, and As, Pb and Zn concentrations of the fly ash are the parameters that most closely reflect the properties of the source coal.     

Optical properties of pseudovitrinite; implications for its origin

A set of Pennsylvanian coals from the North American coal basins, ranging in vitrinite reflectance from 0.65% to 1.75%, was examined, with special emphasis on the optical properties of pseudovitrinite. The results suggest that pseudovitrinite originates from the same material as telocollinite. Slits in the pseudovitrinite seem to have originated in situ due to low-temperature oxidation of woody material; their opening might have been facilitated by devolatilization during coalification. The dominant orientation of the slits is perpendicular to bedding. The intensity and orientation of the slits in pseudovitrinite could be important factors in predicting coalbed gas extraction from coal.     

A Holocene high-resolution record of aquatic productivity,seasonal anoxia and meromixis from varved sediments of Lake Łazduny,North-Eastern Poland: insight from a novel multi-proxy approach

Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high-resolution hyperspectral imaging with µ-XRF and HPLC-pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve-scale resolution. Our ~9700 cal a bp varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a bp ) to mesotrophic conditions in the Mid- and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm-moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi-decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a bp. Anthropogenic deforestation around 400 cal a bp resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.